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Insight into vertical piezoelectric characteristics regulated thermal transport in van der Waals two-dimensional materials

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Rare Metals 2024年第2期43卷 770-779页

作者： Dong-Hai Wei E Zhou Jin-Yuan Xu Hui-Min Wang Chen Shen Hong-Bin Zhang Zhen-Zhen Qin Guang-Zhao Qin State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body College of Mechanical and Vehicle EngineeringHunan UniversityChangsha410082China Hunan Key Laboratory for Micro-Nano Energy Materials and Device and School of Physics and Optoelectronics Xiangtan UniversityXiangtan411105China Institute of Materials Science Technical University of DarmstadtAlarich-Weiss-Str.264287DarmstadtGermany School of Physics and Microelectronics Zhengzhou UniversityZhengzhou450001China

The urgent demand of extreme(ultra-high/low)thermal conductivity materials is triggered by the high-power device,where exploring the theories and mechanisms of regulating thermal transport properties plays a key role.Herein,we elaborately investigate the effect of vertical(out-of-plane)piezoelectric characteristics on thermal transport,which is historically undiscovered.The different stacking-order(AA and AB)bilayer boron nitride(Bi-BN)in two-dimensional(2D)materials are selected as study cases.By performing state-of-the-art first-principles calculations,it is found that the polarization charge along the out-of-plane orientation ascends significantly with the increasing piezoelectric response in AB stacked Bi-BN(Bi-BN-AB)followed by the enhanced interlayer B–N atomic interactions.Consequently,the amplitude of phonon anharmonicity in Bi-BN-AB increases larger than that in the AA stacked Bi-BN(Bi-BN-AA),resulting in the dramatic weakening of the thermal conductivity by 20.34%under 18%strain.Our research reveals the significant role of the vertical(out-of-plane)piezoelectric characteristic in regulating thermal transport and provides new insight into accurately exploring the thermal transport performance of 2D van der Waals materials.

关键词： Thermal conductivity piezoelectric effect 2D materials Bilayer BN Strain engineering

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Review on piezoelectric actuators:materials,classifications,applications,and recent trends

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Frontiers of Mechanical Engineering 2024年第1期19卷 5-33页

作者： Xuyang ZHOU Shuang WU Xiaoxu WANG Zhenshan WANG Qixuan ZHU Jinshuai SUN Panfeng HUANG Xuewen WANG Wei HUANG Qianbo LU Institute of Flexible Electronics(IFE) Northwestern Polytechnical UniversityXi’an 710072China School of Automation Northwestern Polytechnical UniversityXi’an 710072China Key Laboratory of Flexible Electronics of Zhejiang Province Ningbo Institute of Northwestern Polytechnical UniversityNingbo 315103China

piezoelectric actuators are a class of actuators that precisely transfer input electric energy into displacement,force,or movement outputs efficiently via inverse piezoelectric effect-based electromechanical coupling.Various types of piezoelectric actuators have sprung up and gained widespread use in various applications in terms of compelling attributes,such as high precision,flexibility of stoke,immunity to electromagnetic interference,and structural scalability.This paper systematically reviews the piezoelectric materials,operating principles,representative schemes,characteristics,and potential applications of each mainstream type of piezoelectric actuator.Herein,we intend to provide a more scientific and nuanced perspective to classify piezoelectric actuators into direct and indirect categories with several subcategories.In addition,this review outlines the pros and cons and the future development trends for all kinds of piezoelectric actuators by exploring the relations and mechanisms behind them.The rich content and detailed comparison can help build an in-depth and holistic understanding of piezoelectric actuators and pave the way for future research and the selection of practical applications.

