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Chromium transformation driven by iron redox cycling in basalt-derived paddy soil with high geological background values

引用

Journal of Environmental Sciences 2023年第3期125卷 470-479页

作者： Ke Zhang Yang Yang Wenting Chi Guojun Chen Yanhong Du Shiwen Hu Fangbai Li Tongxu Liu Guangzhou Institute of Geochemistry Chinese Academy of SciencesGuangzhou 510640China National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and ManagementInstitute of Eco-environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China University of Chinese Academy of Sciences Beijing 100049China

The flooding and drainage of paddy fields has great effects on the transformation of heavy metals, however, the transformation of Cr in basalt-derived paddy soil with high geological background values was less recognized. The typical basalt-derived paddy soil was incubated under alternating redox conditions. The Cr fractions and the dynamics of Fe/N/S/C were examined. The HCl-extractable Cr increased under anaerobic condition and then decreased during aerobic stage. The UV-vis spectra of the supernatant showed that amounts of colloids were released under anaerobic condition, and then re-aggregated during aerobic phase. The scanning transmission electron microscopy(TEM) and X-ray photoelectron spectroscopy(XPS) revealed that Fe oxides were reduced and became dispersed during anaerobic stage, whereas Fe(Ⅱ) was oxidized and recrystallized under aerobic condition. Based on these results, a kinetic model was established to further distinguish the relationship between the transformation of Cr and Fe. During anaerobic phase, the reduction of Fe(Ⅲ) oxides not only directly released the structurally bound Cr, but also enhanced the breakdown of soil aggregation and dissolution of organic matter causing indirect mobilization of Cr. During aerobic phase, the oxidation of Fe (Ⅱ) and further recrystallization of newly formed Fe(Ⅲ) oxides might induce the re-aggregation of soil colloids and further incorporation of Cr. In addition,the kinetic model of Cr and Fe transformation was further verified in the pot *** model-based findings demonstrated that the Cr transformation in the basalt-derived paddy soil with high geological background values was highly driven by redox sensitive iron cycling.

关键词： Chromium Paddy soil Iron oxides Redox high geological background

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