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Gas release characteristics during carbonization of iron coke hot briquette and influence of heating rate

Journal of iron and Steel Research International 2023年第11期30卷 2163-2172页

作者： Zi-yu Wang Dong Han Zheng-gen Liu Man-sheng Chu Yong-jie Zhang Li-feng Zhang Ji-wei Bao Ming-yu Wang School of Metallurgy Northeastern UniversityShenyang110819LiaoningChina Engineering Research Center of Frontier Technologies for Low-Carbon Steelmaking(Ministry of Education) Shenyang110819LiaoningChina Liaoning Province Engineering Research Center for Technologies of Low-Carbon Steelmaking Shenyang110819LiaoningChina

The release characteristics of CH_(4),H_(2),CO and CO_(2) from iron coke hot briquette(ICHB)during carbonization were *** results show that compared with briquette without iron ore,Fe_(3)O_(4) can inhibit the release rate of H2 and promote the production of CO and CO_(2).In addition,when the heating rate increases from 3 to 7℃/min,the release rates of CH4 and H2 increase,while the release rates of CO and CO_(2) first increase and then *** carbonization process of ICHB was segmented,and corresponding kinetic analysis was carried *** results show that the activation energy of StageⅡand StageⅣis higher in the carbonization process of ICHB,and the active pyrolysis of coal and the reduction of iron ore occur in these two *** addition,the effect of heating rate on the kinetic parameters of ICHB carbonization process was *** was found that when the heating rate increased,the reaction activation energy of StageⅣdecreased first and then increased,which was consistent with the release law of CO and CO_(2).The analysis showed that the increase in heating rate leads to more reactions at higher temperatures,resulting in an increase in the release rate of some *** addition,thermal hysteresis can also cause some processes to fail to fully react at the end of *** is also found that the apparent activation energy and preexponential factor have kinetic compensation effect during the car-bonization of ICHB.

关键词： iron coke hot briquette Carbonization Gas release characteristic Heating rate Kinetics

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Non-isothermal reduction process analysis of iron-bearing burden with charging iron coke hot briquette under simulated blast furnace conditions

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Journal of iron and Steel Research International 2022年第5期29卷 741-750页

作者： Hong-tao Wang Man-sheng Chu Ji-wei Bao Zheng-gen Liu Hong-ming Long School of Metallurgy Engineering Anhui University of TechnologyMa’anshan243032AnhuiChina State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang110819LiaoningChina School of Metallurgy Northeastern UniversityShenyang110819LiaoningChina Key Laboratory of Metallurgical Emission Reduction&Resources Recycling Anhui University of TechnologyMinistry of EducationMa’anshan243032AnhuiChina

Highly reactive iron coke hot briquette(ICHB)prepared by carbonizing the agglomerate of iron-bearing substance and blended coals is regarded as an alternative fuel to mitigate carbon emission and energy consumption of blast ***,the reduction process of iron-bearing burden is extremely crucial for blast furnace *** effects of ICHB on the non-isothermal reduction process of iron-bearing burden with different reduction properties were thus experimentally studied under the conditions of simulated blast furnace lump zone(below 1100°C),and the related mechanism was discussed and *** results showed that the non-isothermal reduction process of iron-bearing burden is promoted by adding *** the charging ratio of ICHB is increased from 0%to 30%,the reduction degree of pellet is increased from 22.91%to 36.62%,but the increased amplitude is leveled ***,the reduction degree of sinter is raised from 35.10%to 93.33%.It is also indicated that the promotion effect of ICHB on the non-isothermal reduction of iron-bearing burden depends on the reduction property of *** with the burden with poor reduction performance(such as pellet 1),the promotion is more significant for the burden with good reduction property(such as sinter 1)since the reduction reaction of iron oxide in iron-bearing burden and the gasification of carbon in ICHB are remarkably reinforced each *** practical application of ICHB in blast furnace should be utilized with highly reductive iron-bearing burden.

关键词： iron coke hot briquette Non-isothermal reduction iron-bearing burden Low carbon emission Blast furnace

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