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Geochemical investigation of low latitude black shale intervals of the Lower to Middle Jurassic succession, Indus basin, Pakistan

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Frontiers of Earth Science 2022年第3期16卷 568-586页

作者： Fahad ALI Shiqi ZHANG Muhammad HANIF Mohibullah MOHIBULLAH Yaxuan ZHANG Muhammad USMAN Sheng WANG Xueliang LIU Pengjie MA Dongmou HUANG School of Geosciences China University of Petroleum(East China)Qingdao 266580China Department of Geology Bacha Khan UniversityCharsadda 24430Pakistan National Centre of Excellence in Geology University of PeshawarPeshawar 25000Pakistan Department of Geology University of BalochistanQuetta 87300Pakistan School of geosciences The University of EdinburghEdinburghEH89JUUK Lukeqin Oil Production Plant PetroChina Tuha OilfieldTurpan City 828202China

The Lower to Middle Jurassic sedimentary succession is dominated by siliciclastics with a significant amount of black shales in the Indus basin,Pakistan.Several outcrop samples have been studied using an integrated approach to interpret the conceptual depositional setting from carbon and oxygen isotopes(δ^(13)C&δ18O),organic geochemistry,and palynofacies with major and trace element analysis.For interpretation of trace element data,various single and elemental ratios have been used in this research to unlock the geological history of the studied strata.Ti/Al is 1.96 for high-potential source rock and 7.82 for non-potential source rock,and Cr(less than 1)indicates low clastic input with low oxygen for stratified and stagnant water.The ratios of V/(V+Cr),V/(V+Ni),V/Mo,V/Ni,(Cu+Mo)/Zn,Mo/Al,isotopic values ofδ^(13)C andδ18O and besides the V/Cr elemental ratio,all proxies indicate that there are oxygen-depleted anoxic conditions at high potentials,while in non-potential source rock,these ratios show oxic to sub-oxic settings.In addition to the trace element correlation with total organic carbon,the influx of organic matter is determined by the palynoafacies analysis,which indicates mixed terrestrial and marine organic influx in high-potential source rock and vice versa.Furthermore,the studies of palynofaceis DFPF A-D and SFPF A-B suggest that the depositional setting of black shale occurred in the anoxic proximal to distal shelf.The results suggest that the regional and local occurrence of black shale during the Lower to Middle Jurassic and its geological condition were addressed,and these play an important role in its depositional and paleooceanographic setting in the Eastern Tethys.

关键词： black shale Jurassic trace elements organic matter Indus basin Pakistan

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Greenhouse Gas Emissions from Agro-Ecosystems and Their Contribution to Environmental Change in the Indus basin of Pakistan

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Advances in Atmospheric Sciences 2008年第6期25卷 1043-1052页

作者： M. Mohsin IQBAL M. Arif GOHEER Global Change Impact Studies Centre （ GCISC） National Centre for Physics （NCP） Complex Quaid-e-Azam University P.O. QA U-45320 Islamabad Pakistan

There is growing concern that increasing concentrations of greenhouse gases in the atmosphere have been responsible for global warming through their effect on radiation balance and temperature. The magnitude of emissions and the relative importance of different sources vary widely, regionally and locally. The Indus basin of Pakistan is the food basket of the country and agricultural activities are vulnerable to the effects of global warming due to accelerated emissions of GHGs. Many developments have taken place in the agricultural sector of Pakistan in recent decades in the background of the changing role of the government and the encouragement of the private sector for investment in new ventures. These interventions have considerable GHG emission potential. Unfortunately, no published information is currently available on GHG concentrations in the Indus basin to assess their magnitude and emission trends. The present study is an attempt to estimate GHG （CO2, CH4 and N2O） emissions arising from different agro-ecosystems of Indus basin. The GHGs were estimated mostly using the IPCC Guidelines and data from the published literature. The results showed that CH4 emissions were the highest （4.126 Tg yr^-1） followed by N20 （0.265 Tg yr^-1） and CO2 （52.6 Tg yr^-1）. The sources of CH4 are enteric fermentation, rice cultivation and cultivation of other crops. N2O is formed by microbial denitrification of NO3 produced from applied fertilizer-N on cropped soils or by mineralization of native organic matter on fallow soils. CO2 is formed by the burning of plant residue and by soil respiration due to the decomposition of soil organic matter.

