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in-situ hydrothermal synthesized γ-Al_2O_3/O-g-C_3N_4 heterojunctions with enhanced visible-light photocatalytic activity in water splitting for hydrogen

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Journal of Energy Chemistry 2016年第4期25卷 594-600页

作者： Yu Wang Yaping Zeng Boqiao Li Anqi Li Ping Yang Liu Yang Gang Wang Jinwei Chen Ruilin Wang College of Materials Science and Engineering Sichuan University

In this work, γ-Al2O3and hydrogen peroxide treated g-C3N4(O-g-C3N4) were combined through a novel in-situ hydrothermal method to form heterojunction structured photocatalysts. These photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), UV–vis diffuse reflectance spectroscopy and photoluminescence spectroscopy (PL). FT-IR results indicate that oxygen functional groups can be grafted on the surface of O-g-C3N4by hydrogen peroxide treatment. The visible light photocatalytic hydrogen evolution rate was investigated in 10 vol% TEOA aqueous solution. The optimal Al2O3mass content is set to be 20 wt% and the corresponding hydrogen evolution rate is 1288 µmol/h/g which is approximately 6, 3 folds that of pristine g-C3N4and O-g-C3N4respectively and 1.6 folds that of mechanical mixed composite with the same Al2O3mass content. The photocurrent density–time curves were carried out under visible light illumination for four on–off cycles. The electrochemical impedance spectroscopy (EIS) measurements verified the enhanced separation efficiency of electron–hole pairs. This work raised a new method to form the heterojunction structured photocatalysts and achieved a remarkable improvement of the photocatalytic activity in water splitting for hydrogen under visible light irradiation. © 2016

关键词： O doped g-C3N4 γ-Al2O3 Visible-light photocatalysis in-situ hydrothermal Hydrogen

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Photocatalytic degradation of organic pollutants using green oil palm frond-derived carbon quantum dots/titanium dioxide as multifunctional photocatalysts under visible light radiation

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Chinese Journal of Chemical Engineering 2022年第11期51卷 21-34页

作者： Zeng Wei Heng Woon Chan Chong Yean Ling Pang Lan Ching Sim Chai Hoon Koo Lee Kong Chian Faculty of Engineering and Science Universiti Tunku Abdul RahmanSungai Long CampusJalan Sungai LongCheras43000 KajangSelangorMalaysia Centre for Photonics and Advanced Materials Research Universiti Tunku Abdul RahmanSungai Long CampusJalan Sungai LongCheras43000 KajangSelangorMalaysia

The present work suggested the use of waste oil palm frond as an alternative precursor for nitrogendoped carbon quantum dots(NCQDs)and proposed a straightforward in-situ hydrothermal method for the preparation of NCQDs/TiO_(2)*** elemental composition,morphological,structural and optical characteristics of NCQDs/TiO_(2)nanocomposites have been comprehensively *** successful grafting of NCQDs on TiO_(2)matrix was confirmed by the formation of Ti AOAC bond and the electronic coupling between theπ-states of NCQDs and the conduction band of TiO_(2).For the first time,the oil palm frond-derived NCQDs/TiO_(2)was adopted in the photodegradation of methylene blue(MB)under visible-light *** a result,the photocatalytic efficiency of NCQDs/TiO_(2)nanocomposites(86.16%)was 2.85 times higher than its counterpart TiO_(2)(30.18%).The enhanced performance of nanocomposites was attributed to the pivotal roles of NCQDs serving as electron mediator and visiblelight ***,the optimal NCQDs loading was determined at 4 ml while the removal efficiency of NCQDs/TiO_(2)-4 was the highest at a catalyst dosage of 1 g.L^(-1)under alkaline *** research work is important as it proposed a new insight to the preparation of biomass-based NCQDs/TiO_(2)using a facile synthetic method,which offers a green and sustainable water remediation technology.

关键词： Oil palm frond biomass N-doped carbon quantum dots Titanium-dioxide in-situ hydrothermal Visible light photocatalysis Methylene blue

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