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CuO-nanoparticles modified carbon paste electrode for square wave voltammetric determination of lidocaine: Comparing classical and Box–Behnken optimization methodologies

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Chinese Chemical Letters 2016年第6期27卷 837-842页

作者： Nadereh Rahbar Zahra Ramezani Jamalaldin Ghanavati Nanotechnology Research Center Faculty of Pharmacy Ahvaz Jundishapur University of Medical Sciences Medicinal Chemistry Department Ahvaz Jundishapur University of Medical Sciences

In this research, copper oxide nanoparticles modified carbon paste electrode was developed for the voltammetric determination of lidocaine. The square wave voltammogram of lidocaine solution showed a well-defined peak between ＋0.5 and ＋1.5 V. Instrumental and chemical parameters influencing voltammetric response were optimized by both one at a time and Box–Behnken model of response surface methodology. The results revealed that there was no significant difference between two methods of optimization. The linear range was 1–2500 μmol L^-1（Ip= 0.11 C（LH）＋ 17.38, R^2= 0.999）. The LOD and LOQ based on three and ten times of the signal to noise（S/N） were 0.39 and 1.3 μmol L^-1（n = 10）,respectively. The precision of the method was assessed for 10 replicate square wave voltammetry（SWV）determinations each of 0.05, 0.5 and 1 μmol L^-1 of lidocaine showing relative standard deviations 4.1%,3.7% and 2.1%, respectively. The reliability of the proposed method was established by application of the method for the determination of lidocaine in two pharmaceutical preparations, namely injection and gel.

关键词： Square wave voltammetry CuO nanoparticles Lidocaine modified carbon paste electrode

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Electrochemical determination of vitamin C in the presence of uric acid by a novel TiO_2 nanoparticles modified carbon paste electrode

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Chinese Chemical Letters 2010年第12期21卷 1471-1474页

作者： Mohammad Mazloum-Ardakani Mohammad Ali Sheikh-Mohseni Hadi Beitollahi Ali Benvidi Hossein Naeimi Department of Chemistry Faculty of ScienceYazd UniversityYazd89195-741I.R.Iran Department of Organic Chemistry Faculty of ChemistryUniversity of KashanKashanI.R.Iran

The electrochemical behavior of vitamin C（ascorbic acid or AA） is investigated on the surface of a carbon-paste electrode modified with TiO2 nanoparticles and 2,2＇-（1,2 butanediylbis（nitriloethylidyne））-bis-hydroquinone（BBNBH）.The prepared modified electrode showed an efficient catalytic role in the electrochemical oxidation of AA,leading to remarkable decrease in oxidation overpotential and enhancement of the kinetics of the electrode *** modified electrode exhibits well-separated oxidation peaks for AA and uric acid（UA）.The modified electrode is successfully applied for the accurate determination of AA in pharmaceutical preparations.

关键词： Ascorbic acid Uric acid TiO2 nanoparticles Electrocatalysis modified carbon paste electrode

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