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Studies on the molecular chain Conformation Stability of Aminated Konjac Glucomannan

Chinese Journal of Structural Chemistry 2013年第12期32卷 1845-1853页

作者： WANG Li-Xia WEN Cheng-Rong WU Jing LIN Hai-Dong HU Shu-Guo PANG Jie College of Food Science and Technology Fujian Agriculture and Forestry University Department of Biology Science and Technology Minnan Normal University

Konjac glucomannan （KGM） was aminated by 2-chloroethyl-amine （CEA） as reagent so as to study the influence of concentration of CEA （based on the amount of KGM）, concentration of NaOH, reaction time and temperature on the extent of amination. And the molecular simulation technology was adopted to analyze the conformation stability of aminate （AKGM）. The results indicate that when the amount of CEA is higher, the extent of amination is higher. The optimum concentration of NaOH, reaction time and temperature are 10% NaOH, 70 ℃ and 45 rain, respectively. IR shows KGM is successfully aminated. The conformation of AKGM is in a random clew-like shape.

关键词： konjac glucomannan （KGM） aminated modification aminated konjacglucomannan （AKGM） molecular chain conformation stability

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Effects of Irradiation on the Structure-activity Relationship of Konjac Glucomannan molecular chain Membrane

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Chinese Journal of Structural Chemistry 2012年第6期31卷 857-866页

作者：吴春华彭述辉温成荣王丽霞熊波刘雅楠范琳琳姚闽娜庞杰 College of Food Science Fujian Agriculture and Forestry University Department of Food Science Guangzhou City Polytechnic

To know the effects of irradiation on the konjac glucomannan （KGM） molecular chain membrane, KGM membrane solution was treated with the irradiation dose of 0-20 kGy in this study, and the structure and properties of KGM membrane were analyzed with Infrared spectrum, Raman spectrum, X-ray, SEM scanning and so on. The results revealed that the effects of different irradiation doses on the KGM molecular chain structure were different. Higher irradiation dose （20 kGy） resulted in partial damage against KGM membrane crystal structure, and there was no obvious change for the amorphous structure; with membrane property test, the tensile strength of KGM membrane gradually increased with the increase of irradiation dose and its elongation at break reduced, but these changes were not significant, WVP value reduced; with SEM, the membrane surface treated with irradiation was smoother even than the membrane without treatment. In addition, when increasing the irradiation dose, membrane surface became more even, and arrangement was more orderly and compact. KGM membrane nrooerties, and it is an ideal Irradiation modification could effectively improve the modification method.

关键词： KGM molecular chain irradiation modification membrane structure mechanicalproperty

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Transverse relaxation characteristic and stress relaxation model considering molecular chains of HTPB coating based on pre-strained thermal aging

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Defence Technology（防务技术） 2021年第3期17卷 821-828页

作者： Yong-qiang Du Jian Zheng Gui-bo Yu Jian-zhuang Zhi Shijiazhuang Campus Army Engineering UniversityShijiazhuang050003China Intelligent Manufacturing Institute Hebei College of Industry and TechnologyShijiazhuang050003China

In order to accurately describe the transverse relaxation characteristic and stress relaxation modulus of HTPB coating during pre-strain thermal aging process,a one month thermal aging test was carried out at70C with pre-strain of 0%,3%,6%and 9%,respectively.The low-field1 H NMR and stress relaxation modulus tests were carried out for HTPB coating at different aging stages.The stress relaxation model considering the molecular chains was proposed according to the changes of crosslinking chain and dangling chain of HTPB coating during pre-strain aging.The results showed that with the increase of aging time,the decay rate of transverse relaxation curve became faster,the transverse relaxation time decreased,the value of combined parameter q Mrl increased,the proportion of crosslinking chain decreased,while the proportion of dangling chain increased.Moreover,the stress relaxation modulus increased,the crosslinking network structure of HTPB coating became denser and the degree of crosslinking increased.At the initial aging stage,the pre-strain will destroy the crosslinking network structure of HTPB coating to a certain extent.With the increase of aging time,the effect of pre-strain will gradually weaken and the influence of aging on materials will gradually increase.The correlations between the stress relaxation model considering the molecular chains and the test results were more than 0.9950,which can accurately describe the stress relaxation modulus of HTPB coating during the pre-strain thermal aging process.

关键词： HTPB Pre-strain aging Transverse relaxation characteristic molecular chain Stress relaxation model

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