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Bi^(3+)-activated dual-wavelength emitting phosphors toward effective optical thermometry

Chinese Chemical Letters 2024年第3期35卷 486-492页

作者： Yu Xue Yuqi Chen Guixian Li Weixi Xia Qinan Mao Lang Pei Meijiao Liu Liang Chu Jiasong Zhong Center of Advanced Optoelectronic Materials College of Materials and Environmental EngineeringHangzhou Dianzi UniversityHangzhou 310018China College of Electronics and Information Hangzhou Dianzi UniversityHangzhou 310018China Department of Chemistry Zhejiang Sci-Tech UniversityHangzhou 310018China

optical thermometry as an important local temperature-sensing technique,has received increasing attention in scientific and industrial areas.However,it is still a big challenge to develop luminescent materials with self-activated dual-wavelength emissions toward high-sensitivity optical thermometers.Herein,a novel ratiometric thermometric strategy of Bi^(3+)-activated dual-wavelength emission band was realized in the same lattice position with two local electronic states of La_(3)Sb_(1-x)Ta_xO_(7):Bi^(3+)(0≤x≤1.0)materials based on the different temperature-dependent emission behaviors,benefiting from the highlysensitive and regulable emission to the coordination environment of Bi^(3+).The structural and spectral results demonstrate that the emission tremendously shifted from green to blue with 68 nm and the intensity was enhanced 2.6 times.Especially,the visual dual-wavelength emitting from two emission centers was presented by increasing the Ta^(5+)substitution concentration to 20%or 25%,mainly originating from the two local electronic states around the Bi^(3+)emission center.Significantly,the dual-wavelength with different thermal-quenching performance provided high-temperature sensitivity and good discrimination signals for optical thermometry in the range between 303 and 493 K.The maximum relative sensitivity reached 2.64%/K(La_(3)Sb_(0.8)Ta_(0.2)O_(7):0.04Bi^(3+)@383 K)and 1.91%/K(La_(3)Sb_(0.75)Ta_(0.25)O_(7):0.04Bi^(3+)@388 K).This work reveals a rational design strategy of different local electronic states around the singledoping multiple emission centers towards practical applications,such as luminescence thermometry and white LED lighting.

关键词： Dual-wavelength emitting Cationic substitution Two local electronic states optical thermometry Bi^(3+)-doped phosphor

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Multi-ratio optical thermometry and energy storage characteristics of Yb^(3+)/Er^(3+)/Tm^(3+)doped BaNb_(2)O_(6)transparent glass-ceramics

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Journal of Materials Science & Technology 2023年第7期138卷 138-148页

作者： Junhao Xing Feng Luo Yaoyi Qin Xiaolu Chen Yingying Liang Zhixin Gao Fei Shang Huarui Xu Guohua Chen School of Material Science and Engineering Guangxi Key Laboratory of Information MaterialsGuilin University of Electronic TechnologyGuilin 541004China

In order to meet the needs of new materials gradually developing towards miniaturization,integration,and light weight,multifunctional BaNb_(2)O_(6):Yb^(3+)/Er^(3+)/Tm^(3+)transparent glass-ceramics were success-fully prepared by melt quenching and controllable crystallization.Its structure,luminescence,and en-ergy transmission were studied.Using the opposite temperature dependence of the Tm^(3+)emission band and the corresponding large energy level gap,a maximum relative sensitivity of 2.3%K^(-1)based on thermal coupling levels(TCLs)is obtained in a wide temperature range(298-673 K).The multi-ratio optical thermometry based on TCLs and non-TCLs is successfully realized by using the different emission bands of double emission centers,which makes it possible for self-reference optical temperature measurement modes.In addition,the transparent glass-ceramic exhibits excellent electrical properties under 700 kV cm^(-1)electric field:high discharge energy density(W_(d)=0.99 J cm^(-3)),huge instantaneous power density(225.3 MW cm^(-3)),and ultra-fast discharge rate(T_(0.9)≤15.8 ns).The prepared glass-ceramic is expected to be a new type of lead-free multifunctional photoelectric material for temperature sensors and transparent electronic devices.

