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Surface-Driven high-pressure Processing

Engineering 2018年第3期4卷 311-320页

作者： Keith E. Gubbins Kai Gu Liangliang Huang Yun Long J. Matthew Mansell Erik E. Santiso Kaihang Shi Malgorzata Sliwifiska-Bartkowiak Deepti Srivastava Department of Chemical and Biomolecular Engineering North Carolina State University Raleigh NC 27695-7905 USA Department of Chemistry Zhejiang University Hangzhou 310027 China School of Chemical Biological and Materials Engineering The University of Oklahoma Norman OK 73019 USA Department of Chemical and Biomolecular Engineering National University of Singapore Singapore 117585 Singapore Faculty of Physics Adam Mickiewicz University in Poznan Poznaan 61-614 Poland

The application of high pressure favors many chemical processes, providing higher yields or improved rates in chemical reactions and improved solvent power in separation processes, and allowing activation barriers to be overcome through the increase in molecular energy and molecular collision rates. high pressures-up to millions of bars using diamond anvil cells-can be achieved in the laboratory, and lead to many new routes for chemical synthesis and the synthesis of new materials with desirable thermody- namic, transport, and electronic properties. On the industrial scale, however, high-pressure processing is currently limited by the cost of compression and by materials limitations, so that few industrial processes are carried out at pressures above 25 MPa. An alternative approach to high-pressure processing is pro- posed here, in which very high local pressures are generated using the surface-driven interactions from a solid substrate. Recent experiments and molecular simulations show that such interactions can lead to local pressures as high as tens of thousands of bars （1 bar=1×10^5 Pa）, and even millions of bars in some cases. Since the active high-pressure processing zone is inhomogeneous, the pressure is different in dif- ferent directions. In many cases, it is the pressure in the direction parallel to the surface of the substrate （the tangential pressure） that is most greatly enhanced. This pressure is exerted on the molecules to be processed, but not on the solid substrate or the containing vessel. Current knowledge of such pressure enhancement is reviewed, and the possibility of an alternative route to high-pressure processing based on surface-driven forces is discussed. Such surface-driven high-pressure processing would have the advantage of achieving much higher pressures than are possible with traditional bulk-phase processing, since it eliminates the need for mechanical compression. Moreover, no increased pressure is exerted on the containing vessel fo

关键词： Confinement high pressure high pressure phase high pressure reaction high pressure manufacture high pressure chemical processing

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