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无真空、低成本Mist-CVD外延制备高质量单晶NiO/Ga_(2)O_(3)p-n异质结与器件

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Science China Materials 2024年第5期67卷 1646-1653页

作者：张泽雨林宋庆文刘丁赫闫奕如陈昊穆昌根陈大正冯倩张进成张玉明郝跃张春福 National Key Laboratory of Wide Bandgap Semiconductor Devices and Integrated Technology School of MicroelectronicsXidian UniversityXi’an710071China

在氧化镓(Ga_(2)O_(3))材料p型掺杂困难的背景下,Ga_(2)O_(3)p-n异质结器件在氧化镓器件的应用中起着重要作用.因此,寻找一种高效、经济的制备方法制备Ga_(2)O_(3)异质结对器件应用具有重要意义.在这项工作中,我们成功基于低成本、无真... 详细信息

在氧化镓(Ga_(2)O_(3))材料p型掺杂困难的背景下,Ga_(2)O_(3)p-n异质结器件在氧化镓器件的应用中起着重要作用.因此,寻找一种高效、经济的制备方法制备Ga_(2)O_(3)异质结对器件应用具有重要意义.在这项工作中,我们成功基于低成本、无真空的雾化学气相沉积(Mist-CVD)外延制备了单晶氧化镍(NiO)和β-Ga_(2)O_(3)异质结.其中,NiO(111)和β-Ga_(2)O_(3)(-201)的XRD摇摆曲线半高宽分别为0.077°和0.807°.NiO与β-Ga_(2)O_(3)之间的能带表现为Ⅱ型异质结构.基于此异质结,我们制备了准垂直器件,器件具有明显的p-n结整流特性,反向击穿电压为117 V.本工作为β-Ga_(2)O_(3)异质p-n结的制备提供了一种低成本、高质量的方法.

关键词： β-Ga_(2)O_(3) heterojunction structure p-n junctions NiO mist-CVD

Synthesis of AgCl/Ti_(3)C_(2)@TiO_(2)Ternary Composite Photocatalysts for Photocatalytic Oxidation of 1,4-Dihydropyridine and Tetracycline Hydrochloride

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China Petroleum Processing & Petrochemical Technology 2023年第2期25卷 10-23页

作者： Wu Hanliu Quan Yan Liu Meiling Tian Xuemei Ren Chunguang Wang Zhonghua Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province College of Chemistry and Chemical EngineeringChina West Normal UniversityNanchong 637002China College of Life Sciences Yantai UniversityYantai 264005China

AgCl/Ti_(3)C_(2)@TiO_(2)ternary composites were prepared to form a heterojunction structure between AgCl and TiO_(2)and introduce Ti3C2 as a cocatalyst.The as-prepared AgCl/Ti_(3)C_(2)@TiO_(2)composites showed higher photocatalytic activity than pure AgCl and Ti_(3)C_(2)@TiO_(2)for photooxidation of a 1,4-dihydropyridine derivative(1,4-DHP)and tetracycline hydrochloride(TCH)under visible light irradiation(λ>400 nm).The photocatalytic activity of AgCl/Ti_(3)C_(2)@TiO_(2)composites depended on Ti_(3)C_(2)@TiO_(2)content,and the catalytic activity of the optimized samples were 6.9 times higher than that of pure AgCl for 1,4-DHP photodehydrogenation and 7.3 times higher than that of Ti_(3)C_(2)@TiO_(2)for TCH photooxidation.The increased photocatalytic activity was due to the formation of a heterojunction structure between AgCl and TiO_(2)and the introduction of Ti3C2 as a cocatalyst,which lowered the internal resistance,sped up the charge transfer,and increased the separation efficiency of photogenerated carries.Photogenerated holes and superoxide radical anions were the major active species in the photocatalytic process.

关键词： AgCl/Ti_(3)C_(2)@TiO_(2) composite photocatalyst cocatalyst heterojunction structure in situ solvothermal growth method

Enhanced charge carrier injection in heterojunction organic field-effect transistor by inserting an MoO_3 buffer layer

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Chinese Physics B 2012年第11期21卷 416-420页

作者：于欣格于军胜黄伟曾红娟 State Key Laboratory of Electronic Thin Films and Integrated Devices School of Optoelectronic InformationUniversity of Electronic Science and Technology of China

A top-contact organic field-effect transistor （OFET） is fabricated by adopting a pentacene/1,11-bis（di-4- tolylaminophenyl） cyclohexane （TAPC） heterojunction structure and inserting an MoO3 buffer layer between the TAPC organic semiconductor layer and the source/drain electrode. The performances of the heterojunction OFET, including output current, field-effect mobility, and threshed voltage~ are all significantly improved by introducing the MoO3 thin buffer layer. The performance improvement of the modified heterojunction OFET is attributed to a better contact formed at the Au/TAPC interface due to the MoO3 thin buffer layer, thereby leading to a remarkable reduction of the contact resistance at the metal/organic interface.

