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methylene blue intercalated vanadium oxide with synergistic energy storage mechanism for highly efficient aqueous zinc ion batteries

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Journal of Energy Chemistry 2023年第2期77卷 269-279,I0007页

作者： Yunxiao Tong Ying Zang Senda Su Yinggui Zhang Junzhuo Fang Yongqing Yang Xiaoman Li Xiang Wu Fuming Chen Jianhua Hou Min Luo State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering School of Chemistry and Chemical EngineeringNingxia UniversityYinchuan 750021NingxiaChina School of Materials Science and Engineering Shenyang University of TechnologyShenyang 110870LiaoningChina Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials School of Physics and Telecommunication EngineeringSouth China Normal UniversityGuangzhou 510006GuangdongChina College of Environment Science and Engineering Yangzhou UniversityYangzhou 225009JiangsuChina

With the rise of aqueous multivalent rechargeable batteries,inorganic-organic hybrid cathodes have attracted more and more attention due to the complement of each other’s advantages.Herein,a strategy of designing hybrid cathode is adopted for high efficient aqueous zinc-ion batteries(AZIBs).methylene blue(MB)intercalated vanadium oxide(HVO-MB)was synthesized through sol-gel and ion exchange method.Compared with other organic-inorganic intercalation cathode,not only can the MB intercalation enlarge the HVO interlayer spacing to improve ion mobility,but also provide coordination reactions with the Zn^(2+)to enhance the intrinsic electrochemical reaction kinetics of the hybrid electrode.As a key component for the cathode of AZIBs,HVO-MB contributes a specific capacity of 418 mA h g^(-1) at 0.1 A g^(-1),high rate capability(243 mA h g^(-1) at 5 A g^(-1))and extraordinary stability(88%of capacity retention after 2000cycles at a high current density of 5 A g^(-1))in 3 M Zn(CF_(3)SO_(3))_(2) aqueous electrolyte.The electrochemical kinetics reveals HVO-MB characterized with large pseudocapacitance charge storage behavior due to the fast ion migration provided by the coordination reaction and expanded interlayer distance.Furthermore,a mixed energy storage mechanism involving Zn^(2+)insertion and coordination reaction is confirmed by various ex-situ characterization.Thus,this work opens up a new path for constructing the high performance cathode of AZIBs through organic-inorganic hybridization.

关键词： Synergistic energy storage mechanism Aqueous zinc-ion batteries Vanadium oxides Pre-intercalation strategy methylene blue

Synergetic degradation of methylene blue through photocatalysis and Fenton reaction on two-dimensional molybdenite-Fe

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Journal of Environmental Sciences 2022年第1期34卷 11-23页

作者： Chang Liu Bingqiao Yang Jianxin Chen Feifei Jia Shaoxian Song Hubei Key Laboratory of Mineral Resources Processing and Environment Wuhan University of TechnologyWuhan 430070China Xingfa School of Mining Engineering Wuhan Institute of TechnologyWuhan 430073China School of Resources and Environmental Engineering Wuhan University of TechnologyWuhan 430070China

The greatest problem in conventional Fenton reaction is the slow production of ROS(reactive oxygen species)because of the inefficient Fe^(3+)/Fe^(2+) conversion.Based on the extraordinary photo-response property of two-dimensional molybdenite(2DM),photogenerated electrons can be easy separated to accelerate the regeneration of Fe^(2+).In this work,Fe^(2+)-anchored 2DM(2DM-Fe)was prepared and used as a heterogeneous Fenton catalyst to investigate the degradation efficiency to methylene blue(MB)in the presence of light.According to experimental results,2DM-Fe exhibited extraordinary catalytic activity in MB elimination,which ascribed to the synergetic effect of photogenerated carriers and anchored Fe^(2+) to H_(2)O_(2) activation.In addition,2DM-Fe showed nearly 100%degradation efficiency to MB within 5 cycles with slight leaching amount of Mo and Fe ions,implying the strong stability and reusability in H_(2)O_(2) system.Furthermore,the influences of H_(2)O_(2) and 2DM-Fe dosages,pH values as well as the degradation efficiency to different dyes were also investigated.According to quenching experiments and EPR(electron paramagnetic resonance)test,the degradation mechanism of MB mainly ascribed to the oxidation of HO•and•O_(2)^(−).This finding provides a novel strategy to design rational Fenton catalyst and has great significance to water remediation in the future.