关键词： greenhouse gases agriculture Indus basin Pakistan

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Geographic distribution of arsenic contamination in the Himalayan Rivers flowing through Pakistan: Implications for its natural source and effects of anthropogenic activities

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International Journal of Sediment Research 2023年第4期38卷 543-555页

作者： Ishtiaque Hussain Hafiz Ur.Rehman Takaaki Itai Junaid Ali Khattak Abida Farooqi Environmental Geochemistry Laboratory Department of Environmental Sciences Faculty of Biological Sciences Quaid-i-Azam University Department of Environmental Sciences University of Baltistan Skardu Graduate School of Sciences and Engineering Kagoshima University Department of Earth and Planetary Environmental Science (UG) Graduate School of Science The University of Tokyo Department of Earth and Planetary Physics (UG) Graduate School of Science The University of Tokyo Department of Earth and Planetary Science (GR) Graduate School of Science The University of Tokyo

Arsenic(As) in natural hydrological systems is known as a worldwide major environmental concern. A geochemical and sedimentological study was done to ascertain the origin and geographical distribution of As in surface water and fluvial sediment collected from the floodplains/basins of the River indus and its four major tributaries that drain through the northern Pakistan. The hydrogeochemical compositions of all five rivers were similar with calcium(Ca2+) and bicarbonate(HCO3-) being the dominating ions. The concentration of As ranged from 0.62-24.05 μg/L(average 3.7 ± 3.5 μg/L, n = 61) in river water, 2.3-23.4 mg/kg(average 5.7 ± 3.9 mg/kg) in suspended sediment, and 2.0-13 mg/kg(average4.13 ± 2.3 mg/kg) in fluvial sediment. Various approaches were used, including mineralogical, sequential extraction, geochemical, and statistical analyses to investigate the distribution, behavior, and potential sources of As in the sediment. The effect of geological factors on the distribution of As was also studied.No noticeable changes in the relative abundance of minerals were observed in the sediment at different locations along the river. Both mineralogical and statistical analyses showed that silicate minerals like muscovite, biotite, and chloride are the main As reservoir while oxides minerals like hematite and magnetite, which are minor components in the sediment are second largest As carrier. A geochemical baseline, using the normalization and cumulative frequency distribution curves was constructed for As.The estimated mean human contribution of As was 3.4% in the indus River, 1.9% in the Jhelum River, 13.7%in the Chenab River, 17.5% in the Ravi River and 5.4% in the Sutlej River, indicating relatively higher effects of anthropogenic activity along the Chenab River and Ravi River. The almost negligible effects of anthropogenic activities were additionally confirmed through the pollution assessment parameters estimated from the geo-enrichment, contamination factors, and accumulation index analyses. The current data sugg

关键词： Arsenic Indus basin Geochemical baseline Source Contamination assessment

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Modelling the Spatial Distribution of Arsenic in Water and Its Correlation with Public Health, Central Indus basin, Pakistan

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Journal of Geoscience and Environment Protection 2016年第2期4卷 18-25页

作者： Yawar Hussain Adil Dilawar Sadia Fida Ullah Gulraiz Akhter Hernan Martinez-Carvajal Muhammad Babar Hussain Abdul Qayyum Aslam Department of Civil and Environmental Engineering University of Brasilia Brasilia Brazil Department of Physics University of Sargodha Sargodha Pakistan Department of Biological Sciences University of Brasilia Brasilia Brazil Department of Earth Sciences Quaid-i-Azam University Islamabad Pakistan Faculty of Mines National University of Colombia at Medellín Medellín Colombia Department of Theoretical and Astrophysics Xiamen University Xiamen China College of Earth and Environmental Sciences University of the Punjab Lahore Pakistan

