检索结果-南通市图书馆

Dual-functional marigold-like Zn_(x)Cd_(1-x)S homojunction for selective glucose photoreforming with remarkable H_(2)coproduction

引用

Journal of Energy Chemistry 2023年第4期79卷 158-167页

作者： Fuyan Kang Cai Shi Yeling Zhu Malin Eqi Junming Shi Min Teng Zhanhua Huang Chuanling Si Feng Jiang Jinguang Hu Key Laboratory of Bio-based Material Science and Technology Ministry of EducationMaterial Science and Engineering CollegeNortheast Forestry UniversityHarbin 150040HeilongjiangChina Tianjin Key Laboratory of Pulp and Paper College of Light Industry and EngineeringTianjin University of Science and TechnologyTianjin 300457China Sustainable Functional Biomaterials Lab Department of Wood ScienceUniversity of British Columbia2424 Main MallVancouver V6T 1Z4Canada Department of Chemical and Petroleum Engineering University of Calgary2500 University DriveNWCalgaryAlberta T2N 1N4Canada

The global commitment to pivoting to sustainable energy and products calls for technology development to utilize solar energy for hydrogen(H_(2))and value-added chemicals production by biomass ***,a novel dual-functional marigold-like Zn_(x)Cd_(1-x)S homojunction has been the production of lactic acid with high-yield and H_(2)with high-efficiency by selective glucose *** optimized Zn_(0.3)Cd_(0.7)S exhibits outstanding H_(2)generation(13.64 mmol h^(-1)g^(-1)),glucose conversion(96.40%),and lactic acid yield(76.80%),over 272.80 and 19.21 times higher than that of bare ZnS(0.05 mmol h^(-1)g^(-1))and CdS(0.71 mmol h^(-1)g^(-1))in H_(2)generation,*** marigold-like morphology provides abundant active sites and sufficient substrates accessibility for the photocatalyst,while the specific role of the homojunction formed by hexagonal wurtzite(WZ)and cubic zinc blende(ZB)in photoreforming biomass has been demonstrated by density functional theory(DFT)*** is converted to lactic acid on the WZ surface of Zn_(0.3)Cd_(0.7)S via the photoactive species·O_(2)^(-),while the H_(2)is evolved from protons(H^(+))in H_(2)O on the ZB surface of Zn_(0.3)Cd_(0.7)*** work paves a promising road for the production of sustainable energy and products by integrating photocatalysis and biorefine.

关键词： Zn_(x)Cd_(1-x)S homojunction Selective glucose photoreforming Biomass valorization Sustainable H_(2) photoreforming mechanism

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：