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Bioresource Upgrade for Sustainable Energy,Environment,and Biomedicine

nano-Micro Letters 2023年第3期15卷 48-97页

作者： Fanghua Li Yiwei Li KSNovoselov Feng Liang Jiashen Meng Shih‑Hsin Ho Tong Zhao Hui Zhou Awais Ahmad Yinlong Zhu Liangxing Hu Dongxiao Ji Litao Jia Rui Liu Seeram Ramakrishna Xingcai Zhang Center for nanofibers and nanotechnology National University of SingaporeSingapore 119260Singapore State Key Laboratory of Urban Water Resource and Environment Harbin Institute of TechnologyHarbin 150090People’s Republic of China School of Engineering Massachusetts Institute of TechnologyCambridgeMA 02139USA John A Paulson School of Engineering and Applied Sciences Harvard UniversityCambridgeMA 02138USA The Key Laboratory for Biomedical Photonics of MOE at Wuhan National Laboratory for Optoelectronics–Department of Biomedical Engineering College of Life Science and TechnologyHuazhong University of Science and TechnologyWuhanHubei 430074People’s Republic of China Centre for Advanced 2D Materials National University of SingaporeSingapore 117546Singapore School of Physics and Astronomy The University of ManchesterManchester M139PLUK Department of Anesthesia Critical Care and Pain MedicineMassachusetts General Hospital and Harvard Medical SchoolBostonMA 02114USA Department of Energy and Power Engineering Tsinghua UniversityBeijing 100084People’s Republic of China Departamento de Quimica Organica Universidad de CordobaEdificio Marie Curie(C‑3)Ctra Nnal IV‑AKm 39614014 CordobaSpain Department of Chemical Engineering Monash UniversityClaytonVIC 3800Australia School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore

We conceptualize bioresource upgrade for sustainable energy,environment,and biomedicine with a focus on circular economy,sustainability,and carbon neutrality using high availability and low utilization biomass(HALUB).We acme energy-efficient technologies for sustainable energy and material recovery and applications.The technologies of thermochemical conversion(TC),biochemical conversion(BC),electrochemical conversion(EC),and photochemical conversion(PTC)are summarized for HALUB.Microalgal biomass could contribute to a biofuel HHV of 35.72 MJ Kg^(-1)and total benefit of 749$/ton biomass via TC.Specific surface area of biochar reached 3000 m^(2)g^(-1)via pyrolytic carbonization of waste bean dregs.Lignocellulosic biomass can be effectively converted into bio-stimulants and biofertilizers via BC with a high conversion efficiency of more than 90%.Besides,lignocellulosic biomass can contribute to a current density of 672 mA m^(-2)via EC.Bioresource can be 100%selectively synthesized via electrocatalysis through EC and PTC.Machine learning,techno-economic analysis,and life cycle analysis are essential to various upgrading approaches of HALUB.Sustainable biomaterials,sustainable living materials and technologies for biomedical and multifunctional applications like nano-catalysis,microfluidic and micro/nanomotors beyond are also highlighted.New techniques and systems for the complete conversion and utilization of HALUB for new energy and materials are further discussed.

关键词： High availability low utilization biomass(HALUB) Circular economy Machine learning Energy-efficient conversion nano-catalysis

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High-loading, ultrafine Ni nanoparticles dispersed on porous hollow carbon nanospheres for fast (de)hydrogenation kinetics of MgH_(2)

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Journal of Magnesium and Alloys 2022年第12期10卷 3354-3366页

作者： Shun Wang Mingxia Gao Zhihao Yao Kaicheng Xian Meihong Wu Yongfeng Liu Wenping Sun Hongge Pan State Key Laboratory of Silicon Materials Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province&School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027P.R.China

Magnesium hydride(MgH2) is one of the most promising hydrogen storage materials for practical application due to its favorable reversibility, low cost and environmental benign;however, it suffers from high dehydrogenation temperature and slow sorption kinetics.Exploring proper catalysts with high and sustainable activity is extremely desired for substantially improving the hydrogen storage properties of MgH2. In this work, a composite catalyst with high-loading of ultrafine Ni nanoparticles(NPs) uniformly dispersed on porous hollow carbon nanospheres is developed, which shows superior catalytic activity towards the de-/hydrogenation of MgH2. With an addition of 5wt% of the composite, which contains 90 wt% Ni NPs, the onset and peak dehydrogenation temperatures of MgH2are lowered to 190 and 242 ℃, respectively. 6.2 wt% H2is rapidly released within 30 min at 250 ℃. The amount of H2that the dehydrogenation product can absorb at a low temperature of 150 ℃ in only 250 s is very close to the initial dehydrogenation value. A dehydrogenation capacity of 6.4wt% remains after 50 cycles at a moderate cyclic regime, corresponding to a capacity retention of 94.1%. The Ni NPs are highly active,reacting with MgH2and forming nanosized Mg2Ni/Mg2NiH4. They act as catalysts during hydrogen sorption cycling, and maintain a high dispersibility with the help of the dispersive role of the carbon substrate, leading to sustainably catalytic activity. The present work provides new insight into designing stable and highly active catalysts for promoting the(de)hydrogenation kinetics of MgH2.

关键词： Hydrogen storage materials nano-catalysis Magnesium hydride Porous hollow carbon nanospheres Ni nanoparticles

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Factors Affecting the Catalytic Performance of nano-catalysts

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Chinese Journal of Chemistry 2022年第4期40卷 515-523页

作者： Hongling Yang Yue Wu Zewen Zhuang Yang Li Chen Chen Department of Chemistry Tsinghua UniversityBeijing 100084China

Comprehensive Summary nano-catalysis plays a vital role in the industrially chemical transformations.The increasingly severe energy crisis and environmental issues spur scientists to exploit novel nano-catalysts in diverse fields.It is essential to understand the fundamental physicochemical properties of nano-catalysts to develop efficient systems,whose design can be subsequently precisely tuned at the atomic level.In this review,we summarize several key factors affecting the catalytic activity of nano-catalysts,including structure,composition,size,and interface,providing guidance for the atomic level control of high-efficient nano-catalysts.Finally,we present a brief conclusion and some thoughts on nano-catalysis.

关键词： Heterogeneous catalysis nano-catalysis Single-atom catalysis Structure-activity relationships Interfaces

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