关键词： Two-dimensional molybdenite Fenton Photocatalysis methylene blue

Silicalite-1 zeolite encapsulated Fe nanocatalyst for Fenton-like degradation of methylene blue

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Chinese Journal of Chemical Engineering 2023年第1期53卷 251-259页

作者： Hongwei Guo Linyuan Chen Xueying Zhang Huanhao Chen Yan Shao State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 211816China School of Environmental Science and Engineering Nanjing Tech UniversityNanjing 211816China

Encapsulation of Fe nanoparticles in zeolite is a promising way to significantly improve the catalytic activity and stability of Fe-based catalysts during the degradation process of organic pollutants.Herein,Fe nanocatalysts were encapsulated into silicalite-1(S-1)zeolite by using a ligand-protected method(with dicyandiamide(DCD)as a organic ligand)under direct hydrothermal synthesis condition.High-resolution transmission electron microscopy(HRTEM)results confirmed the high dispersion of Fe nanocatalysts which were successfully encapsulated within the voids among the primary particles of the S-1 zeolite.The developed S-1 zeolite encapsulated Fe nanocatalyst(Fe@S-1)exhibited significantly improved catalytic activity and reusability in the catalytic degradation process of methylene blue(MB).Specifically,the developed Fe0.021@S-1 catalyst showed high catalytic degradation activity,giving a high MB degradation efficiency of 100%in 30 min,outperformed the conventional impregnated catalyst(Fe/S-1).Moreover,the Fe@S-1 catalyst afforded an outstanding stability,showing only ca.7.9%activity loss after five cycling tests,while the Fe/S-1 catalyst presented a significantly activity loss of 50.9%after only three cycles.Notably,the encapsulation strategy enabled a relatively lower Fe loading in the Fe@S-1 catalyst in comparison with that of the Fe/S-1 catalyst,i.e.,0.35%vs.0.81%(mass).Radical scavenging experiments along with electron spin resonance(ESR)measurements confirmed that the major role ofOH in the MB degradation process.Specifically,Fe@S-1 catalyst with high molar ratio of[Fe(DCD)]Cl3 is beneficial to form Fe complexes/nanoclusters in the voids(which has large pore size of 1–2 nm)among the primary particles of the zeolite,and thus improving the diffusion and accessibility of reactants to Fe active sites,and thus exhibiting a relatively higher degradation efficiency.This work demonstrates that zeolite-encapsulated Fe nanocatalysts present potential applications in the advanced oxidation of wastewater treatment.

关键词： Zeolite Encapsulation Fe nanocatalyst Degradation methylene blue

Understanding association between methylene blue dye and biosorbent: Palmyrah sprout casing in adsorption process in aqueous phase

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Water Science and Engineering 2023年第2期16卷 154-164页

作者： D.M.N.H.Jayasuriya Kannan Nadarajah Department of Agricultural Engineering Faculty of AgricultureUniversity of JaffnaAriviyal NagarKilinochchi 44000Sri Lanka

Water pollution caused by industrial dyes has become a severe problem in the modern world. Biosorbents can be used in an eco-friendly manner to remove industrial dyes. In this study, five biosorbents were selected: palmyrah sprout casing (PSC), manioc peel, lime peel, king coconut husk, and coconut kernel. Batch adsorption experiments were conducted to identify the best biosorbent with the highest ability to adsorb methylene blue (MB) from wastewater. The detailed mechanisms of PSC used in the adsorptive removal of MB in aqueous phase were investigated. Of the five biosorbents, PSC exhibited the best removal performance with an adsorption capacity at equilibrium (qe) of 27.67 mg/g. The qe values of lime peel, king coconut husk, manioc peel, and coconut kernel were 24.25 mg/g, 15.29 mg/g, 10.84 mg/g, and 7.06 mg/g, respectively. To explain the mechanisms of MB adsorption with the selected biosorbents, the Fourier transform infrared (FTIR) spectrometry and X-ray diffraction (XRD) analyses were performed to characterize functional properties, and isotherm, kinetic, rate-limiting, and thermodynamic analyses were conducted. The FTIR analysis revealed that different biosorbents had different functional properties on their adsorptive surfaces. The FTIR and XRD results obtained before and after MB adsorption with PSC indicated that the surface functional groups of carbonyl and hydroxyl actively participated in the removal process. According to the isotherm analysis, monolayer adsorption was observed with the Langmuir model with a determination coefficient of 0.998. The duration to reach the maximum adsorption capacity for MB adsorption with PSC was 120 min, and the adsorption process was exothermic due to the negative enthalpy change (-9.950 kJ/mol). Moreover, the boundary layer thickness and intraparticle diffusion were the rate-limiting factors in the adsorption process. As a new biosorbent for MB adsorption, PSC could be used in activated carbon production to enhance the performance of dye removal.