Like India, Bangladesh and China, Pakistan also has some regions where concentration of Arsenic in water has crossed the WHO safe drinking water limits, 10 ppb. Presence of Arsenic in drinking water is causing serious human health issues for the local residents of Sindh and southern Punjab, which needs serious attention. The present study is focused on the spatial distribution of Arsenic in groundwater and its relationship with the major reported human diseases at settlement level of District Layyah. Data collection is done by taking water samples from hand pumps and health issues reported at the local health care centers adjoining to that sampling pump. The spatial distribution of Arsenic concentration in groundwater is done by using Inversion Distance Weight (IDW) technique. Arsenic Risk Index (ARI) is developed based of WHO health standards, and then used to divide study area into two Arsenic Risk Zones as no risk and high risk with As values less or equal to 10 ng·ml-1 and greater than 10 ng·ml-1, respectively . In the final step these zones were correlated with the diseases at village level. The results show that, Arsenic is high near the indus River and it decreases in central and eastern parts towards Chenab River. Same trend of Indo-Chenab Arsenic gradient is followed by skin diseases among the people especially, in tehsil Layyah and tehsil Koror. It is concluded that high Arsenic amount in water and skin diseases are highly dependent on the recharge from indus River.

关键词： Arsenic GIS Human Health IDW Indus basin Layyah

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Disintegration of uncertainties associated with real-time multi-satellite precipitation products in diverse topographic and climatic area in Pakistan

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Journal of Mountain Science 2021年第3期18卷 716-734页

作者： Muhammad MASOOD Ghulam NABI Muhammad BABUR Aftab Hussain AZHAR Muhammad KALEEM ULLAH Centre of Excellence in Water Resources Engineering University of Engineering&Technology GT-RoadLahore 54890Pakistan Civil Engineering Department University of Central PunjabLahore 54782Pakistan Directorate of Hydrology Pakistan Water&Power Development Authority(WAPDA)MDO-WAPDAMangla Dam10200Pakistan Civil Engineering Department University of LahoreLahore 54000Pakistan

Satellite-based Precipitation Estimates(SPEs)have gained importance due to enhanced spatial and temporal resolution,particularly in Indus basin,where raingauge network has fewer observation stations and drainage area is laying in many countries.Formulation of SPEs is based on indirect mechanism,therefore,assessment and correction of associated uncertainties is required.In the present study,disintegration of uncertainties associated with four prominent real time SPEs,IMERG,TMPA,CMORPH and PERSIANN has been conducted at grid level,regional scale,and summarized in terms of regions as well as whole study area basis.The bias has been disintegrated into hit,missed,false biases,and Root Mean Square Error(RMSE)into systematic and random errors.A comparison among gauge-and satellite-based precipitation estimates at annual scale,showed promising result,encouraging use of real time SPEs in the study area.On grid basis,at daily scale,from box plots,the median values of total bias(-0.5 to 0.5 mm)of the used SPEs were also encouraging although some under/over estimations were noted in terms of hit bias(-0.15 to 0.05 mm/day).Relatively higher values of missed(0.3 to 0.5 mm/day)and false(0.5 to 0.7 mm/day)biases were observed.The detected average daily RMSE,systematic errors,and random errors were also comparatively higher.Regional-scale spatial distribution of uncertainties revealed lower values of uncertainties in plain areas,depicting the better performance of satellite-based products in these areas.However,in areas of high altitude(>4000 m),due to complex topography and climatic conditions(orographic precipitation and glaciated peaks)higher values of biases and errors were observed.Topographic barriers and point scale gauge data could also be a cause of poor performance of SPEs in these areas,where precipitation is more on ridges and less in valleys where gauge stations are usually located.Precipitation system’s size and intensity can also be a reason of higher biases,because Microwave Imager underestimate precipitation in s

关键词： Satellite precipitation Real-time Error characterization IMERG Indus basin

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Evaluation of soil loss severity and ecological restoration approach for sustainable agriculture in the Hindu Kush, Karakoram and Himalaya region

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Journal of Mountain Science 2024年第5期21卷 1509-1521页

作者： Arshad ASHRAF Imran AHMAD Climate Energy and Water Research InstituteNational Agricultural Research Centre(NARC)Islamabad 44000Pakistan

