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Plasma Science and Technology 2024年第6期26卷 14-21页

作者：李娜张立松张小楠宫丽悦羌建兵梅显秀 Key Laboratory of Materials Modification by Laser Ion and Electron BeamsMinistry of EducationDalian University of TechnologyDalian 116024People’s Republic of China School of Science Dalian Jiaotong UniversityDalian 116028People’s Republic of China

In this paper,high-energy Ne ions were used to irradiate Zr_(63.5)Cu_(23)Al_(9)Fe_(4.5) metallic glass(MG)and crystalline W to investigate their difference in mechanical response after irradiation.The results showed that with the irradiation dose increased,the tensile micro-strain increased,nano-hardness increased from 7.11 GPa to 7.90 GPa and 8.62 GPa,Young’s modulus increased,and H3/E2 increased which indicating that the plastic deformability decreased in crystalline W.Under the same irradiation conditions,the Zr_(63.5)Cu_(23)Al_(9)Fe_(4.5) MG still maintained the amorphous structure and became more disordered despite the longer range and stronger displacement damage of Ne ions in Zr_(63.5)Cu_(23)Al_(9)Fe_(4.5) MG than in crystalline W.Unlike the irradiation hardening and embrittlement behavior of crystalline W,Zr_(63.5)Cu_(23)Al_(9)Fe_(4.5) MG showed the gradual decrease in hardness from 6.02 GPa to 5.89 GPa and 5.50 GPa,the decrease in modulus and the increase in plastic deformability with the increasing dose.Possibly,the irradiation softening and toughening phenomenon of Zr_(63.5)Cu_(23)Al_(9)Fe_(4.5) MG could provide new ideas for the design of nuclear materials.

关键词： heavy ions irradiation displacement damage metallic glass crystalline W mechanical property

Unveiling the early stage evolution of local atomic structures in the crystallization process of a metallic glass

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Chinese Physics B 2024年第3期33卷 58-64页

作者：马琳杨晓东杨锋周鑫嘉武振伟 Institute of Nonequilibrium Systems School of Systems ScienceBeijing Normal UniversityBeijing 100875China

The early stage evolution of local atomic structures in a multicomponent metallic glass during its crystallization process has been investigated via molecular dynamics simulation.It is found that the initial thermal stability and earliest stage evolution of the local atomic clusters show no strong correlation with their initial short-range orders,and this leads to an observation of a novel symmetry convergence phenomenon,which can be understood as an atomic structure manifestation of the ergodicity.Furthermore,in our system we have quantitatively proved that the crucial factor for the thermal stability against crystallization exhibited by the metallic glass is not the total amount of icosahedral clusters,but the degree of global connectivity among them.

关键词： metallic glass crystallization molecular dynamics simulation local atomic clusters

High-Density Nanowells Formation in Ultrafast Laser-Irradiated Thin Film metallic glass

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Nano-Micro Letters 2022年第6期14卷 308-322页

作者： Mathilde Prudent Djafar Iabbaden Florent Bourquard Stéphanie Reynaud Yaya Lefkir Alejandro Borroto Jean-François Pierson Florence Garrelie Jean-Philippe Colombier Univ Lyon UJM-Saint-EtienneCNRSInstitute of Optics Graduate SchoolLaboratoire Hubert CurienUMR CNRS 551642023 St-EtienneFrance Universitéde Lorraine CNRSIJL54000 NancyFrance

We present an effective approach for fabricating nanowell arrays in a one-step laser process with promising applications for the storage and detection of chemical or biological elements.Biocompatible thin films of metallic glasses are manufactured with a selected composition of Zr_(65)Cu_(35),known to exhibit remarkable mechanical properties and glass forming ability.Dense nanowell arrays spontaneously form in the ultrafast laser irradiation spot with dimensions down to 20 nm.The flared shape observed by transmission electron microscopy is ideal to ensure chemical or biological material immobilization into the nanowells.This also indicates that the localization of the cavitation-induced nanopores can be tuned by the density and size of the initial nanometric interstice from the columnar structure of films deposited by magnetron sputtering.In addition to the topographic functionalization,the laser-irradiated amorphous material exhibits structural changes analyzed by spectroscopic techniques at the nanoscale such as energy-dispersive X-ray spectroscopy and electron energy loss spectroscopy.Results reveal structural changes consisting of nanocrystals of monoclinic zirconia that grow within the amorphous matrix.The mechanism is driven by local oxidation process catalyzed by extreme temperature and pressure conditions estimated by an atomistic simulation of the laser-induced nanowell formation.