关键词： Biosorbents Isotherm Kinetics methylene blue Rate-limiting factor Thermodynamics

Dual MOFs composites:MIL-53 coated with amorphous UiO-66 for enhanced photocatalytic oxidation of tetracycline and methylene blue

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Nano Research 2023年第5期16卷 6160-6166页

作者： Xuesheng Liu Xiangyu Zhao Hong Meng Junsu Jin Beijing Key Laboratory of Membrane Science and Technology Beijing University of Chemical TechnologyBeijing 100029China State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of ChemistryXinjiang UniversityUrumqi 830046China

In this work,we proposed a novel strategy for the photocatalytic degradation of the target pollutants tetracycline(TC)and methylene blue(MB)using core–shell dual metal-organic frameworks(MOFs)composites.A series of mesoporous composites MIL-53@UiO-66 were synthesized by solvent-thermal synthesis via coating UiO-66 on the surface of MIL-53.The results show that under the same degradation conditions,only 30 and 15 min are needed to degrade 93%of TC and 96%of MB in the photo-Fenton reaction system,respectively.The amorphous shell layer brings stronger adsorption to the catalyst.MIL-53@UiO-66 composites with equalizing Fermi level are formed to promote photon absorption and electron transfer.Meanwhile,the MIL-53@UiO-66 composites with excellent stability will be a promising catalyst for environmental remediation.

关键词： dual metal-organic frameworks(MOFs) core–shell structure tetracycline methylene blue photocatalysis

Investigation of photoelectrocatalytic degradation mechanism of methylene blue by a-Fe_(2)O_(3) nanorods array

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Chinese Journal of Chemical Engineering 2023年第5期57卷 162-172页

作者： Yaqiao Liu Shuozhen Hu Xinsheng Zhang Shigang Sun State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

Efficiently and thoroughly degrading organic dyes in wastewater is of great importance and challenge.Herein,vertically oriented mesoporous a-Fe_(2)O_(3)nanorods array(a-Fe_(2)O_(3)-NA)is directly grown on fluorine-doped tin oxide(FTO)glass and employed as the photoanode for photoelectrocatalytic degradation of methylene blue simulated dye wastewater.The Ovsites on the a-Fe_(2)O_(3)-NA surface are the active sites for methylene blue(MB)adsorption.Electrons transfer from the adsorbed MB to Fe-O is detected.Compared with electrocatalytic and photocatalytic degradation processes,the photoelectrocatalytic(PEC)process exhibited the best degrading performance and the largest kinetic constant.Hydroxyl,superoxide free radicals,and photo-generated holes play a jointly leading role in the PEC degradation.A possible degrading pathway is suggested by liquid chromatography-mass spectroscopy analysis.This work demonstrates that photoelectrocatalysis by a-Fe_(2)O_(3)-NA has a remarkable superiority over photocatalysis and electrocatalysis in MB degradation.The in-depth investigation of photoelectrocatalytic degradation mechanism in this study is meaningful for organic wastewater treatment.

关键词： a-Fe_(2)O_(3)nanorods array methylene blue Photoelectrocatalytic degradation mechanism Free radicals Photo-generated holes

Porous polyurethane hydrogels incorporated with CMC for eliminating methylene blue from water

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International Journal of Smart and Nano Materials 2023年第1期14卷 57-76页

作者： Li Wang Qing Yang Yong Yang Kun Luo Ruqing Bai Peicong Zhang Department of Biomedical Engineering School of Big Health and Intelligent EngineeringChengdu Medical CollegeChengduChina College of Materials Chemistry&Chemical EngineeringChengdu University of TechnologySichuanP.R.China State Key Laboratory of Mechanical Transmission Chongqing University400044ChongqingChina College of Materials Chemistry&Chemical EngineeringChengdu University of Technology610059SichuanP.R.China

Here,a series of polyurethane porous hydrogels(PUF-s)loaded with different sodium carboxymethyl cellulose(CMC)were successfully prepared by one-step foaming method.The physio-chemical prop-erties and morphologies were characterized.The effects of CMC content,adsorbent dosage,temperature,pH value and other fac-tors on the adsorption of methylene blue(MB)dye in water by CMC-PUF-s were also investigated through static adsorption experi-ments.The results showed that CMC-PUF-10 had excellent adsorp-tion performance for MB solution with removal rate of 81.47%,and the maximum adsorption capacity was 27.5 mg/g.In addition,the study of adsorption kinetics and adsorption isotherms showed that the adsorption of MB by CMC-PUF was more consistent with Langmuir isotherm adsorption model and pseudo second-order kinetic model.The adsorption thermodynamics study suggested that the adsorption process of MB by CMC-PUF-10 was sponta-neous and exothermic at room temperature.The results of cyclic adsorption experiment demonstrated that the removal rate of MB reached above 70%after five cycles,indicating the foams with excellent recyclability.Finally,a low-cost,environmentally friendly and recyclable MB adsorbent was synthesized in this study.As polyurethane foam was synthesized by one-step foaming method,this adsorbent can be prepared on site in practical application and reduce the transportation cost.

