检索结果-南通市图书馆

Natural tourmaline activated peracetic acid for efficient degradation of sulfadiazine: Reaction mechanisms and catalyst reusability

引用

Progress in Natural Science:Materials International 2023年第4期33卷 458-466页

作者： Zhendong Chen Liuyang He Shitai Shen Desong Zhang Zhuqi Chen Li Wu Lie Yang Hubei Key Laboratory of Mineral Resources Processing and Environment School of Resources and Environmental Engineering Wuhan University of Technology School of Environmental Science and Engineering Huazhong University of Science and Technology Key Laboratory of Vegetation Ecology of the Ministry of Education School of Environment Northeast Normal University

Peracetic acid(PAA) has received extensive attention in the water treatment due to its high oxidation potential and low toxicity of by-products. In this study, natural non-toxic mineral tourmaline(TM) was used to activate PAA to remove sulfadiazine(SDZ). The TM/PAA system could remove 92 % SDZ in 120 min. The radical analysis confirmed the co-existence of both free radical and non-free radical degradation pathways in the TM/PAA system,indicating that singlet oxygen(1O2) and acetyl(per)oxy radicals(CH3C(O)O· and CH3C(O)OO·) were the main reactive oxygen species. The Fe2+/Fe3+ratio on the TM surface decreased during the degradation of SDZ due to Fe2+consumption. The effect of water matrix on SDZ removal indicated that Cl-, SO42-and NO3-posed little effect on SDZ removal, while CO32-inhibited SDZ removal by affecting pH. Particularly, humic acid(HA) slightly promoted SDZ removal. Ten by-products of SDZ were identified by HPLC-MS/MS, and four possible transformation pathways(SO2detachment, S–N breakage, amino acid oxidation, and hydroxylation) were *** was recycled five times and the removal of SDZ remained above 85 %, confirming its excellent *** work indicates the TM/PAA system is of great potential for the application on the organic contaminant removal.

关键词： Peracetic acid Tourmaline Singlet oxygen organic radicals

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：