关键词： piezoelectric actuator piezoelectric effect amplified piezoelectric actuator ultrasonic actuator stepping actuator piezoelectric polymer

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Highly efficient reduction of aqueous Cr(VI) with novel ZnO/SnS nanocomposites through the piezoelectric effect

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Journal of Environmental Sciences 2022年第8期34卷 57-66页

作者： Hao Sun Soo-Jin Park Department of Chemistry and Chemical Engineering Inha UniversityIncheon 22212South Korea

In this work, novel ZnO/SnS nanocomposites were successfully synthesized via a hydrothermal approach, which is developed for piezoelectric catalytic reduction of hexavalent chromium(Cr(VI)) in an aqueous solution. The constructed ZnO/SnS nanocomposites exhibited higher catalytic efficiency for Cr(VI) reduction under a mechanical force(e.g., ultrasonic vibration) compared to pristine ZnO and SnS. In particular, the ZnO/SnS(with 30 wt.% of SnS) heterojunctions revealed an optimal degradation activity among all the prepared samples, which completely removed the Cr(VI)(20 mg/L) solution within 35 min. Moreover, the piezoelectric catalytic activity of ZnO/SnS remained stable after four consecutive cycling experiments. The results of the morphology observations indicated that the SnS nanoparticles adhere to the surface of the ZnO nanorods. The improved piezoelectric catalytic performance of the ZnO/SnS heterojunctions can be attributed to the formation of an intimate interfacial between ZnO and SnS, which effectively inhibits the electron-hole recombination and speeds up the rate of charge transfer. The study reveals a new design of ZnO/SnS heterojunctions as a high-performance and eco-friendly piezoelectric catalyst and provides a promising strategy for addressing environmental problems and energy crises.

关键词： Cr(VI)reduction ZnO/SnS piezoelectric effect

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Extraordinary piezoelectric effect induced in two-dimensional rare earth monochalcogenides via reducing system dimensionality

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Journal of Materiomics 2023年第1期9卷 72-81页

作者： Neveen I.Atallah Maged El-Kemary Fabien Pascale Khaled E.El-Kelany Institute of Nanoscience and Nanotechnology Kafrelsheikh University33516Kafr el-skiekhEgypt Universite de Lorraine-Nancy CNRSLaboratoire de Physique et Chimie TheoriquesUMR 7019Vandoeuvre-les-NancyFrance

piezoelectricity is pivotal for applications in micro/nanoelectromechanical systems(MEMS/NEMS).Inducing such a property in 2D systems via the reduction of the dimensionality of their corresponding 3D bulk is here explored.Based on DFT theory and Gaussian-type-localized basis sets,the structural,electronic,mechanical,and piezoelectric properties of both 3D and 2D rare earth monochalcogenides RmX(Rm=Tm,Yb,Lu,and X=S,Se,Te)are investigated using the CRYSTAL code.Most intriguingly,the 2D LuX compounds display a buckled structure,where the Lu and X atoms protrude from the monolayer surface leading to an additional out-of-plane piezoelectric effect;(e_(31)=2104.84,1770.28,1689.79 pC/m,and d31=56.37,49.76,and 147.90 pm/V for LuS,LuSe,and LuTe,respectively).Such piezoelectric response is two orders of magnitude larger than the one of recently reported 2D ferroelectric MXenes,and is nearly thirty times larger than the commonly used AlN and GaN bulk structures.Furthermore,the reduced elastic constants obtained,when compared to other 2D materials,confirm the flexibility and softness of the considered 2D systems.

关键词： 2D materials Rare earth monochalcogenides DFT Gaussian basis CRYSTAL code piezoelectric effect MEMS/NEMS

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Recent Advances in Strain-Induced piezoelectric and Piezoresistive effect-Engineered 2D Semiconductors for Adaptive Electronics and Optoelectronics

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Nano-Micro Letters 2020年第8期12卷 236-279页

作者： Feng Li Tao Shen Cong Wang Yupeng Zhang Junjie Qi Han Zhang Institute of Microscale Optoelectronics International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of EducationCollege of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060People’s Republic of China School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083People’s Republic of China

The development of two-dimensional(2D)semiconductors has attracted widespread attentions in the scientific community and industry due to their ultra-thin thickness,unique structure,excellent optoelectronic properties and novel physics.The excellent flexibility and outstanding mechanical strength of 2D semiconductors provide opportunities for fabricated strain-sensitive devices and utilized strain tuning their electronic and optic–electric performance.The strain-engineered one-dimensional materials have been well investigated,while there is a long way to go for 2D semiconductors.In this review,starting with the fundamental theories of piezoelectric and piezoresistive effect resulted by strain,following we reviewed the recent simulation works of strain engineering in novel 2D semiconductors,such as Janus 2D and 2D-Xene structures.Moreover,recent advances in experimental observation of strain tuning PL spectra and transport behavior of 2D semiconductors are summarized.Furthermore,the applications of strain-engineered 2D semiconductors in sensors,photodetectors and nanogenerators are also highlighted.At last,we in-depth discussed future research directions of strain-engineered 2D semiconductor and related electronics and optoelectronics device applications.

