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hollow carbon nanofibers with dynamic adjustable pore sizes and closed ends as hosts for high-rate lithiumsulfur battery cathodes

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Nano Research 2018年第3期11卷 1238-1246页

作者： Xiang-Qian Zhang Bin He Wen-Cui Li An-Hui Lu State Key Laboratory of Fine Chemicals School of Chemical Engineering Faculty of Chemical Environmental and Biological Science and Technology Dalian University of Technology Linggong Road 2 Dalian 116024 China

Designing a better carbon framework is critical for harnessing the high theoretical capacity of Li-S batteries and avoiding their drawbacks, such as the insulating nature of sulfur, active material loss, and the polysulfide shuttle reaction. Here, we report an ingenious design of hollow carbon nanofibers with closed ends and protogenetic mesopores in the shell that can be retracted to micropores after sulfur infusion. Such dynamic adjustable pore sizes ensure a high sulfur loading, and more importantly, eliminate excessive contact of sulfur species with the electrolyte. Together, the high aspect ratio and thin carbon shells of the carbon nanofibers facilitate rapid transport of Li^＋ ions and electrons, and the closed-end structure of the carbon nanofibers further blocks polysulfide dissolution from both ends, which is remarkably different from that for carbon nanotubes with open ends. The obtained sulfur-carbon cathodes exhibit excellent performance marked by high sulfur utilization, superior rate capability （1,170, 1,050, and 860 mA.h.g-1 at 1.0, 2.0, and 4.0 C （1 C = 1.675 A·g^-1）, respectively）, and a stable reversible capacity of 847 mA·h·g^-1 after 300 cycles at a high rate of 2.0 C.

关键词： hollow carbon nanofibers pore-adjusting strateg sulfur cathodes rate capability energy materials

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Porous nitrogen-enriched hollow carbon nanofibers as freestanding electrode for enhanced lithium storage

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Chinese Journal of Chemical Engineering 2021年第4期34卷 416-422页

作者： Xiaosa Xu Yuqian Qiu Jianping Wu Baichuan Ding Qianhui Liu Guangshen Jiang Qiongqiong Lu Jiangan Wang Fei Xu Hongqiang Wang State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene(NPU)Xi'an 710072China Leibniz Institute for Solid State and Materials Research(IFW)Dresden e.V. Helmholtzstr 2001069 DresdenGermany

Onedimensional porous carbons bearing high surface areas and sufficient heteroatom doped functionalities are essential for advanced electrochemical energy storage devices,especially for developing freestanding film *** we develop a porous,nitrogenenriched,freestanding hollow carbon nanofiber(PNFHCF)electrode material via filtration of polypyrrole(PPy)hollow nanofibers formed by in situ selfdegraded templateassisted strategy,followed by NH3assisted *** PNFHCF retains the freestanding film morphology that is composed of threedimensional networks from the entanglement of 1D nanofiber and delivers 3.7fold increase in specific surface area(592 m^(2)g^(-1))compared to the carbon without NH_(3)treatment(FHCF).In spite of the enhanced specific surface area,PNFHCF still exhibits comparable high content of surface N functionalities(8.8%,atom fraction)to *** developed hierarchical porous structure without sacrificing N doping functionalities together enables the achievement of high capacity,highrate property and good cycling stability when applied as selfsupporting anode in lithiumion batteries,superior to those of FHCF without NH3 treatment.

关键词： Energy Electrochemistry Nanomaterials hollow carbon nanofibers Freestanding electrode Lithium-ion batteries

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Fabrication of 3D ordered needle-like polyaniline@hollow carbon nanofibers composites for flexible supercapacitors

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Chinese Chemical Letters 2021年第8期32卷 2448-2452页

作者： Xuepeng Ni Yang Jiang Haoyu Chen Kunming Li Huifang Chen Qilin Wu Anqi Ju College of Materials Science and Engineering&State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Donghua UniversityShanghai 201620China Zhejiang Provincial Key Laboratory of Yarn Material Forming and Composite Processing Technology Jiaxing UniversityShanghai 201620China Key Laboratory of High-Performance Fibers&Products Ministry of EducationDonghua UniversityJiaxing 314001China

carbon nanofiber-based supercapacitors have broad prospects in powering wearable electronics owing to their high specific capacity,fast charge/discharge process,along with long-cycling ***,a poly(ac rylo n it rile-co-β-methyl hydrogen itaconate) copolymer was prepared and used to synthesize flexible hollow carbon nanofibers(HCNFs) via an electrospinning method without breaking after multiple ***,the inner and outer surfaces of HCNFs were evenly covered with ordered needlelike polyaniline(PANI) through in-situ polymerization methods to obtain three-dimensional flexible HCNFs/PANI composites,which exhibited a high capacity 1196.7 F/g at 1 A/g and good cycling stability(90.1% retention at 5 A/g after 3000 cycles).The symmetrical supercapacitor based on the HCNFs/PANI composites also delive red an outsta nding electrochemical performance with high energy/power density(60.28 Wh/kg at 1000 W/kg) and superior cycling durability(90% capacitance retention after at 5 A/g3000 cycles),which confirmed that the HCNFs/PANI composites had a wide application potential in flexible energy storage devices.

关键词： Flexible Polyaniline Electrospinning hollow carbon nanofibers Supercapacitors

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