关键词： Nanowell Nanoripple metallic glass Surface functionalization Femtosecond laser

Influence of oscillation strain on the dynamic mechanical relaxation of a La-based metallic glass

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Science China(Technological Sciences) 2023年第11期66卷 3309-3316页

作者： LIANG ShuYi ZHANG LangTing WANG YunJiang PINEDA E QIAO JiChao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi’an 710072China State Key Laboratory of Nonlinear Mechanics Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China Department of Physics Institute of Energy TechnologiesUniversitat Politècnica de Catalunya–BarcelonaTechBarcelona 08019Spain Innovation Center NPU-ChongqingChongqing 401135China

Dynamic mechanical relaxation processes,particularly secondary relaxation processes,are closely related to the mechanical and physical properties of metallic glasses.Here the effect of oscillation strain amplitude on the secondary relaxation of a typical Labased metallic glass was studied using the dynamic mechanical analysis method.The apparent activation energy of theβrelaxation is shown to increase with the oscillation strain amplitude.When it changes from 0.02%to 0.16%,the activation energy increases from 0.73 to 0.96 eV.Simultaneously,the intensity of theβrelaxation shifts toward high temperature.Additionally,the apparentβrelaxation is found to be sensitive to the physical aging below the glass transition temperature.The findings suggest a correlation between the inelastic deformation and the relaxation behavior of amorphous metals.

关键词： metallic glass dynamic mechanical analysis internal friction βrelaxation oscillation amplitude

The anelastic origin of mechanical cycling induced rejuvenation in the metallic glass

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Science China(Physics,Mechanics & Astronomy) 2023年第8期66卷 93-100页

作者： Langting Zhang Yunjiang Wang Yong Yang Jichao Qiao School of Mechanics CivilEngineering and ArchitectureNorthwestern Polytechnical UniversityXi'an 70072China State Key Laboratory of Nonlinear Mechanics Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China Department of Mechanical Engineering College of EngineeringCity University of Hong KongHong Kong 999077China Department of Materials Science and Engineering College of EngineeringCity University of Hong KongHong Kong 999077China Innovation Center NPU-ChongqingChongqing 401135China

Mechanical cycling is one of the effective methods to rejuvenate metallic glasses(MGs)and improve their mechanical properties.The anelastic origin of the rejuvenation by mechanical cycling in a La_(30)Ce_(30)Ni_(10)Al_(20)Co_(10) MG was investigated via differential scanning calorimetry(DSC)and dynamic mechanical analysis(DMA).We demonstrate that mechanical cycling promotes the activation of flow defects with short relaxation times,leading to anelastic strains and therefore considerable energy storage,which manifests itself as larger relaxation enthalpy on the DSC curves of MGs.However,the MGs release the excess relaxation enthalpy caused by anelastic strain with time,thus suppressing atomic mobility and elevating β relaxation activation energies.The strategy of mechanical cycling at small strains,as demonstrated in the current work,can expand the energy states of MGs over a wide range of relaxation enthalpies.