关键词： Glass ceramics Luminescence optical thermometry Energy storage

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Effect of radiative loss mechanisms on FIR thermometric parameters of Nd3+-doped lithium tellurite glasses

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Journal of Rare Earths 2024年第7期42卷 1250-1257页

作者： C.Y.Morassuti A.P.L Silva L.A.O.Nunes S.M.Lima L.H.C.Andrade optical and Photothermal Spectroscopy Group (GEOF) Center for Studies in Natural Resources (CERNA)State University of Mato Grosso do Sul(UEMS) Renato Archer Information Technology Center Institute of Physics of Sao Carlos University of S?o Paulo

Nd3+-doped tellurite glasses are promising materials for thermometers based on the fluorescence intensity ratio（FIR） technique.Nevertheless,at high Nd3+concentrations,energy transfer（ET） processes such as optical reabsorption and cross-relaxation can affect the Nd3+emission,which has been little explored in the literature.Therefore,the present work investigated the use of Nd3+-doped tellurite glass(samples doped with Nd3+at 0.2 mol%,0.5 mol%,2.0 mol%,and 4.0 mol%) in fluorescence thermometers,in the temperature range from 299 to 371 K.The results indicate a strong dependence of the FIR parameters on the Nd3+concentration,due to changes in the emission band profiles caused by optical reabsorption of the Nd3+emissions and cross-relaxation processes.A decrease of the relative sensitivity of the ratio4F5/2→4I9/2/4F3/2→4I9/2is observed for samples doped with higher amounts of Nd3+.The maximum relative sensitivity at 299 K is 3.00%/K,which is the highest value among the reported Nd3+ions.

关键词： Fluorescence intensity ratio Judd-Ofelt Nd3+-doped tellurite glass optical thermometry Rare earths

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Improving luminescence and thermometric performance of Ba_(2)CaWO_(6):Er^(3+) by tri-doping with Yb^(3+) and Na^(+)

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Journal of Rare Earths 2023年第1期41卷 42-50页

作者： Lingyun Li Ziwei Zhou Fazheng Huang Senlin Peng Yantang Huang Guoqiang Wang Xinxu Li Fei-Fei Chen Chengkai Yang Xin-Xiong Li Yan Yu Key Laboratory of Advanced Materials Technology College of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China College of Chemistry Fuzhou UniversityFuzhou 350108China College of Physics and Information Engineering Fuzhou UniversityFuzhou 350108China

The Er3+doped double perovskite Ba_(2)CaWO_(6) crystal is a promising ratiometric thermometer based on the fluorescence intensity ratio(FIR) of transitions from ^(2)H_(11/2) and ^(4)S_(3/2) to the lowered ^(4)I_(15/2) level.However,the Ca^(2+) vacancy defect caused by the charge difference between rare-earth ions and the substituted alkaline-earth ions gives rise to the non-radiative probability and limits the thermal sensitivity.Here,the up-conversion luminescence and thermometric performance of Er^(3+),Yb^(3+) dopedBa_(2)CaWO_(6) are tuned by tri-doping with alkaline ions.The Ca^(2+) vacancy defect can be eliminated by the introduction of Na^(+),which occupies the Ca^(2+) site when it is doped into Ba_(2)CaWO_(6) with Er^(3+) and Yb^(3+).On the contrary,the doping of Cs^(+) into Ba_(2)CaWO_(6) with Er^(3+) and Yb^(3+) enhances the defect concentration because it occupies the site of Ba^(2+).Thus,the tri-doping of Na^(+) reduces the non-radiative probability and enhances the quantum efficiency of Er^(3+),leading to the improvement of the thermometric sensitivity of Ba_(2)CaWO_(6).As a result,we get an excellent thermometric Ba_(2)CaWO_(6):8%Yb^(3+),3.5%Er^(3+),6%Na^(+) powder with a luminescence lifetime of 515 μs and maximum thermal sensitivity(S_(r)) of 1.45%/K,which is more than three times higher than that of the BCWO:Er^(3+) powder.