Soil erosion has resulted in removal of the topsoils containing fine soil particles and plant nutrients, causing decrease in soil fertility in the Hindu Kush, Karakoram and Himalaya(HKH) region. The existing production of cereal crop grains has been reduced to one third of the potential crop grains production owing to land degradation and poor farming practices. It is necessary to assess risk of soil loss and identify appropriate controlling measures to address issues of low agriculture productivity and water insecurity in the region. In the present study, severity of soil loss was predicted using Revised Universal Loss Equation(RUSLE) and ecological measures were identified for sustainable mountain agriculture in the HKH region of Upper Indus basin, Pakistan. Overall 62.6% area was found to have very low risk of soil loss, i.e., 100 t/(ha·yr) in about 6.8% and 7.4% areas respectively. The mean rate of soil loss was about 41.9 t/(ha·yr) in the Hindu Kush, 31.1 t/(ha·yr) in the Himalayas, 18.8 t/(ha·yr) in the Karakoram and overall 29.7 t/(ha·yr) in the three HKH ranges. As such no considerable measures have been adopted by the communities for restoration of the degraded areas except raising fruit/farm trees and supporting limited social forestry for their livelihoods. The slopes cleared for cultivation and susceptible to erosion may be stabilized through sowing/planting of multi-purpose plant species and formation of proper bench terraces. The conservation of forest ecosystem and pastures at higher elevations would help in reducing overland water flow, risk of flash flood hazard and minimizing sediment loads in the downstream. It is essential to adopt site-specific resource conservation techniques and restore possible ecosystem health for sustainable agriculture and economic development in the region in future.

关键词： Climate change Erodibility Indus basin Land degradation Slope stabilization

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Plates Boundary and Structural Geology of Balochistan and Indus basins through Field Observations on Chaman Transform Fault and Western indus Suture (Pakistan): Dinosaurs from Pakistan with Attributed Bones and Key Features: Titanosaurs from India with Updated Assessment on Jainosaurus

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Open Journal of Geology 2022年第11期12卷 1032-1079页

作者： Muhammad Sadiq Malkani Geological Survey of Pakistan Muzaffarabad Pakistan

The plate boundary between Balochistan and Indus basins is found on the position where Western indus Suture and Chaman Transform fault converge in the south (Uthal-Bela-Ornach-Nal-Basima). From Basima to northward the both structures bifurcate and separate more than 50 km in the Zhob region, the Chaman Transform fault lies in the west as straight way in flysh and slates of Balochistan basin, and Western indus suture lies in the east mostly straight and wide (more than 20 km wide) galaxy way like belt (gentle wavy in the central portion from Quetta to Zhob). Plate boundary between Balochistan basin and Indus basin lies in the Western indus suture. The both structures are about 1000 - 1500 km trends northward. The northward bending of strikes in the southern Balochistan basin (from Arabian sea to Kharan) on the western flank of Chaman transform fault and dragging of Kharan limestones revealed left lateral strike slip fault. The structures of Balochistan basin are mostly imbricated while the structure of Indus basin is mostly folded. Different basins in Pakistan yielded dinosaurs and diverse Mesozoic vertebrates like poripuchian titanosaurian sauropods, vitakrisaurid abelisaurian theropods, induszalimids, sulaimanisuchid and mithsaraikistanid mesoeucrocodiles, saraikisaurid pterosaurs, wasaibpanchid bird, madtsoiid snake, zahrisaurid plesiosaur and some fishes. From Pakistan 10 titanosaurs were named while from India 5 titanosaurs were named and discussed here. The updated assessment for the attribution of bones to Jainosaurus septentrionalis resulted the braincase its type or in other case braincase and scapula referable to Isisaurus colberti matching its long articular surface for coracoid of distal scapula. Key bones which were previously referred to Jainosaurus septentrionalis belong to mostly Gspsaurus pakistani and Balochisaurus malkani (stocky titanosaurs) and a few bones to Isisaurus colberti and Pakisaurus balochistani (slender titanosaurs).

关键词： Plates Boundary Chaman Transform Fault Western indus Suture Structural Geology Balochistan basin Tethys Link Indus basin Gondwanan Link Dinosaurs Titanosaurs Comparison Maastrichtian Pakistan India Jainosaurus

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