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glass formation ability and Kinetics of the Gd55A120Ni25 Bulk Metallic glass

Chinese Physics Letters 2006年第3期23卷 672-674页

作者：赵哲龙夏雷丁鼎董远达 Institute of Materials Shanghai University Shanghai 200072Center for Advanced Microanalysis Shanghai University Shanghai 200444

We report a new bulk glass-forming alloy GdssA12oNi25. The bulk sample of the alloy is prepared in the shape of rods in diameter 2ram by suction casting. The rod exhibits typical amorphous characteristics in the x-ray diffraction pattern, paramagnetic property at 30OK, distinct glass transition and multi-step crystallization behaviour in differential scanning calorimetry traces. The gJass formation ability of the alloy is investigated by using the reduced glass transition temperature Trg and the parameter γ- Kinetics of glass transition and primary crystallization is also studied. The fragility parameter m obtained from the Vogel-Fulcher-Tammann dependence of glass transition temperature Tg on In φ （φ is the heating rate） classifies the bulk metallic glasses into the intermediate category according to Angell＇s classification.

关键词： glass formation ability Kinetics Bulk Metallic glass

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Critical Cooling Rate for the glass formation of Ferromagnetic Fe_(80)P_(13)C_7 Alloy

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Acta Metallurgica Sinica(English Letters) 2013年第1期26卷 56-62页

作者： Kai XU Yan WANG Jinfeng LI Qiang LI School of Physics Science and Technology Xinjiang University State Key Laboratory of Powder Metallurgy Central South University

In this paper the critical cooling rate, Rc, for the glass formation of Fe80P13C7 alloy has been determined using both Uhlmann＇s and Barandiaran-Colmenero＇s method. In Uhlmann＇s method, all kinds of the expres-sions of △G^l-s （T） and η/（T） determined using the different modes and methods had been investigated. It is indicated that the Rc for the glass formation of FesoP13C7 alloy can be estimated to be 349 K/s by Uhlmann＇s method based on the appropriate expressions of △G^l-s（T） and η/（T）. The calculated result accords with our experimental result. The Rc for the glass formation of Fe80P13C7 alloy has also been determined to be 0.49 K/s using Barandiaran-Colmenero＇s method. This resultant Rc is unreasonable low and it indicates that Barandiaran-Colmenero＇s method does not suit to Fe-based alloy.

关键词： glass formation ability Critical cooling rate Fe80P13C7 alloy

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glass formation,thermal and mechanical properties of ZrCuAlNi bulk metallic glasses

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Transactions of Nonferrous Metals Society of China 2018年第6期28卷 1157-1165页

作者： C.E.BORJA I.A.FIGUEROA O.LOZADA-FLORES M.ESTRADA G.A.LARA-RODRIGUEZ J.A.VERDUZCO Instituto de Investigacion en Metalurgia y Materiales Universidad Michoacana de San Nicolfis de Hidalgo (UMSNH)Fco. J. Mujica S/N Col. Felicitas del Rio C.P. 58030 Morelia Mich. Mexico Instituto de Investigaciones en Materiales Universidad Nacional Autonoma de Mdxico (UNAM) Circuito Exterior S/N Cd. Universitaria C.P. 04510 Cd. Mx. Mexico

The glass forming ability, thermal and mechanical properties of some Zr Cu Al Ni bulk metallic glasses were analyzed. The compositions of the alloys were theoretically determined with the dense packing and kinetic fragility index models. Cylindrical and conical ingots were produced by copper mould suction-casting under Ar atmosphere. The conical ingots were characterized by means of X-ray diffraction in order to determine the glassy structure. It was found that both alloys have a critical glassy diameter, Dc, of 3 mm. Thermal behaviours were investigated by differential scanning calorimetry at heating rates of 0.5, 0.67 and 0.83 K/s. The gamma parameter γ, supercooled liquid region ΔTx, and reduced glass transition temperature Trg, of the experimentally obtained glasses indicated high glass forming ability. The glassy compositions showed a fragility index of ~40 GPa. The compression test of the investigated alloys was carried out at a strain rate of 0.016 s^-1, obtaining a elastic modulus of ~83 GPa, total deformation of ~5%, yield strength of 1.6 GPa and hardness of 4 GPa. It was concluded that the use of the dense packing and kinetic fragility index models helped to predict glass-forming compositions in the family alloy investigated.

关键词： bulk metallic glass glass formation ability fragility index packing efficiency suction casting

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