关键词： Up-conversion luminescence optical thermometry Ba_(2)CaWO_(6) Er^(3+) Double perovskite Rare earths

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An optical thermometer with high sensitivity and superior signal discriminability based on dual-emitting Ce^(3+)/Eu^(2+)co-doped La5Si2BO13 thermochromic phosphor

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Journal of Rare Earths 2021年第11期39卷 1311-1319,I0001页

作者： Fuwen Liu Ying Tian Degang Deng Ming Wu Bowen Chen Liuyan Zhou Shiqing Xu Institute of Optoelectronic Materials and Devices China Jiliang UniversityHangzhou 310018China

A novel non-contact optical thermometer,qualified with high sensitivity and temperature resolution,is urgently needed for temperature measuring of micro devices,moving objects and specific severe environments.Hence,a series of dual-emitting La_(5)Si_(2)BO_(13):Ce^(3+),Eu^(2+)phosphors were synthesized.The two ions show diverse responses with the changing in temperature.The variational emissions of Ce^(3+)and Eu^(2+)can be converted to FIR(fluorescence intensity ratio)signals.The maximal absolute sensitivity Sa and relative sensitivity Sr reach up to 0.07526%/K and 3.2241%/K,respectively.It is worthy noting that the Sa and Sr possess the same variation tendency and both have high values in the low temperature region(293-373 K),showing the great temperature measuring property especially in low temperature region.The temperature sensing characteristics are superior to the results of most previous reports.The energy transfer(ET)process is certified to occur from Ce^(3+)to Eu^(2+)ions.These studies indicate that La_(5)Si_(2)BO_(13):Ce^(3+),Eu^(2+)phosphor could have a good prospect for optical thermometry.

关键词： La_(5)Si_(2)BO_(13) FIR optical thermometry Energy transfer Rare earths

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Site preference and the optical thermometry strategy by different temperature response from two sites environment of Mn2+ in K7ZnSc2B15O30

Site preference and the optical thermometry strategy by diff...

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中国稀土学会2021学术年会

作者： Ying Fu Chao Li Feng Zhang Shixiang Huang Zhangyue Wu Yuhua Wang Zhengzheng Zhang Key Lab of Photovoltaic Materials of Henan Province Henan University National & Local Joint Engineering Laboratory for optical Conversion Materials and Technology Lanzhou University

A novel optical thermometry strategy based on different temperature response from two sites environment of Mnin KZnScBO:Mnhad been reported.The color tunable Mndoped KZnScBO luminescence materials were successfully prepared,and the photoluminescence properties were studied.Using density functional theory,the electronic structure was estimated.The calculated result showed that KZnScBO was a direct-band gap material with the energy gap of 4.22 eV.Upon the excitation of UV light,the photoluminescence spectra of KZnScBO:Mnphosphors demonstrated two emission bands centered at 584 nm and 675 nm attributed to the substitution of Znand Scsites with Mnrespectively.Depending on the concentration of Mn,the emitting color can be tunable from yellow to red in the Mndoped single-phase phosphors.The temperature-dependent luminescence properties of KZnScBO:Mnwas anlysized range from 300 to 520 K.The results indicated that the thermal quenching properties of Mnat the two kinds of lattice sites are different.When Mnoccupied the position of Sc,the luminescence intensity decreased significantly with the increasing of temperature,on the contrary,when Mnoccupied the position of Zn,the luminescence intensity decreased slightly with the rise of temperature.This situation caused a significant change in the fluorescence intensity ratio of the two emission bands.Further study showed that the typical phosphor had a high relative and absolute sensitivity respectively with maximum value of 1.84%K and 0.0311 K at 520 K,and the temperature resolution is about 0.8 K.These results indicated that the single Mndoped KZnScBO materials showed a potential application for optical thermometry.

关键词： site preference photoluminescence properties multiband emission temperature response optical thermometry

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基于调控Cr^(3+)锐线发射带宽的柔性光纤温度传感器

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Science China Materials 2023年第10期66卷 4022-4029页

作者：汪玉珍金建策刘高超夏志国 School of Physics and Optoelectronics South China University of TechnologyGuangzhou 510641China State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied TechniquesGuangdong Engineering Technology Research and Development Centre of Special Optical Fiber Materials and DevicesSchool of Materials Science and EngineeringSouth China University of TechnologyGuangzhou 510641China