关键词： 2D semiconductors Strain piezoelectric effect Piezoresistive effect Electronic and optoelectronics

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Fundamental solutions of critical wedge angles for one-dimensional piezoelectric quasicrystal wedge

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Applied Mathematics and Mechanics(English Edition) 2022年第5期43卷 709-728页

作者： Xiang MU Xiaoyu FU Liangliang ZHANG Zhaowei ZHU Jinming ZHANG Yang GAO College of Science China Agricultural UniversityBeijing 100083China College of Engineering China Agricultural UniversityBeijing 100083China

Two problems of a one-dimensional(1D)piezoelectric quasicrystal(QC)wedge are investigated,i.e.,the two sides of the wedge subject to uniform tractions and the wedge apex subject to the concentrated force.By virtue of the Stroh formalism and Barnett-Lothe matrices,the analytical expressions of the displacements and stresses are derived,and the generalized solutions for the critical wedge angles are discussed.Numerical examples are given to present the mechanical behaviors of the wedge in each field.The results indicate that the effects of the uniform tractions and the concentrated force on the phonon field displacement are larger than those on the phason field.

关键词： quasicrystal(QC) wedge piezoelectric effect critical angle analytical solution

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piezoelectric effects and electronic structures of InAs/GaAs quantum dots grown along (111) and (011) directions

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Chinese Physics B 2010年第6期19卷 482-486页

作者：赵伟俞重远刘玉敏 Key Laboratory of Information Photonics and Optical Communications Ministry of EducationBeijing University of Posts and Telecommunications

piezoelectric effects and electronic structures of InAs/GaAs quantum dots grown along （111） and （011） directions are investigated in this paper. The finite element method is used. Electronic energy levels are calculated by solving the three-dimensional effective mass Schrodinger equation including a strain modified confinement potential and piezoelectric effects. The difference in electronic structure between quantum dots grown along the （111） direction and the （011） direction are compared. The cubic and truncated pyramidal shaped quantum dots are adopted.

关键词： quantum dot electronic structure piezoelectric effect

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High efficiently harvesting visible light and vibration energy in(1−x)AgNbO_(3)-xLiTaO_(3) solid solution around antiferroelectric-ferroelectric phase boundary for dye degradation

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Journal of Advanced Ceramics 2022年第10期11卷 1641-1653页

作者： Tufeng HE Zhenzhu CAO Guorong LI Yanmin JIA Biaolin PENG College of Chemical Engineering Inner Mongolia University of TechnologyHohhot 010051China Key Laboratory of Inorganic Function Material and Device Shanghai Institute of CeramicsChinese Academy of SciencesShanghai 200050China School of Science Xi’an University of Posts&TelecommunicationsXi’an 710121China School of Advanced Materials and Nanotechnology Xidian UniversityXi’an 710126China

Simultaneously employing light and vibration energy by piezoelectric material to realize environmental remediation is an advanced oxidation method.Silver niobate(AgNbO_(3))is a visible light driven photocatalyst for the removal of organic pollutants.However,the high recombination rate of photo-generated electrons and holes suppresses its photocatalytic activity.piezoelectric potential excited by vibration can facilitate the separation of light induced charges.Unfortunately,AgNbO_(3) is an antiferroelectric.In this work,distinct photo-/vibration-bi-catalysis has been achieved in ferroelectric(1−x)AgNbO_(3)-xLiTaO_(3) solid solution.The results show that ~96% Rhodamine B(RhB)can be decomposed under the bi-excitation of ultrasound and visible light within 120 min with 0.95AgNbO_(3)-0.05LiTaO_(3) catalyst.The synergy effect from efficient visible light excitation and enhanced separation of the photo-induced charges from the electric field by the mechanical strain results in the distinct decomposition performance of catalysts.

