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Injector Quantum Dot Molecule Infrared Photodetector:A Concept for Efficient Carrier Injection

Nano-Micro Letters 2011年第2期3卷 121-128页

作者： Thomas Gebhard Thomas Gebhard Photonics InstituteVienna University of Technology

Quantum dot infrared photodetectors are expected to be a competitive technology at high oper ation temperatures in the long and very long wavelength infrared spectral *** the fact that they already achieved notable success,the performance suffers from the thermionic emission of electrons from the quantum dots at elevated temperatures resulting in a decreasing *** order to provide an efficient carrier injection at high temperatures,quantum dot infrared photodetectors can be separated into two parts:an injection part and a detection part,so that each part can be separately *** order to integrate such functionality into a device,a new class of quantum dot infrared photodetectors using quantum dot molecules will be *** addition to a general discussion simulation results suggest a possibility to realize such a device.

关键词： Quantum dot infrared photodetector Injection Quantum dot molecule high temperature operation Responsivity

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Impact of Thickness of Polymer Electrolyte Membrane on temperature Distributions in Single Cell of Polymer Electrolyte Fuel Cell Operated at high temperature

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Journal of Energy and Power Engineering 2018年第2期12卷 80-92页

作者： Akira Nishimura Yusuke Sato Masato Yoshimura Satoru Kamiya Masafumi Hirota Division of Mechanical Engineering Graduate School of EngineeringMie UniversityTsu-cityMie 514-8507Japan

This study is to understand the impact of operating condition, especially initial operation temperature （Tini） which is set in high temperature range, on the temperature profile of the interface between PEM （polymer electrolyte membrane） and catalyst layer at the cathode （i.e., the reaction surface） in a single PEFC （polymer electrolyte fuel cell）. A 1D multi-plate heat transfer model based on the temperature data of separator measured using thermograph in a power generation experiment was developed to evaluate the reaction surface temperature （Treact）. This study investigated the effects of Tini, flow rate and relative humidity of supply gas as well as thickness of PEM on the temperature distribution on reaction surface. As a result, the impact of flow rate of supply gas on the temperature distribution is not significant irrespective of relative humidity conditions as well as PEM type. When operated at high temperature, the temperature distribution is relatively flat in the case of thicker PEM （Nafion 115）, while Treact rises from the inlet to the outlet large and the temperature distribution is wide in the case of thin PEM （Nafion 211） irrespective of relative humidity condition. Since the water transfer through PEM in the case of Nafion 211 is better than Nafion 115 due to thin PEM, the power generation is promoted along the gas flow with the aid of humidification by water produced from electrochemical reaction.

关键词： PEFC heat transfer model temperature distribution high temperature operation thickness of PEM.

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Impact of Relative Humidity of Supply Gas on temperature Distributions in Single Cell of Polymer Electrolyte Fuel Cell When Operated at high temperature

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Journal of Energy and Power Engineering 2017年第11期11卷 706-718页

作者： Akira Nishimura Masato Yoshimura Satoru Kamiya Masafumi Hirota Eric Hu Division of Mechanical Engineering Graduate School of Engineering Mie University Tsu-eity Mie 514-8507 Japan School of Mechanical Engineering the University of Adelaide Adelaide SA 5005 Australia

For improving the performance of stationary PEFC （polymer electrolyte fuel cell） system, the cell operating temperature up to 90℃ will be preferred in Japan during the period from 2020 to 2030. To understand the operation of the PEFC system under relatively high temperature conditions, detail heat and mass transfer analysis is required. The purpose of this study is to analyze the impact of relative humidity of supply gas on temperature distribution on the backside of separator in single ceil of PEFC using Nation membrane at higher temperature e.g. 90℃. The in-plane temperature distribution when power was being generated was measured using thermograph with various relative humidity of supply gases. It was found that the in-plane temperature distribution at the anode was more even than that at the cathode irrespective of the relative humidity of supply gas at the anode and the cathode. The temperature elevated along gas flow through the gas channel at the cathode irrespective of relative humidity of supply gas at the anode and the cathode. The in-plane temperature distribution at the cathode was narrower with the increase in Tini irrespective of relative humidity of supply gas at the cathode, while it was not observed when changing the relative humidity of supply gas at the anode. When the relative humidity of supply gas at cathode decreased, the in-plane temperature distribution at the anode was wider compared to decreasing the relative humidity of supply gas at the anode. The study concluded that the impact of relative humidity of supply gas at both anode and cathode had little impact on the in-plane temperature distribution at the cathode.

关键词： PEFC temperature distribution high temperature operation relative humidity.

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Numerical Analysis on temperature Distribution in a Single Cell of PEFC Operated at higher temperature by1D Heat Transfer Model and 3D Multi-Physics Simulation Model

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Energy and Power Engineering 2023年第5期15卷 205-227页

作者： Akira Nishimura Kyohei Toyoda Daiki Mishima Eric Hu Division of Mechanical Engineering Graduate School of Engineering Mie University Tsu Japan

This study is to understand the impact of operating conditions, especially initial operation temperature (Tini) which is set in a high temperature range, on the temperature profile of the interface between the polymer electrolyte membrane (PEM) and the catalyst layer at the cathode (i.e., the reaction surface) in a single cell of polymer electrolyte fuel cell (PEFC). A 1D multi-plate heat transfer model based on the temperature data of the separator measured using the thermograph in a power generation experiment was developed to evaluate the reaction surface temperature (Treact). In addition, to validate the proposed heat transfer model, Treact obtained from the model was compared with that from the 3D numerical simulation using CFD software COMSOL Multiphysics which solves the continuity equation, Brinkman equation, Maxwell-Stefan equation, Butler-Volmer equation as well as heat transfer equation. As a result, the temperature gap between the results obtained by 1D heat transfer model and those obtained by 3D numerical simulation is below approximately 0.5 K. The simulation results show the change in the molar concentration of O2 and H2O from the inlet to the outlet is more even with the increase in Tini due to the lower performance of O2 reduction reaction. The change in the current density from the inlet to the outlet is more even with the increase in Tini and the value of current density is smaller with the increase in Tini due to the increase in ohmic over-potential and concentration over-potential. It is revealed that the change in Treact from the inlet to the outlet is more even with the increase in Tini irrespective of heat transfer model. This is because the generated heat from the power generation is lower with the increase in Tini due to the lower performance of O2 reduction reaction.

关键词： PEFC Heat Transfer Model temperature Distribution Numerical Simulation high temperature operation

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