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Highly efficient vanadium redox flow batteries enabled by a trilayer polybenzimidazole membrane assembly

CARBON ENERGY 2024年第7期6卷 191-204页

作者： Bui, Trung Tuyen Shin, Mingyu Rahimi, Mohammad Bentien, Anders Kwon, Yongchai Henkensmeier, Dirk Korea Inst Sci & Technol KIST Hydrogen Fuel Cell Res Ctr Seoul South Korea Univ Sci & Technol KIST Sch Div Energy & Environm Technol Seoul South Korea Korea Univ Grad Sch Energy & Environm Seoul South Korea Korea Inst Sci & Technol KIST Hydrogen Fuel Cell Res Ctr Seoul 02792 South Korea Seoul Natl Univ Sci & Technol Dept Chem & Biomol Engn Seoul South Korea Seoul Natl Univ Sci & Technol Dept Chem & Biomol Engn 232 Gongneung ro Seoul 01811 South Korea Aarhus Univ Dept Biol & Chem Engn Aarhus Denmark

A novel polybenzimidazole (PBI)-based trilayer membrane assembly is developed for application in vanadium redox flow battery (VRFB). The membrane comprises a 1 mu m thin cross-linked poly[2,2'-(p-oxydiphenylene)-5,5'-bibenzimidazole] (OPBI) sandwiched between two 20 mu m thick porous OPBI membranes (p-OPBI) without further lamination steps. The trilayer membrane demonstrates exceptional properties, such as high conductivity and low area-specific resistance (ASR) of 51 mS cm(-1) and 81 m Omega cm(2), respectively. Contact with vanadium electrolyte increases the ASR of trilayer membrane only to 158 m Omega cm(2), while that of Nafion is 193 m Omega cm(2). VO2+ permeability is 2.73 x 10(-9) cm(2) min(-1), about 150 times lower than that of Nafion NR212. In addition, the membrane has high mechanical strength and high chemical stability against VO2+. In VRFB, the combination of low resistance and low vanadium permeability results in excellent performance, revealing high Coulombic efficiency (>99%), high energy efficiency (EE; 90.8% at current density of 80 mA cm(-2)), and long-term durability. The EE is one of the best reported to date.

关键词： polybenzimidazole porous membrane proton conductivity trilayer VRFBs proton-exchange membranes CONDUCTIVITY PERFORMANCE DEGRADATION STABILITY MECHANISM SOLVENT STORAGE ENERGY

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Progress on the mechanisms of Ru-based electrocatalysts for the oxygen evolution reaction in acidic media

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Journal of Energy Chemistry 2023年第10期85卷 220-238,I0008页

作者： Yuanyuan Shi Han Wu Jiangwei Chang Zhiyong Tang Siyu Lu Green Catalysis Center and College of ChemistryZhengzhou UniversityZhengzhou 450001HenanChina CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China

Water electrolysis using proton-exchange membranes is one of the most promising technologies for carbon-neutral and sustainable energy ***,the overall efficiency of water splitting is limited by the oxygen evolution reaction(OER).Nevertheless,a trade-off between activity and stability exists for most electrocatalytic materials in strong acids and oxidizing media,and the development of efficient and stable catalytic materials has been an important focus of *** this view,gaining in-depth insights into the OER system,particularly the interactions between reaction intermediates and active sites,is significantly *** this end,this review introduces the fundamentals of the OER over Ru-based materials,including the conventional adsorbate evolution mechanism,lattice oxygen oxidation mechanism,and oxide path ***,the up-to-date progress of representative modifications for improving OER performance is further discussed with reference to specific mechanisms,such as tuning of geometric,electronic structures,incorporation of proton acceptors,and optimization of metal-oxygen ***,some valuable insights into the challenges and opportunities for OER electrocatalysts are provided with the aim to promote the development of next-generation catalysts with high activity and excellent stability.

关键词： Oxygen evolution reaction Ru-based electrocatalysts Acidic solutions Mechanism proton-exchange membranes

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