我们设计并制备了一种基于LiGa_(4)(MgGe)_(0.5)O_(8):Cr荧光粉变温发光特性的柔性温度传感光纤.通常来说,随着温度的升高,发光材料基质的电子-声子作用将加剧,这会导致其发射峰的半高宽(FWHM)在升温时不断加宽.在本工作中,随着LiGa_(5-... 详细信息

我们设计并制备了一种基于LiGa_(4)(MgGe)_(0.5)O_(8):Cr荧光粉变温发光特性的柔性温度传感光纤.通常来说,随着温度的升高,发光材料基质的电子-声子作用将加剧,这会导致其发射峰的半高宽(FWHM)在升温时不断加宽.在本工作中,随着LiGa_(5-x)(MgGe)_(x)O_(8):Cr中[Mg^(2+)-Ge^(4+)]化学单元成分比例的增加,荧光粉近红外发光的FWHM出现明显展宽,其外量子效率也从24.8%增加到50.0%.进一步研究发现,LiGa_(4)-(MgGe)_(0.5)O_(8):Cr纳米荧光粉的发光具有优异的热稳定性和温度传感特性,在443 K时绝对灵敏度可达7.51 cm^(-1)K^(-1),303 K下相对灵敏度为0.64%K^(-1).基于此,我们搭建了具有可重复性、高精度和优异稳定性的柔性全光纤系统,并将其用于实时监测物体的温度.本研究不仅探索了具有锐线发射的Cr^(3+)掺杂发光材料的应用,而且丰富了基于荧光材料带宽特性的光学测温新思路.

关键词： optical thermometry full width at half maximum(FWHM) flexible optical fiber structural modification

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Luminescent and thermometric properties of dual emitting Eu^(2+)/Sm^(3+) co-doped Sr_(4)La(PO_(4))_(3)O phosphor based on energy transfer

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Journal of Rare Earths 2021年第3期39卷 261-268,I0001页

作者： Fuwen Liu Degang Deng Ming Wu Bowen Chen Liuyan Zhou Shiqing Xu Institute of optoelectronic Materials and Devices China Jiliang UniversityHangzhou 310018China

Eu^(2+)/Sm^(3+)co-doped dual-emitting Sr_(4)La(PO_(4))_(3)O phosphors were synthesized through a convenient high temperature solid state reaction in reductive atmosphere.The structure,luminescence,energy transfer and temperature-dependent luminescence properties of Eu^(2+)/Sm^(3+)co-doped Sr_(4)La(PO_(4))_(3)O phosphors were researched and analyzed in detail.The blue emission of Eu^(2+)and the red emission of Sm^(3+)can work together as FIR signals.Based on the different response characteristics of these two ion emissions to temperature,Sr_(4)La(PO_(4))_(3)O:Eu^(2+)/Sm^(^(3+))phosphor achieves the relative sensitivity of0.48384%/K and a wide range of temperature measurements from room temperature to 573 K.The results reveal that the Sr_(4)La(PO_(4))_(3)O:Eu^(2+)/Sm^(3+)phosphor has application prospect in the field of high temperature optical thermometry.The energy transfer mechanism is proved to be the dipole-dipole interaction between Eu^(2+)and Sm^(3+)ions.

关键词： Sr_(4)La(PO_(4))_(3)O FIR optical thermometry Energy transfer Rare earths

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Luminescence properties of Eu3+doped YBO3 for temperature sensing

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Journal of Rare Earths 2017年第4期35卷 356-360页

作者：赵路曹中民韦先涛尹民陈永虎 Department of Physics University of Science and Technology of China Hefel 230026China

YBO3：2 at.% Eu3＋ was prepared by the solid state reaction and its temperature dependent luminescence was investigated for possible applications in temperature sensing. Phase composition of this material was confirmed by X-ray powder diffraction analysis and excitation and emission spectra were also provided. Under excitation of 355 nm, the fluorescence originating from 5D0 and 5D1 states varied as the temperature rose in a region from 333 to 773 K. The fluorescence intensity ratio （FIR） of SD0 and 5D1 was investigated which increased significantly with the rise of temperature. The maximal relative sensitivity in the whole temperature range was 1.8% K-1（at 333 K）. The results recommended YBO3：Eu3＋ as a new material of the FIR method for non-contact optical thermometry.

关键词： FIR optical thermometry solid state reaction intensity ratio rare earths

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