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Outstanding strength and conductivity of metallic glass composites with multiscale configuration

Rare Metals 2023年第9期42卷 3099-3113页

作者： Wei-Zong Bao Jie Chen Jun-Zhi Li Bo-Hua Yu Chu-Yuan Liu Ping Jiang Zu-Jia Liu Kai-Tao Hu Dmitri V.Louzguine-Luzgin Guo-Qiang Xie School of Materials Science and Engineering Harbin Institute of Technology(Shenzhen)Shenzhen518055China Advanced Institute for Materials Research(WPI-AIMR) Tohoku UniversitySendai980-8577Japan MathAM-OIL National Institute of Advanced Industrial Science and Technology(AIST)Sendai980-8577Japan State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin150001China

Cu-based composites with multiscale configuration for electrical contact applications are fabricated via a ball milling(BM)-spark plasma sintering(SPS)-aging process.Synergistic strengthening of the Cu alloy matrix by micro-scale metallic glass particles and nanoscale intracrystalline precipitation phases is realized.The annealing technique achieves the decomposition of solute atoms in the Cu alloy,ensuring the excellent electrical properties of the matrix conductive network.The composite with multiscale configuration achieves an outstanding combination of ultimate compressive strength of(1114±15)MPa and electrical conductivity of 33.0%±1.1%International Annealed Copper Standard(IACS)after annealing at 400.C for 10.0 h.Investigation of the strengthening and conductivity mechanisms suggests that the precipitation of the Cr-rich phase within the matrix crystals is a critical contributor to the concerted enhancement of strength and conductivity.In addition,the positive role of nanocrystals precipitated at the edges of metallic glass particles on the interfacial bonding of composites is addressed.

关键词： metallic glass composites Multiscale configuration Strength Conductivity

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Mechanical behavior and deformation mechanism of shape memory bulk metallic glass composites synthesized by powder metallurgy

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Journal of Materials Science & Technology 2022年第19期114卷 42-54页

作者： Tianbing He Tiwen Lu Daniel Sopu Xiaoliang Han Haizhou Lu Kornelius Nielsch Jürgen Eckert Nevaf Ciftci Volker Uhlenwinkel Konrad Kosiba Sergio Scudino Leibniz IFW Dresden Institute for Complex MaterialsHelmholtzstraße 2001069 DresdenGermany Guangdong Key Laboratory for Advanced metallic Materials Processing South China University of TechnologyGuangzhou 510640China Erich Schmid Institute of Materials Science Austrian Academy of SciencesJahnstraße 12Leoben A-8700Austria Leibniz IFW Dresden Institute for Metallic MaterialsHelmholtzstraße 2001069 DresdenGermany TU Dresden Institute of Materials Science01062 DresdenGermany TU Dresden Institute of Applied Physics01062 DresdenGermany Department Materials Physics Montanuniversität LeobenJahnstraße 12A-8700 LeobenAustria Leibniz Institute for Materials Engineering IWT 28359 BremenGermany University of Bremen Faculty of Production Engineering28359 BremenGermany

The synthesis of martensitic or shape-memory bulk metallic glass composites(BMGCs)via solidification of the glass-forming melts requires the meticulous selection of the chemical composition and the proper choice of the processing parameters in order to ensure that the glassy matrix coexists with the desired amount of austenitic phase.Unfortunately,a relatively limited number of such systems,where austenite and glassy matrix coexist over a wide range of compositions,is available.Here,we study the effective-ness of powder metallurgy as an alternative to solidification for the synthesis of shape memory BMGCs.Zr_(48)Cu_(36)Al_(8)Ag_(8)matrix composites with different volume fractions of Ni_(50.6)Ti_(49.4)are fabricated using hot pressing and their microstructure,mechanical properties and deformation mechanism are investigated employing experiments and simulations.The results demonstrate that shape-memory BMGCs with tun-able microstructures and properties can be synthesized by hot pressing.The phase stability of the glass and austenitic components across a wide range of compositions allows us to examine fundamental as-pects in the field of shape memory BMGCs,including the effect of the confining stress on the martensitic transformation exerted by the glassy matrix,the contribution of each phase to the plasticity and the mechanism responsible for shear band formation.The present method gives a virtually infinite choice among the possible combinations of glassy matrices and shape memory phases,expanding the range of accessible shape memory BMGCs to systems where the glassy and austenitic phases do not form simul-taneously using the solidification route.

关键词： metallic glass composites Niti alloys Mechanical properties Shear bands Martensitic transformation

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