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Effects of Na_(2)CO_(3)on reduction mechanism and kinetics of iron during deep reduction of ilmenite concentrate

Journal of Iron and Steel Research International 2023年第3期30卷 419-428页

作者： Xiao-dong Lv You-ling Hou Yun-tao Xin Wei Lv Xue-wei Lv Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and New Materials Chongqing UniversityChongqing 400044China College of Materials Science and Engineering Chongqing UniversityChongqing 400044China School of Metallurgy Northeastern UniversityShenyang 110819LiaoningChina

High-quality upgraded titanium slag obtained through semi-molten reduction with the addition of Na_(2)CO_(3)is important for the fluidizing chlorination process to produce TiO_(2)*** key is the effect of Na_(2)CO_(3)on the reduction behavior of ***,the effects of Na_(2)CO_(3)on reduction mechanism and kinetics of iron during deep reduction of ilmenite concentrate were *** results indicated that the metallization ratio of the reduced sample increased with increasing temperature,time,and dose of Na_(2)CO_(3).The addition of Na_(2)CO_(3)significantly accelerated the reduction of iron in the ilmenite concentrate and promoted the growth of iron ***,the addition of Na_(2)CO_(3)produced sodium iron titanates;thus,the metallization ratio of the sample decreased with an increase in the temperature and time when the temperature was above 1200℃and the time was more than 30 *** the doses of Na_(2)CO_(3)were 0,3,and 6 wt.%,the reduction of iron was controlled by the interfacial chemical reaction,both the interfacial chemical reaction and diffusion,and diffusion,respectively,and the apparent activation energies were 134.91,64.89,and 120.82 kJ/mol,respectively.

关键词： Ilmenite concentrate Sodium carbonate metallization ratio Reduction mechanism Kinetics

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