关键词： piezoelectric effect photocatalysis visible light decomposition

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Stretchable nanogenerators for scavenging mechanical energy

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Nano Research 2023年第9期16卷 11682-11697页

作者： Chong Guo Lan Xu Yuan Su Hongwei Li Mei Zhang Ya Yang CAS Center for Excellence in Nanoscience Beijing Key Laboratory of Micro-nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing 101400China Beijing Key Laboratory of Clothing Materials R&D and Assessment Beijing Engineering Research Center of Textile NanofiberSchool of Materials Design and EngineeringBeijing Institute of Fashion TechnologyBeijing 100029China School of Nanoscience and Technology University of Chinese Academy of SciencesBeijing 100049China Center on Nanoenergy Research School of Physical Science and TechnologyGuangxi UniversityNanning 530004China

Using stretchable nanogenerators to obtain disordered mechanical energy from the environment is an ideal way to realize wearable power supply equipment and self-power electronic devices,and alleviate the energy crisis.It is of great significance to integrate the stretchability into the nanogenerator,which can fit the complex shape of the target object better and is well suitable for wearable electronics.When applied to the human body,it can directly harvest human body mechanical energy to power wearable electronic devices and get rid of the trouble of charging.This paper systematically reviewed nanogenerators in stretchability,focusing on stretchable triboelectric nanogenerators,stretchable piezoelectric nanogenerators,and stretchable hybrid nanogenerators.Their physical mechanism,material selection,structure design,and output performance are discussed in detail.It is concluded that the fabrication methods of various devices can be broadly categorized into the two most important device types,namely fiber-like and planar.A detailed analysis of representative work and the latest progress in the past decade is performed.It is most important that excellent stretchability and high-power output are the key point to realize application value of stretchable nanogenerators.In addition,we discuss opportunities and challenges,as well as future development direction of stretchable nanogenerators.

关键词： stretchable wearable devices triboelectric nanogenerator piezoelectric effect hybrid nanogenerator

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piezoelectric Materials for Controlling Electro-Chemical Processes

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Nano-Micro Letters 2020年第11期12卷 51-89页

作者： Weiqi Qian Weiyou Yang Yan Zhang Chris R.Bowen Ya Yang CAS Center for Excellence in Nanoscience Beijing Key Laboratory of Micro‑nano Energy and SensorBeijing Institute of Nanoenergy and NanosystemsChinese Academy of SciencesBeijing 100083People’s Republic of China Institute of Materials Ningbo University of TechnologyNingbo 315211People’s Republic of China Department of Mechanical Engineering University of BathBath BA27AKUK School of Nanoscience and Technology University of Chinese Academy of SciencesBeijing 100049People’s Republic of China Center on Nanoenergy Research School of Physical Science and TechnologyGuangxi UniversityNanning 530004People’s Republic of China

piezoelectric materials have been analyzed for over 100 years,due to their ability to convert mechanical vibrations into electric charge or electric fields into a mechanical strain for sensor,energy harvesting,and actuator applications.A more recent development is the coupling of piezoelectricity and electro-chemistry,termed piezo-electro-chemistry,whereby the piezoelectrically induced electric charge or voltage under a mechanical stress can influence electro-chemical reactions.There is growing interest in such coupled systems,with a corresponding growth in the number of associated publications and patents.This review focuses on recent development of the piezo-electro-chemical coupling multiple systems based on various piezoelectric materials.It provides an overview of the basic characteristics of piezoelectric materials and comparison of operating conditions and their overall electro-chemical performance.The reported piezo-electro-chemical mechanisms are examined in detail.Comparisons are made between the ranges of material morphologies employed,and typical operating conditions are discussed.In addition,potential future directions and applications for the development of piezo-electro-chemical hybrid systems are described.This review provides a comprehensive overview of recent studies on how piezoelectric materials and devices have been applied to control electro-chemical processes,with an aim to inspire and direct future efforts in this emerging research field.

关键词： piezoelectric materials piezoelectric effect Electro-chemistry Piezo-electro-chemistry

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