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Influence of pH on the Formation, Composition and Protectiveness of Fluoride Conversion Film Deposited on AZ31 Magnesium Alloy in kf solution

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金属学报:英文版 2023年第9期36卷 1397-1408页

作者： Liping Wu Chen Liu Jie Wei Junhua Dong Lin Zhao Chao Li Wei Ke Yiqing Chen Changgang Wang Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang110016China State Key Laboratory of Metal Material for Marine Equipment and Application Anshan114009China

In deaerated 0.1 M kf solution at pH 5, pH 7.5 and pH 9, fluoride films were deposited on AZ31 magnesium (Mg) alloy at − 1.4 V vs saturated calomel electrode (SCE). The morphology, phase composition, elemental and compositional depth distribution of different fluoride films and their influences on the corrosion resistance of AZ31 Mg alloy were explored in detail. The results indicated that the films deposited at weak acidic and nearly neutral pH consisted of two layers with amorphous Mg(OH)_(2) and MgF_(2) as the inner layer, and Mg(OH)_(2), MgF_(2) and KMgF_(3) crystals the outer layer. The film deposited at alkaline pH was a monolayer structure consisting of amorphous Mg(OH)_(2) as the major constitute and MgF_(2) as the minor constitute. The protectiveness of fluoride film was intimately related to its composition and structure. The content and crystal regularity of KMgF_(3) were the two main factors influencing the protectiveness of fluoride film. The fluoride film deposited at pH 7.5 offered the best protection to AZ31 Mg alloy.

关键词： Magnesium alloy Potentiostatic deposition Fluoride film kf solution

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Effect of applied potential on the microstructure, composition and corrosion resistance evolution of fluoride conversion film on AZ31 magnesium alloy

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Journal of Materials Science & Technology 2018年第11期34卷 2084-2090页

作者： Liping Wu Changgang Wang Durga Bhakta Pokharel Ini-Ibehe Nabuk Etim Lin Zhao Junhua Dong Wei Ke Nan Chen Environmental Corrosion Center Institute of Metal ResearchChinese Academy of Sciences

AZ31 magnesium（Mg） alloy was potentiostatic polarized in 0.1 M deaerated kf solution with pH 7.5 from-0.4 V to-1.4 V with an interval of-0.2 V. The polarization process was described by the potentiostatic current decay. The resultant film was analyzed by scanning electron microscopy（SEM）, X-ray diffraction（XRD）, X-ray photoelectron spectroscopy（XPS） and electrochemical impedance spectroscopy（EIS）. The results demonstrated that the deposited film included a Mg（OH）2/MgF2 containing inner layer and a Mg（OH）-2/MgF2/KMgF3 comprising outer layer. The high polarized potential produced high content of MgF2 but low content of KMgF3 and thin film. Conversely, the low polarized potential produced small content of MgF2 but high content of KMgF3 and thick film. The optimal corrosion resistance of the deposited film was obtained at-1.4 V, which was closely related with the content of MgF2 and KMgF3 and the film thickness.

关键词： Potentiostatic Fluoride conversion film AZ33 magnesium alloy kf solution Corrosion

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