检索结果-南通市图书馆

Self-assemble construction of hetero-structured Co(OH)_(2)/mxene aerogel toward Li-S batteries as a self-supported host and bifunctional catalyst

引用

Rare Metals 2024年第11期43卷 5652-5663页

作者： Yang Liu Ke Tan Sen Liu Xu Zhang Mao-Qiang Shen Xue-Sen Liu Xin-Yue Gao Lin-Rui Hou Chang-Zhou Yuan School of Materials Science&Engineering University of JinanJinan 250022China

The shuttling diffusion of polysulfides is a bottleneck that seriously limits the performance of Li-S *** construction of sulfur cathodes with reliable trapping ability of polysulfides is the key to overcome such ***,a hierarchical porous architecture,i.e.,Co(OH)_(2)sheets bonded Ti_3C_(2)T_x mxene aerogel(Co(OH)_(2)/MXA),is constructed via a facile selfassembled approach and used as an efficient free-standing polysulfides *** interconnected three-dimensional(3D)porous network with void space and strong interfacial interaction not only enables high sulfur loading but facilitates fast ion and electron *** and theoretical results confirm the hetero-framework exhibits outstanding immobilization and conversion ability for polysulfides due to its polar surface and bifunctional catalytic activities toward both formation and decomposition of *** optimized Co(OH)_(2)/MXA cathode delivers excellent rate capability(407 mAh·g^(-1)at 5C)with a sulfur loading of 2.7 mg·cm^(-2),and ultra-stable cycling performance as an extremely small capacity decay of~0.005%per cycle within 1700 cycles at 1C is achieved with a high sulfur loading of 6.7 mg·cm^(-2).More significantly,our design structural/componential methodology here promises the mxene-based aerogel electrodes for LiS batteries and beyond.

关键词： mxene aerogel Co(OH)_(2)sheets Hetero-architecture Self-standing hosts Li-S batteries

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Ultralight and superelastic mxene/reduced graphene oxide aerogels for electromagnetic interference shielding

引用

Nano Research 2025年第1期18卷 1-9页

作者： Xinfeng Zhou Yang Dai Guoyao Yue Yiman Zhang Lulu Li Zhong-Zhen Yu Peng Min Hao-Bin Zhang 21 State Key Laboratory of Organic-Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China Beijing Key Laboratory of Advanced Functional Polymer Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China Present address:BOE Technology Innovation Center BOE Technology Group Co.Ltd.Beijing 100176China Xi’an Modern Chemistry Research Institute Xi’an 710065China

Lightweight aerogels feature multifunctionality and a high porosity,yet accompanied with poor structure recovery under large strain *** this work,we develop an air bubble-ice crystal dual template and annealing strategy to integrate low density and high resilience for the conductive transition metal carbides/nitrides(mxene)composite *** air bubbles and ice crystals synergistically exclude the nanosheets to the gas-liquid interfaces,thereby constructing unique Y-shaped junctions and robust *** annealing process greatly enhances the interlayer *** external load,the Yshaped structures prevent the stress concentration at the junctions by transferring the forces to the skeleton for maintaining structural *** addition,the wrinkled and thick cell walls,together with the enhanced interlayer interactions,endow the aerogel with exceptional structural stability and *** a result,the mxene/reduced graphene oxide(RGO)composite aerogels exhibit superelasticity with reversible compressive strains of up to 95%.In addition,the electron bridging effect of the RGO sheets affords the aerogel to deliver excellent electromagnetic interference shielding performance,as high as 46.3 dB at 2.5 ***,the remarkable reshapeability of the aerogels allows for precise regulation of structure and performance(33.5-75.1 dB)by a simple wetting compression *** summary,this work offers helpful inspirations for developing lightweight and superelasticity aerogels for extensive applications.

关键词： lightweight superelasticity mxene aerogel electromagnetic interference shielding reshapeability

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：