检索结果-南通市图书馆

Polymer dispersed ionic liquid electrolytes with high ionic conductivity for ultrastable solid-state lithium batteries

引用

Carbon Energy 2023年第5期5卷 115-126页

作者： Shengyu Qin Yaping Cao Jianying Zhang Yunxiao Ren Chang Sun Shuoning Zhang Lanying Zhang Wei Hu Meina Yu Huai Yang School of Materials Science and Engineering Beijing Advanced Innovation Center for Materials Genome EngineeringPeking UniversityBeijingPeople's Republic of China Institute for Advanced Materials and Technology University of Science and Technology BeijingBeijingPeople's Republic of China Key Laboratory of Polymer Chemistry and Physics of Ministry of Education Peking UniversityBeijingPeople's Republic of China

Solid polymer electrolytes(SPEs)have emerged as one of the most promising candidates for building solid-state lithium batteries due to their excellent flexibility,scalability,and interfacial compatibility with electrodes.However,the low ionic conductivity and poor cyclic stability of SPEs do not meet the requirements for practical applications of lithium batteries.Here,a novel polymer dispersed ionic liquid-based solid polymer electrolyte(PDIL-SPE)is fabricated using the in situ polymerization-induced phase separation(PIPS)method.The as-prepared PDIL-SPE possesses both outstanding ionic conductivity(0.74 mS cm^(-1) at 25℃)and a wide electrochemical window(up to 4.86 V),and the formed unique three-dimensional(3D)co-continuous structure of polymer matrix and ionic liquid in PDIL-SPE can promote the transport of lithium ions.Also,the 3D co-continuous structure of PDIL-SPE effectively accommodates the severe volume expansion for prolonged lithium plating and stripping processes over 1000 h at 0.5 mA cm^(-2) under 25℃.Moreover,the LiFePO_(4)//Li coin cell can work stably over 150 cycles at a 1 C rate under room temperature with a capacity retention of 90.6%from 111.1 to 100.7 mAh g^(-1).The PDIL-SPE composite is a promising material system for enabling the ultrastable operation of solid-state lithium-metal batteries.

关键词： high ionic conductivity lithium batteries solid polymer electrolytes solid-state batteries

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Recent advances of composite electrolytes for solid-state Li batteries

引用

Journal of Energy Chemistry 2022年第4期31卷 524-548页

作者： Laiqiang Xu Jiayang Li Honglei Shuai Zheng Luo Baowei Wang Susu Fang Guoqiang Zou Hongshuai Hou Hongjian Peng Xiaobo Ji College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083HunanChina

All-solid-state lithium batteries(ASSLBs)are recognized as high energy density batteries system without safety issues within the next generation of batteries.The development of solid electrolytes is the crucial step of ASSLBs.The composite electrolyte has stable physical and electrochemical characteristics,and its comprehensive performance surpasses the individual solid electrolyte,bringing unique vitality to the solid electrolyte.However,their intrinsic weakness limits the development of composite electrolytes.In this review,we provide a comprehensive and in-depth understanding of the challenges and opportunities of composite electrolytes,with special focus on mechanisms of ion transport,nanostructure design towards high ionic conductivity,interfacial issues within electrolytes and electrodes.Furthermore,future development is prospected,which can shed light on researchers in this field and accelerate the industrial production of composite electrolytes.

关键词： high energy density Composite electrolytes Ion transport high ionic conductivity Interfacial issues

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Novel Zr-doped β-Li_(3)PS_(4) solid electrolyte for all-solid-state lithium batteries with a combined experimental and computational approach

引用

Nano Research 2023年第2期16卷 3516-3523页

作者： Junbo Zhang Guoxi Zhu Han Li Jiangwei Ju Jianwei Gu Renzhuang Xu Sumin Jin Jianqiu Zhou Bingbing Chen Department of Mechanical and Power Engineering Nanjing Tech UniversityNanjing 211816China Qingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdao 266101China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Department of Energy Science and Engineering Nanjing Tech UniversityNanjing 211816China

All-solid-state lithium batteries(ASSLBs)are promising for safety and high-energy-density large-scale energy storage.In this contribution,we propose a Li_(3–4x)Zr_(x)PS_(4)(LZPS)by Zr-dopedβ-Li_(3)PS_(4)(LPS)as a novel solid electrolyte(SE)for ASSLBs based on experimental and simulation methods.The structure,electronic property,mechanical property,and ionic transport properties of LZPS(x=0,0.03,0.06,and 0.1)are investigated with first-principles calculations.Meanwhile,LZPS is prepared by solid states reaction method.By combining experimental analysis and first-principles calculations,it is confirmed that a small amount of Zr4+can be successfully doped into the framework ofβ-LPS composites without significantly compromising structural integrity.When the Zr^(4+)concentration is x=0.03,the doped material Li_(2.88)Zr_(0.03)PS_(4)exhibits the highest ionic conductivity(5.1×10^(−4)S·cm^(−1))at 30℃,and the Li-ion migration energy barrier is the lowest.The Li_(2.88)Zr_(0.03)PS_(4)SE has obtained the best mechanical properties,the good ductility,and shear deformation resistance,which can better maintain the structural stability of the battery.In addition,the Li/Li symmetrical cell is assembled,which shows excellent electrochemical stability of electrolyte against lithium.The constructed all-solid-state batteries(LiCoO_(2)-Li_(6)PS_(5)Cl|Li_(2.88)Zr_(0.03)PS_(4)|Li-In)delivers an initial discharge capacity of 130.4 mAh·g^(−1)at 0.2 C and a capacity retention of 85.1%after 100 cycles at room temperature.This study provides a promising electrolyte for the application of ASSLBs with high ionic conductivity and excellent stability against lithium.

