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Anhydride type film-forming electrolyte additives for high-temperature lini0.6co0.2mn0.2o2//graphite pouch cells

Progress in Natural Science:Materials International 2023年第3期33卷 320-327页

作者： Anwei Zhang Chengyun Wang Weizhen Fan Jingwei Zhao Yanping Huo Xijun Xu GAC Automotive Research &Development Center Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Materials Science and Engineering South China University of Technology Research and Development Center Guangzhou Tinci Materials Technology Co. Ltd. college of Chemical Engineering and Light Industry Guangdong University of Technology

lini0.6co0.2mn0.2o2//graphite full cell, due to its high energy density as the most promising candidate for power batteries received increased attention, but the severe capacity loss under high-temperature conditions prevents their large-scale application. Here, glutaric anhydride(GA) and succinic anhydride(SA) as electrolyte additives are investigated to overcome the high-temperature problem of lini0.6co0.2mn0.2o2//graphite cells. Due to the unique film-forming features and high-temperature stability, the cells containing 0.5% GA and 0.5% SA can retain capacity retention of 91.2% and 92.4% stored at 60°C for 15 days, corresponding to a negligible capacity loss of 4.6 and 0.8 m Ah g-1after 200 cycles, respectively. In addition, the lifespans of cells under 25°C are also significantly extended by introducing GA and SA into the electrolytes. Electrochemical and spectroscopic techniques results indicate the full cell capacity loss is predominantly caused by the unstable anode solid electrolyte interphase(SEI) layer and a stable SEI film derived from GA and SA is formed on the graphite electrode *** SEI film can effectively inhibit the consumption of electrolytes and enhance the high-temperature performance of cells. This work paves a way for moderating high energy density cells’ work under high-temperature operation by developing special anodic film-forming electrolyte additives.

关键词： Anhydride-based Electrolyte additives Film-forming lini0.6co0.2mn0.2o2//graphite High-temperature performance

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