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Dependence of Amorphous Formation Ability on intrinsic parameters in Dy-Gd-Co-Al Alloys

Journal of Materials Science & Technology 2009年第5期25卷 665-668页

作者： Lin Luo Rui Tian Xueshan Xiao Institute of Materials Shanghai University Shanghai 200072 China

A series of Dy（Gd）-based bulk amorphous alloy rods were prepared by water-cooled copper mold method. Thermal stability and structure of Dy-Gd-Co-Al alloys were investigated by differential scanning calorimetry and X-ray diffraction, respectively. The results show that the Dy-Gd-Co-Al alloys have good glass-formation ability, and the Dy31Gd25Co20Al24 alloy can be readily cast into full glassy rods up to 5 mm in diameter. The glass-forming ability of multicomponent alloys was greatly dependent on their chemical interaction and the equivalent bond parameters among atoms such as equivalent electronegativity difference, equivalent atomic size parameter. The Dy （Gd）-based bulk amorphous alloys could be expected as potential functional materials.

关键词： Dy(Gd)-based Glass forming ability intrinsic parameters

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Experimental Study of the Influence of intrinsic parameters on the Thermal Reactivity of Sawdust, Polyethylene Terephthalate and Composite

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Journal of Materials Science and Chemical Engineering 2024年第3期12卷 9-20页

作者： Ange Brel Boukongou Timoléon Andzi Barhé Applied Chemistry Research Laboratory (LARCA) Ecole Normale Supérieure (ENS) Marien NGOUABI University (UMNG) Brazzaville Congo

Several works have been based on the study of thermal variations in biomass to derive more valuable products such as fuels capable of replacing oil in the event of a crisis or activated carbon used as an adsorbent material, widely used in industry for the elimination of unwanted materials, both in liquid and gaseous environments. A study of thermal parameters such as: heating speed, retention time, drying temperature, carbonization temperature, particle size, was carried out with the aim of determining the characteristic factors of the carbonization of Polyethylene terephthalate (PET), sawdust (SC) and sawdust/polyethylene terephthalate (CPS) mixture. The results of the immediate analysis revealed a very low level of ash in PET (0.013%) compared to the level of ash in sawdust (2.9%), as well as a high level of fixed carbon (82.960%), which suggests the presence of mineral oxides and a significant carbon matrix unlike PET, which indicates a very significant organic matrix (essentially made up of organic matter) with the absence of mineral oxides. The study of thermal parameters showed the water loss from Sawdust (SC) and the Sawdust/Polyethylene terephthalate (CPS) mixture, an increase with temperature, unlike that of PET whose variation is essentially zero. Without heat treatment, sawdust alone contains approximately 7% water. The optimal drying temperature for this study is 110˚C for a stay of 24 hours. It appears that the largest mass losses for the PET samples are between 87.19% and 96.05%, followed by that of the mixture, between 47.33% and 64.37%. And the lowest are observed, those of sawdust (from 24.02% to 62.6%). However, here we can say that the influence of the mass is not great, given the slight difference between the losses by temperature. The results of the study of the influence of grain size showed that the differences are insignificant, even if we vary the diameter of the grains from simple to triple. To better minimize physical constraints such as t

关键词： intrinsic parameters Thermal Reactivity Sawdust Polyethylene Terephthalate Composite

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