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Recovery of Cu(Ⅱ) from aqueous solution by induced crystallization in a long-term operation

Journal of Environmental Sciences 2018年第7期30卷 183-191页

作者： Zhimou Wei Ya Xiong Jian Chen Jing Bai Jing Wu Jiane Zuo Kaijun Wang School of Environment Tsinghua University Beijing 100084 China Department of Environmental Science and Engineering China University of Geosciences Beijing 100083 China Chinese Academy for Environmental Planning Beijing 100012 China

The feasibility of copper recovery by induced crystallization in a long period（174 days） was investigated in a seeded fluidized bed reactor（FBR）. The process was divided into 3 periods according to different influent conditions, and the period Ⅲ was separated into Ⅲ-a and Ⅲb due to the adjustment of the molar ratio of CO3^2- concentration to copper concentration（[CT]/[Cu^2＋]）. The removal efficiency could exceed 95% and the average effluent copper concentration decreased to 3.0 mg/L. The mean particle size of seed grains with copper crystals coating on, raised to 0.36 mm from initial 0.18 mm. During period Ⅲ-a, the supersaturation exceeded 2.88 × 104, the removal efficiency decreased to 60%–80% and the particle size dropped to 0.30 mm, due to the generation of fines by homogeneous crystallization and seeds breaking. And the morphology of the crystals on the seed grains changed from rod-like to spherical which lead to the particle size decreasing. In period Ⅲ-b,the supersaturation was modified by adjusting the molar ratio of [CT]/[Cu^2＋] to 1.2 from *** efficiency was back to 95% and the mean particle size grew to 0.36 mm at the end of Ⅲb, the crystals coating on the seeds turned back to rod-like products of good stability. This study illustrated that the copper salt crystal could keep on growing on the seed grains for over 150 days, the feasibility and controllability of copper recovery by induced crystallization process in FBR were satisfactory, even under the dramatic changes in influent conditions.

关键词： Copper removal induced crystallization Fluidized bed reactor Supersaturation Long-term operation

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crystallization BEHAVIOR OF POLYLACTIDE ON HIGHLY ORIENTED POLYETHYLENE THIN FILMS

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Chinese Journal of Polymer Science 2011年第4期29卷 513-519页

作者：闫寿科 State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology

The crystalline structure and morphology of the PLA crystallized isothermally from the glassy state on highly oriented PE substrates at 130℃ were investigated by means of optical microscopy, AFM and X-ray diffraction. The results indicate that the PE substrate influences the crystallization behavior of PLA remarkably, which leads to the growth of PLA crystals on PE substrate always in edge-on form rather than the twisted lamellar crystals from edge-on to flat-on when crystallizing the PLA on glass surface under the same condition. The edge-on PLA lamellae on the PE substrate are preferentially arranged with their long axes in the chain direction of the PE substrate crystals. It is further demonstrated that except for the different crystal orientation, the PE does not influence the crystalline modification and crystallinity of the PLA.

关键词： Polyethylene Poly(lactide) induced crystallization Morphology Orientation.

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