关键词： metallic glass mechanical cycling rejuvenation anelastic strain structural heterogeneity

Yield strength of“brittle”metallic glass

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Journal of Materials Science & Technology 2023年第18期149卷 247-254页

作者： Ruitao Qu Cynthia A.Volkert Zhefeng Zhang Feng Liu State Key Laboratory of Solidification Processing School of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Institute of Materials Physics University of GöttingenFriedrich-Hund-Platz 137077 GöttingenGermany Institute of Metal Research Chinese Academy of SciencesShenyang 110016China

“Brittle”metallic glass(MG)usually fractures catastrophically in a shattering mode under macroscopic compression,because cleavage cracking of splitting that originates from extrinsic flaws dominates the failure of such alloys,which brings challenges for studying yield strength.Here we show that the plastic yielding behavior in a brittle Fe-based MG can be successfully activated by decreasing the sample size to micrometer scale to avoid the possible large tensile stress concentrators.The yield strength was found to be at least 33%higher than the fracture strength measured with bulk samples for the present brittle MG.The results further demonstrate that the critical stresses for shear band initiation and propagation are size-independent,while the required stress for cleavage cracking increases with decreasing sample size.The competition of thermodynamic driving forces between the two processes of shear banding and cleavage cracking hence leads to the size-induced brittle-to ductile-transition.These findings clarify the physical nature of the strength of“brittle”MG,implying the great opportunity for using high-strength brittle MGs in devices with small dimensions.

关键词： metallic glass Yield strength Fracture Shear band Cracking

Enhanced pitting corrosion resistance of a Zr-based metallic glass by ultraviolet light irradiation

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Journal of Iron and Steel Research(International) 2023年第8期30卷 1642-1649页

作者： Z.Chen D.P.Wang S.Wang Y.X.Geng Y.X.Guo Y.C.Wu Z.G.Liu Y.Y.Zhang Y.X.Wang School of Materials Science and Engineering Jiangsu University of Science and Technology.Zhenjiang 212003JiangsuChina School of Mechanical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003JiangsuChina

The influence of ultraviolet light irradiation on the pitting corrosion performance of a Zr_(2)Ni metallic glass was examined using electrochemical methods and immersion test in 0.05 mol/L NaCl solution.From the results of potentiostatic polarization,the pitting potential of the ultraviolet light-irradiated sample shifted positively with a value of~300 mV,revealing the enhanced pitting corrosion resistance of the samples.The corrosion morphology after the immersion test also demonstrated lower degree of corrosion damage and improved pitting resistance of the sample with ultraviolet light irradiation.X-ray photoelectron spectroscopy analysis revealed more zirconium enrichment in the passive film and no chloride ions adsorption for the samples with ultraviolet irradiation,accounting for the suppression of the pit generation and growth.Our findings indicate that ultraviolet light irradiation improves the pitting corrosion resistance of the Zr-based metallic glasses,which are promising structural materials to be used in corrosion environments with high ultraviolet irradiation.

关键词： metallic glass Pitting-Corrosion Ultraviolet light irradiation Passive film

Wettability and Interfacial Reactions Between metallic glass Melts and Cu/Mo Used as Roller Materials for Twin-Roll Casting

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Acta Metallurgica Sinica(English Letters) 2022年第7期35卷 1221-1230页

作者： Yi Wu Long Zhang Hongwei Zhang Huameng Fu Zhengwang Zhu Hong Li Aimin Wang Haifeng Zhang Shi-changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China

Twin-roll casting has been recently revealed to be an effi cient technique to produce rejuvenated metallic glass(MG)strips.Due to the high melting point and high hardness,pure Mo is considered as a good roller material as pure Cu.However,the wettability and interfacial reactions between MG melts and Cu or Mo remain largely unknown.In this work,a series of sessile droplet wetting experiments are designed to investigate the wettability and reactions between Zr_(41.2)Ti_(13.8)Cu_(12.5)Ni_(10)Be_(22.5)(Vit.1)or(Zr 0.401 Ti_(0.133)Cu_(0.118)Ni_(0.101)Be_(0.247))_(99)Nb_(1)(Nb1)MG melts and Cu/Mo substrates at temperatures of 1073,1123 and 1173 K.It is found that the wettability and interfacial reactions of the Vit.1 and Nb1 MG melts on the Cu substrates are very similar.The equilibrium contact angles are~30°at 1073 K and~25°-27°at 1123 K.The MG melts completely spread out on the Cu substrates at 1173 K.Cu substrates are slightly dissolved in the MG melts event at 1073 K,and a transitional reaction layer exists between the droplet and the Cu substrate.In comparison,the Vit.1 MG melt exhibits a much improved wettability on the Mo substrate.The equilibrium contact angle of the Vit.1/Mo is only 6°at 1073 K and 5°at 1123 K.No signifi cant diff usion of Mo into the droplet occurs even at 1173 K with a holding time of~30 min.The interfaces of the Vit.1/Mo samples are sharp,and no interfacial reaction layers form.These fi ndings indicate that pure Mo can be a good roller material for twin-roll casting at high temperatures,and the Mo-made rollers are expected of capability to produce MG strips with good quality.

