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Facile preparation of core-shell Si@Li4Ti5O12 nanocomposite as large-capacity lithium-ion battery anode

Journal of Energy Chemistry 2020年第1期29卷 89-98,I0004页

作者： Mengjing Liu Hanyang Gao Guoxin Hu Kunxu Zhu Hao Huang School of Mechanical and Power Engineering Shanghai Jiao Tong UniversityShanghai 200240China School of Mechanical Engineering Hangzhou Dianzi UniversityHangzhou 310018ZhejiangChina Shanghai Marine Diesel Engine Research Institute Shanghai 200090China

As a promising alternative anode material,silicon(Si)presents a larger capacity than the commercial anode to achieve large capacity lithium-ion batteries.However,the application of pure Si as anode is hampered by limitations such as volume expansion,low conductivity and unstable solid electrolyte interphase.To break through these limitations,the core-shell Si@Li4Ti5O12nanocomposite,which was prepared via in-situ self-assembly reaction and decompressive boiling fast concentration method,was proposed in this work.This anode combines the advantages of nano-sized Si particle and pure Li4Ti5O12(LTO)coating layer,improving the performance of the lithium-ion batteries.The Si@Li4Ti5O12 anode displays a high initial discharge/charge specific capacity of 1756/1383 m Ahg^-1 at 500 mAg^-1(representing high initial coulombic efficiency of 78.8%),a large rate capability(specific capacity of 620 mAhg^-1 at4000 mAg^-1),an outstanding cycling stability(reversible specific capacity of 883 mAhg^-1 after 150 cycles)and a low volume expansion rate(only 3.3% after 150 cycles).Moreover,the synthesis process shows the merits of efficiency,simplicity,and economy,providing a reliable method to fabricate large capacity Si@Li4Ti5O12nanocomposite anode materials for practical lithium-ion batteries.

关键词： Si@Li4Ti5O12 composites Core-shell nanoparticles In-situ self-assembly Decompressive boiling concentration lithium-ion battery anode

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Molten salt synthesis,morphology modulation,and lithiation mechanism of high entropy oxide for robust lithium storage

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Journal of Energy Chemistry 2023年第11期86卷 536-545,I0011页

作者： Xuefeng Liu Honghong Wang Long Dong Kezhuo Li Haijun Zhang Quanli Jia Shaowei Zhang Wen Lei The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina Henan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou 450052HenanChina College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUK Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China

High entropy oxides(HEOs)with ideal element tunability and enticing entropy-driven stability have exhibited unprecedented application potential in electrochemical lithium storage.However,the general control of dimension and morphology remains a major challenge.Here,scalable HEO morphology modulation is implemented through a salt-assisted strategy,which is achieved by regulating the solubility of reactants and the selective adsorption of salt ions on specific crystal planes.The electrochemical properties,lithiation mechanism,and structure evolution of composition-and morphology-dependent HEO anode are examined in detail.More importantly,the potential advantages of HEOs as electrode materials are evaluated from both theoretical and experimental aspects.Benefiting from the high oxygen vacancy concentration,narrow band gap,and structure durability induced by the multi-element synergy,HEO anode delivers desirable reversible capacity and reaction kinetics.In particular,Mg is evidenced to serve as a structural sustainer that significantly inhibits the volume expansion and retains the rock salt lattice.These new perspectives are expected to open a window of opportunity to compositionally/morphologi cally engineer high-performance HEO electrodes.

关键词： High-entropy oxide lithium-ion battery anode Molten salt Morphology modulation Structure stability

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Establishment of green graphite industry:Graphite from biomass and its various applications

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SusMat 2023年第3期3卷 402-415页

作者： Ziyi Shi Shule Wang Yanghao Jin Lingfeng Zhao Shiwei Chen Hanmin Yang Yuxiao Cui Rikard Svanberg Chuchu Tang Jianchun Jiang Weihong Yang PäGJösson Tong Han Department of Materials Science and Engineering KTH Royal Institute of TechnologyStockholmSweden Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and MaterialsCollege of Chemical EngineeringNanjing Forestry UniversityNanjingChina University of Michigan-Shanghai Jiao Tong University Joint Institute Shanghai Jiao Tong UniversityShanghaiChina Department of Fiber and Polymer Technology KTH Royal Institute of TechnologyStockholmSweden Faculty of Creative Arts University of MalayaKuala LumpurMalaysia

Resource-and energy-efficient biomass exploitation for green graphite production is one of the most effective strategies for satisfying graphite demand while minimizing energy consumption and carbon emissions.This study investigated green graphite production from biomass waste and its applications to establish a green graphite industry.Biomass pyrolysis and catalytic graphitization of biochar were studied first to produce green graphite.The optimized green graphite exhibited a reversible capacity of 264 mA h/g and 97%capacity retention over 100 cycles in a half-cell.Green graphite electrodes with a resistivity lower than 5μΩm were fabricated by using organic fraction bio-oil as a green binder.Other green graphite applications,including printing,conductive printing,pencils,and refractories,were also achieved.The overall process of graphite anode and electrode synthesis from biomass waste and short-rotation energy crops was modeled.Approx.95 kg of battery graphite or 109 kg of metallurgical graphite electrodes can be produced per ton of biomass with low primary energy consumption and carbon footprint.Prominently,the modeling result and life cycle assessment demonstrated that,for the production of battery graphite from biomass waste,net-negative-CO_(2)emissions(−0.57 kg CO_(2)-eq/kg graphite powders)with net-negative-primary energy consumption(−28.31 MJ/kg graphite powders)was achieved.

关键词： biomass green graphite lithium-ion battery anode metallurgical graphite electrode negative emission

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