关键词： Carboxymethyl cellulose polyurethane foam hydrogel methylene blue adsorption

Preparation of Kenaf Biochar and Its Adsorption Properties for methylene blue

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Journal of Renewable Materials 2022年第12期10卷 3391-3404页

作者： Xin Wan Zhigang Xia Xiaoli Yang Chenfeng Zhou Yuanming Zhang Haoxi Ben Guangting Han Wei Jiang College of Textiles Qingdao UniversityQingdao260000 China State Key Laboratory of Bio Fibers and Eco-Textiles Qingdao UniversityQingdao266071China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan430000China Key Laboratory of Textile Fiber and Products(Wuhan Textile University) Ministry of EducationWuhan430200China

The toxic dyestuff's from printing and dyeing wastewater have caused serious damages to the ecological environ-ment,thus exploring effective methods to remove them having become a key topic.Here,a series of biochar sam-ples were synthesized form kenaf to adsorb methylene blue(MB),which was acted as the dye representative for the test of adsorption capacity due to the presence of abundant double bond and aroma tic heterocyclic ring.By tuning the raw materials and pyrolysis temperature,a super adsorption capacity about 164.21 mg·g^(-1) was obtained over the biochar that pyrolyzed at 700℃ with the kenaf fiber as raw material Through the physical adsorption,elemental analysis,FTIR spectra and NH_(3)-TPD,it was found the high surface area and pore volume of biochar played a key role in the adsorption of MB,and the acidic sites would also assist the adsorption process.Besides,the adsorption kinetic model was ftted and calculated,implying the MB physically adsorbed on the bio-char rapidly and then occurred chemical adsorption on the acidic sites.In addition,through KBC700 recycling experiments,it was found that kenaf biochar had a good binding force to MB,which effectively avoided secondary pollution.This work provides important insights for the adsorption mechanism of MB by biochar,also offers some guidance for the further synthesis of biochar from various biomass.

关键词： Kenaf biochar pyrolysis temperature adsorption methylene blue kinetic analysis

How to examine anastomotic integrity intraoperatively in totally laparoscopic radical gastrectomy? methylene blue testing prevents technical defect-related anastomotic leaks

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World Journal of Gastrointestinal Surgery 2022年第4期14卷 315-328页

作者： Chun Deng Yang Liu Zhen-Yu Zhang Heng-Duo Qi Zhi Guo Xu Zhao Xiao-Jun Li Department of General Surgery Shaanxi Provincial People's HospitalXi'an 710068Shaanxi ProvinceChina

BACKGROUND Intraoperative methylene blue testing(IMBT),air leak testing,or endoscopy is used to assess the anastomotic integrity of esophagojejunostomy during open total gastrectomy for gastric cancer.Totally laparoscopic radical gastrectomy has been widely used to treat gastric cancer in the last few decades.However,reports on testing anastomotic integrity in totally laparoscopic radical gastrectomy are limited.AIM To explore the effects of IMBT on the incidence of postoperative anastomotic leaks(PALs)and identify the risk factors for PALs in totally laparoscopic radical gastrectomy.METHODS From January 2017 to December 2019,patients who underwent totally laparoscopic radical gastrectomy at the Shaanxi Provincial People's Hospital were retrospectively analyzed.According to whether or not they experienced an IMBT,the patients were divided into an IMBT group and a control group.If the IMBT was positive,an intraoperative suture was required to reinforce the anastomosis.The difference in the incidence of PALs was compared,and the risk factors were investigated.RESULTS This study consisted of 513 patients,211 in the IMBT group and 302 in the control group.Positive IMBT was shown in seven patients(3.3%)in the IMBT group,and no PAL occurred in these patients after suture reinforcement.Multivariate analysis showed that risk factors for predicting positive IMBT were body mass index(BMI)>25 kg/m2(hazard ratio[HR]=8.357,P=0.009),operation time>4 h(HR=55.881,P=0.002),and insufficient surgical experience(HR=15.286,P=0.010).Moreover,15 patients(2.9%)developed PALs in 513 patients,and the rates of PALs were significantly lower in the IMBT group than in the control group[2 of 211 patients(0.9%)vs 13 of 302 patients(4.3%),P=0.0026].Further analysis demonstrated that preoperative complications(HR=13.128,P=0.017),totally laparoscopic total gastrectomy(HR=9.075,P=0.043),and neoadjuvant chemotherapy(HR=7.150,P=0.008)were independent risk factors for PALs.CONCLUSION IMBT is an effective method to evaluate the integrity of anastomosis

关键词： Anastomotic leak Gastric neoplasms Totally laparoscopic radical gastrectomy methylene blue Risk factors