关键词： metallic glass Wettability Interfacial reaction Twin-roll casting Roller material

Aging and rejuvenation during high-temperature deformation in a metallic glass

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Science China(Physics,Mechanics & Astronomy) 2022年第10期65卷 93-100页

作者： Langting Zhang Yunjiang Wang Yong Yang Jichao Qiao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical University(NPU)Xi’an 710072China State Key Laboratory of Nonlinear Mechanics Institute of MechanicsChinese Academy of SciencesBeijing 100190China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China Department of Mechanical Engineering College of EngineeringCity University of Hong KongHong Kong 999077China Department of Materials Science and Engineering College of EngineeringCity University of Hong KongHong Kong 999077China Innovation Center NPU-ChongqingChongqing 401135China

High-temperature deformation has been demonstrated as an effective measure to rejuvenate and optimize the mechanical properties of metallic glasses(MGs).Clarifying the competition between aging and rejuvenation during high-temperature deformation is helpful in rejuvenating MGs accurately.Signatures of aging and rejuvenation in a La_(30)Ce_(30)Ni_(10)Al_(20)Co_(10)MG were investigated via high-temperature deformation and mechanical relaxation.The coupling of thermal history,aging,and mechanical disordering determines the transient deformation and the structural state of MGs.The stress overshoot and anelastic deformation induce structural rejuvenation,increasing the concentration of defects and erasing thermal history.Therefore,the eventually steady-state condition is dependent on ambient temperature and strain rate instead of the initial structure.Furthermore,the one-to-one relationship between defect concentration and strain rate clarifies the structural nature of rejuvenation in amorphous materials.Such a relationship also contributes toward a comprehensive understanding of the structural rejuvenation behavior in amorphous materials.

关键词： metallic glass aging rejuvenation homogenous flow free volume

Unexpected creep behavior in a rejuvenated metallic glass

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Journal of Materials Science & Technology 2023年第32期163卷 140-149页

作者： J.P.Wu Y.Lin F.H.Duan Q.Chen H.T.Wang N.Li J.L.Wen J.Pan L.Liu Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China State Key Laboratory of Material Processing and Die&Mould Technology and School of Materials Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China Laboratory of Nanomaterials&Nanomechanics Department of Mechanical EngineeringCity University of Hong KongHong KongChina Wuhan National High Magnetic Field Center Huazhong University of Science and TechnologyWuhan 430074China Shenzhen Polytechnic Shenzhen 518055China

Rejuvenation,bringing metallic glasses(MGs)to the younger and higher energy states,provides an alternative avenue to explore the interplay between the property and microstructures of MGs.In this study,the creep behavior of the Zr_(69.5)Cu_(12)Ni_(11)Al_(7.5)MGs was experimentally examined by controlling the energy state in terms of structural rejuvenation and thermal annealing.It is found that compared to the as-cast counterpart,the annealed MG at a lower energy state exhibits a higher hardness,a smaller displacement,and a lower creep rate due to the decreased free volume and the inhibited activation of the shear transformation zone.Conversely,the rejuvenated MG at a high energy state displays lower hardness and increased free volume content,yet it demonstrates superior creep resistance compared to its as-cast counterpart,which deviates from conventional understanding.This unexpected phenomenon occurs as the initial high-content free volume annihilates during creep,and strain hardening takes precedence over strain softening as the prevailing process during creep deformation,leading to a superior creep performance in extremely rejuvenated MGs.

关键词： metallic glass Energy state Rejuvenation Creep Strain-hardening