关键词： all-solid-state lithium batteries first-principles calculations high ionic conductivity interface stability

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Modified room temperature solid-state synthesis of yttria-stabilized zirconia(YSZ) nano-powders for solid oxide fuel cells

引用

稀土学报:英文版 2023年第9期41卷 1385-1391,I0004页

作者： Xiaoqian Xu Yurun Feng Zhaoyu Zhong Xue Guo Zhenhao Zhang Jiao Li Shikai Zhao Shigang Wu Haibin Sun School of Materials Science and Engineering Shandong University of TechnologyZibo 255000China Shandong Yasai Ceramic Technology Co. Ltd.Jinan 271100China Shandong Industrial Ceramics Research&Design Institute Co. Ltd.Zibo 255000China

high-performance solid oxide fuel cell(SOFC) is in urgent need of high-quality electrolyte powders with high reactivity and chemical uniformity.Here,8 mol% Y_(2)O_(3) doped ZrO_(2)(YSZ) nano-powders were synthesized by an improved solid-state reaction method at ambient temperature,and were applied to the fabrication of SOFC electrolytes.YSZ nano-powders show average grain sizes of ^(2)0 nm and high dispersibility,which is comparable with or even better than some other chemical methods.Benefitting from their high reactivity,dense YSZ electrolytes(relative density of 97.9%) can be obtained at a relatively low sintering temperature of 1400℃.The optimized electrical conductivity reaches up to a high value of0.034 S/cm at 800 0C in air.The anode supported single cell with the construction of Ni-YSZ/YSZ/Sm_(0.2)Ce_(0.8)O_(2-δ)(SDC)/La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-δ)(LSCF) exhibits the peak power density of 0.827 W/cm^(2) at800℃ while taking wet H_(2) as fuels and ambient air as oxidants.

关键词： Room temperature solid-state reaction YSZ electrolyte high sintering activity high ionic conductivity Rare earths

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

NASICONs-type solid-state electrolytes:The history,physicochemical properties,and challenges

引用

Interdisciplinary Materials 2023年第1期2卷 91-110页

作者： Lixiao Zhang Yimeng Liu Ya You Ajayan Vinu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina International School of Materials Science and Engineering Wuhan University of TechnologyWuhanChina Global Innovative Center for Advanced Nanomaterials(GICAN) School of EngineeringCollege of EngineeringScienceand the EnvironmentThe University of NewcastleCallaghanNew South Wales 2308Australia

Solid-state electrolytes are critical for the development of next-generation high-energy and high-safety rechargeable batteries.Among all the candidates,sodium(Na)superionic conductors(NASICONs)are highly promising because of their evident advantages in high ionic conductivity and high chemical/electrochemical stability.The concept of NASICONs was proposed by Hong and Goodenough et al.in 1976 by reporting the synthesis and characterization of Na1+xZr2(SixP3−x)O12(0≤x≤3),which has attracted tremendous attention on the NASICONs-type solid-state electrolytes.In this review,we are committed to describing the development history of NASICONs-type solid-state electrolytes and elucidating the contribution of Goodenough as a tribute to him.We summarize the correlations and differences between lithium-based and sodium-based NASICONs electrolytes,such as their preparation methods,structures,ionic conductivities,and the mechanisms of ion transportation.Critical challenges of NASICONs-structured electrolytes are discussed,and several research directions are proposed to tackle the obstacles toward practical applications.

关键词： electrode/electrolyte interface grain boundary resistance high ionic conductivity NASICONs solid-state electrolyte

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

high ionic conductive protection layer on Zn metal anode for enhanced aqueous zinc-ion batteries

引用

Chinese Chemical Letters 2023年第6期34卷 563-566页

作者： Xianyu Liu Qiongqiong Lu Aikai Yang Yitai Qian School of Chemical Engineering Lanzhou City UniversityLanzhou 730070China Leibniz Institute for Solid State and Materials Research(IFW)Dresden e.V. Helmholtzstraβe 2001069 DresdenGermany Materials Synthesis and Processing(IEK-1) Institute of Energy and Climate ResearchForschungszentrum Jülich GmbH52425JülichGermany Hefei National Laboratory for Physical Science at the Microscale Department of Applied ChemistryUniversity of Science and Technology of ChinaHefei 230026China

Aqueous zinc-ion batteries(ZIBs)has been regarded as a promising energy storage system for large-scale application due to the advantages of low cost and high safety.However,the growth of Zn dendrite,hydrogen evolution and passivation issues induce the poor electrochemical performance of ZIBs.Herein,a Na_(3)Zr_(2)Si_(2)PO_(12)(NZSP)protection layer with high ionic conductivity of 2.94 m S/cm on Zn metal anode was fabricated by drop casting approach.The protection layer prevents Zn dendrites formation,hydrogen evolution as well as passivation,and facilitates a fast Zn~(2+)transport.As a result,the symmetric cells based on NZSP-coated Zn show a stable cycling over 1360 h at 0.5 m A/cm^(2)with 0.5 m Ah/cm^(2) and 1000 h even at a high current density of 5 m A/cm^(2) with 2 m Ah/cm^(2).Moreover,the full cells combined with V_(2)O_(5)-based cathode displays high capacities and high rate capability.This work offers a facile and effective approach to stabilizing Zn metal anode for enhanced ZIBs.

关键词： Na_(3)Zr_(2)Si_(2)PO_(12) high ionic conductivity Drop casting Surface coating Zinc metal anode Aqueous zinc-ion batteries

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：