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Isolation of Hemicellulose from Wood Chips via Extraction with Kraft green liquor

Chemical Research in Chinese Universities 2010年第4期26卷 667-671页

作者： SUN Hui XU Ying-kai XU Guo-zhi Department of Material Science and Engineering China National Center for Quality Supervison ＆ Test of Plastic Products Beo＇ing Technology and Business University Beijing 100048 P. R. China Department of Surgery University of Pittsburg 3459 Fifth Avenue Pittsburgh PA USA

The present paper covers the extraction of hemicelluloses from woods, i.e., Eucalyptus Globulus, white fir and Douglas fir via green liquor pretreatment and alkali post-treatment with sodium hydroxide. The effects of such extraction conditions as extraction time, temperature on the yields of hemicellulose and the degree of deliginification were investigated. Sugar analyses using Dionex indicate that xylose, glucose and mannose are the main sugar types present in the hemicellulose from Eucalyptus. Other sugar components such as arabinose and galactose were also found in Dogulas fir hemicellulose. The highest yield of hemicellulose was 8.4% for Eucalyptus extracted with green liquor at 130 ℃ for 3.5 h. Further sodium hydroxide extraction for 5 h gave a hemicellulose yield of about 20%. The use of green liquor for the extraction of wood hemicellulose is believed to be the first attempt.

关键词： Hemicellulose Lignin Wood green liquor Alkali extraction

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Recovery of calcium carbonate waste as paper filler in the causticizing process of bamboo kraft pulping

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Journal of Bioresources and Bioproducts 2017年第2期2卷 82-88页

作者： Tian He Mingyou Liu South China University of Technology Guangzhou510640China

In this paper, calcium carbonate waste was recovered as paper filler from the causticizing process of bamboo kraft pulping. The effects of the causticizing process parameters on the filler qualities were investigated, in terms of the whiteness, tear strength, tensile strength and ash content of the filled paper. To investigate the effect of silica content on the qualities of the resultant calcium carbonate filler, the green liquor was desiliconized with aluminum salt modified bentonite prior to the causticizing process to obtain calcium carbonate of various silicon contents, particle size and brightness, and different crystal morphology. It was found that the ionic strength and silicate concentration were the two key factors in affecting the size and shape of the calcium carbonate particles formed in the causticizing process.

关键词： Bamboo Kraft Pulping green liquor Causticization Lime Mud Causticizing Calcium Carbonate PCC Paper Filler

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