检索结果-南通市图书馆

Efficient and recyclable palladium enriched magnetic nanocatalyst for reduction of toxic environmental pollutants

Journal of Environmental Sciences 2021年第3期33卷 189-204页

作者： Manjunatha Kempasiddaiah Vishal Kandathil Ramesh B.Dateer Mahiuddin Baidya Shivaputra A.Patil Siddappa A.Patil Centre for Nano and Material Sciences Jain UniversityJain Global CampusKanakapuraRamanagaramBangalore 562112India Department of Chemistry Indian Institute of Technology MadrasChennai 600036Tamil NaduIndia Pharmaceutical Sciences Department College of PharmacyRosalind Franklin University of Medicine and ScienceNorth ChicagoIL 60064USA

In this paper,highly stable,powerful,and recyclable magnetic nanoparticles tethered Nheterocyclic carbene-palladium(Ⅱ)((CH_(3))_(3)-NHC-Pd@Fe_(3)O_(4))as magnetic nanocatalyst was successfully synthesized from a simplistic multistep synthesis under aerobic conditions through easily available low-cost *** synthesized(CH_(3))_(3)-NHC-Pd@Fe_(3)O_(4) magnetic nanocatalyst was characterized from various analytical tools and catalytic potential of the(CH_(3))_(3)-NHC-Pd@Fe_3 O_4 magnetic nanocatalyst was studied for the catalytic reduction of toxic 4-nitrophenol(4-NP),hexavalent chromium(Cr(Ⅵ)),Methylene Blue(MB)and Methyl Orange(MO)at room temperature in aqueous ***-Visible spectroscopy was employed to monitor the reduction ***(CH_(3))_(3)-NHC-Pd@Fe_(3)O_(4) magnetic nanocatalyst exhibited excellent catalytic activity for the reduction of toxic environmental ***,(CH_(3))_(3)-NHC-Pd@Fe_(3)O_(4) magnetic nanocatalyst could be easily and rapidly separated from the reaction mixture with the help of an external magnet and recycled minimum five times in reduction of 4-NP,MB,MO and four times in Cr(Ⅵ)without significant loss of catalytic potential and remains stable even after reuse.

关键词： magnetic nanocatalyst Wastewater treatment Chemical kinetics Catalyst recyclability

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A magnetic-void-porous MnFe_(2)O_(4)/carbon microspheres nano-catalyst for catalytic ozonation:Preparation,performance and mechanism

引用

Environmental Science and Ecotechnology 2021年第3期7卷 35-47页

作者： Xiaoguang Jin Changyong Wu Xiangmiao Tian Panxin Wang Yuexi Zhou Jiane Zuo State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing100084China State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing100012China Research Center of Environmental Pollution Control Engineering Technology Chinese Research Academy of Environment SciencesBeijing100012China

Wastewater treatment is essential to guarantee human health and ecological *** ozonation with nanocatalysts is a widely studied and efficient treatment ***,this method has always been limited by nanocatalysts disadvantages such as easily loss,difficult to separate and reuse,and catalytic ability decay caused by aggregation,which could cause severe resources waste and potential risk to human health and *** remedy these challenges,a magnetic-void-porous MnFe_(2)O_(4)/carbon microsphere shell nanocatalyst(CMS-MnFe_(2)O_(4))was successfully synthesized using renewable natural *** separation test showed CMS-MnFe_(2)O_(4) was rapidly separated within 2 min under an external magnetic *** catalytic ozonation of oxalic acid(OA),CMS-MnFe_(2)O_(4) showed efficient and stable catalytic efficiency,reaching a maximum total organic carbon removal efficiency of 96.59% and maintained a 93.88% efficiency after 4 *** stable catalytic efficiency was due to the supporting effects of the carbon microsphere shell,which significantly enhanced CMS-MnFe_(2)O_(4) chemical stability and reduced the metal ions leaching to 10-20% of MnFe_(2)O_(4) through electron *** explore the catalytic mechanism,radical experiments were conducted and a new degradation pathway of OA involving superoxide anions rather than hydroxyl radicals was ***,this study suggests that an efficient,recyclable,stable,and durable catalyst for catalytic ozonation could be prepared.

关键词： Catalytic ozonation magnetic nanocatalyst Separation recycling Catalytic mechanism Metal leaching

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：