关键词： organic field-effect transistor （OFET） MoOz buffer layer heterojunction structure con-tact resistance

Segmented Au/PtCo heterojunction nanowires for efficient formic acid oxidation catalysis

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Fundamental Research 2021年第4期1卷 453-460页

作者： Yingjun Sun Bolong Huang Yingjie Li Yingnan Qin Ziqi Fu Mingzi Sun Lei Wang Shaojun Guo School of Materials Science and Engineering Peking UniversityBeijing100871China College of Chemistry and Molecular Engineering Qingdao University of Science and TechnologyQingdao 266042China Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic UniversityHung HomKowloon 999077Hong Kong SARChina BIC-ESAT College of EngineeringPeking UniversityBeijing100871China

Exploring a new strategy for the removal of adsorbed CO (CO^(*)) on a Pt surface at a low potential is the key to achieving enhanced catalysis for the formic acid oxidation reaction (FAOR);however, the development of such a strategy remains a significant challenge. Herein, we report a class of Au/PtCo heterojunction nanowires (HNWs) as efficient electrocatalysts for accelerating the FAOR. This heterojunction structure and the induced Co alloying effects can facilitate formic acid adsorption/activation on Pt with high CO tolerance, generating the FAOR pathway from dehydration to dehydrogenation. The optimized Au_(23)/Pt_(63)Co_(14) HNWs showed the highest specific and mass activities of 11.7 mA cm^(−2)Pt and 6.42 A mg^(−1)Pt reported to date, respectively, which are considerably higher than those of commercial Pt/C. DFT calculations confirmed that the electron-rich Au segment enhances the electronic activity of the PtCo NWs, which not only allows the construction of a highly efficient electron transfer channel for the FAOR but also suppresses CO formation.

关键词： Formic acid oxidation reaction Pt-based catalyst heterojunction structure Nanowires Electrocatalysis

Highly stable aqueous rechargeable Zn-ion battery:The synergistic effect between NaV_(6)O_(15) and V_(2)O_(5) in skin-core heterostructured nanowires cathode

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Journal of Energy Chemistry 2021年第4期30卷 25-33页

作者： Lanlan Fan Zhenhuan Li Weimin Kang Bowen Cheng State Key Laboratory of Separation Membranes and Membrane Processes National Center for International Joint Research on Separation MembranesTiangong UniversityTianjin 300387China School of Materials Science and EngineeringTiangong UniversityTianjin 300387China School of Textiles Tiangong UniversityTianjin 300387China

The aqueous rechargeable Zn-ion batteries based on the safe,low cost and environmental benignity aqueous electrolytes are one of the most compelling candidates for large scale energy storage applications.However,pursuing suitable insertion materials may be a great challenge due to the strong electrostatic interaction between Zn^(^(2+))and cathode materials.Hence,a novel NaV_(6)O_(15)/V_(2)O_(5) skin-core heterostructure nanowire is reported via a one-step hydrothermal method and subsequent calcination for high-stable aqueous Zn-ion batteries(ZIBs).The NaV_(6)O_(15)/V_(2)O_(5) cathode delivers high specific capacity of 390 m Ah/g at 0.3 A/g and outstanding cycling stability of 267 m Ah/g at 5 A/g with high capacity retention over 92.3%after 3000 cycles.The superior electrochemical performances are attributed to the synergistic effect of skin-core heterostructured NaV_(6)O_(15)/V_(2)O_(5),in which the sheath of NaV_(6)O_(15) possesses high stability and conductivity,and the V_(2)O_(5) endows high specific capacity.Besides,the heterojunction structure not only accelerates intercalation kinetics of Zn^(2+)transport but also further consolidates the stability of the layers of V_(2)O_(5) during the cyclic process.This work provides a new perspective in developing feasible insertion materials for rechargeable aqueous ZIBs.

关键词： Aqueous zinc ion battery heterojunction structure High specific capacity Stable long cycle Synergistic effect