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generalized stability criterion for controlling solidification segregation upon twin-roll casting

Journal of Materials Science & Technology 2023年第3期134卷 163-177页

作者： Pan Wu Yubing Zhang Jiaqi Hu Shaojie Song Yong Li Huiyuan Wang Guo Yuan Zhaodong Wang Shizhong Wei Feng Liu State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Analytical and Testing Center Northwestern Polytechnical UniversityXi’an 710072China State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819China State Key Laboratory of Super hard Materials Jilin UniversityChangchun 130012China National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials Henan University of Science and TechnologyLuoyang 471003China

Macro-and micro-segregation formed upon twin-roll casting(TRC)can be inherited from sub-rapid solid-ification to solid-state transformation,even to plastic deformation,thus deteriorating drastically mechan-ical properties of as-produced thin *** many works focusing mainly on controlling fields of thermal,concentration and convection have been reported,how to control artificially and quantitatively the segregation using a theoretical connection between processing parameters and solidification models,has not been realized,*** it,a systematical framework integrating non-equilibrium dendritic growth and overall solidification kinetics with the TRC parameters,was constructed applying a general-ized stability(GS)conception deduced from transient thermodynamic driving force△G^(t)and transient ki-netic energy barrier Q_(eff)^(t)evolving upon *** from this framework considering synergy of thermodynamics and kinetics(i.e.,thermo-kinetic synergy),a criterion of high△G^(t)-high GS guaranteed that the macro(i.e.,the centerline)and the micro(i.e.,the edge)segregation can be suppressed by in-creasing△G^(t)and GS at the beginning and the ending stage of sub-rapid solidification,*** typical thermo-kinetic combination producing the microstructure can be inherited into the plastic de-formation,as reflected by corresponding strength-ductility *** work realized quantitative controlling of TRC by a theoretical connection between processing parameters and solidification models,where,an optimization for sub-rapid solidification segregation using the GS conception including△G^(t)and Q_(eff)^(t)has been performed.

关键词： Segregation Sub-rapid solidification generalized stability Twin-roll casting Thermo-kinetics

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Thermo-kinetic connectivity by integrating thermo-kinetic correlation and generalized stability

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Journal of Materials Science & Technology 2022年第32期127卷 225-235页

作者： Yuqing He Shaojie Song Jinglian Du Haoran Peng Zhigang Ding Huaiyu Hou Linke Huang Yongchang Liu Feng Liu State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Analytical&Testing Center Northwestern Polytechnical UniversityXi’an 710072China School of Materials and Chemical Engineering Xi’an Technological UniversityXi’an 710021China Nano and Heterogeneous Materials Center School of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing 210094China State Key Lab of Hydraulic Engineering Simulation and Safety School of Materials Science&EngineeringTianjin UniversityTianjin 300072China

Designing structured materials with optimized mechanical properties generally focuses on engineering microstructures,which are closely determined by the processing routes,such as phase transformations(PTs)and plastic deformations(PDs).Both PTs and PDs follow inherent trade-off relation between thermodynamic driving force ΔG and kinetic energy barrier Q,i.e.,so-called thermo-kinetic *** analyzing nucleation and growth and proposing a conception of negative driving force integrating strain energy,interface energy and any kind of energy that equivalently inhibits the PT itself,ΔG^(S),unified expressions for the thermo-kinetic correlation and generalized stability(GS)were derived for three kinds of PTs,i.e.,diffusive PTs with simultaneously decreasedΔG and increased Q,diffusive PTs with simultaneously increasedΔG and decreased Q,and displacive PTs with simultaneously increased ΔG and decreased *** leads to so-called thermo-kinetic connectivity by integrating the thermo-kinetic correlation and the GS,where,by application in typical PTs,it was clearly shown,a criterion of high ΔG-high GS can be predicted by modulating chemical driving force,negative driving force and kinetic energy barrier for diffusion or *** thermo-kinetic connectivity,analogous procedure for dislocation evolution upon PDs was performed,and materials design in terms of the highΔG-high GS criterion was discussed and prospected.

关键词： Thermo-kinetic correlation Negative driving force generalized stability Thermo-kinetic connectivity

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Optimizing mechanical properties of magnesium alloys by philosophy of thermo-kinetic synergy:Review and outlook

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Journal of Magnesium and Alloys 2022年第2期10卷 346-383页

作者： Tianle Wang Feng Liu State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’anShaanxi 710072China Analytical&Testing Center Northwestern Polytechnical UniversityXi’anShaanxi 710072China

Although several strategies(including grain refinement,texture adjustment,precipitation hardening,etc.)have been verified to effectively improve the mechanical properties of lightweight magnesium(Mg)alloys,considerable efforts are still needed to be made to comprehensively understand the potential mechanisms controlling complex microstructures and deformation behaviors exhibited by the hexagonal close-packed host lattice of Mg,thus assisting the rational design of materials at a more physical *** the cornerstone of this review,a universal rule,the so-called synergy of thermodynamics and kinetics(i.e.,thermo-kinetic diversity,correlation and connectivity),including a recently proposed theory of generalized stability(GS),is introduced to deepen our understanding on common behaviors in Mg alloys(i.e.,deformations(slip and twining modes),phase transformations(especially for precipitations)and interactions in between)at a new *** by the GS theory,typical cases for Mg alloys design are qualitatively evaluated to reemphasize the traditional strengthening and toughening strategies mentioned above and to illuminate their exquisite coordination for breaking through the trade-off relationship between strength and ductility,corresponding to a typical thermo-kinetic pair(i.e.,high driving force(ΔG)-high GS).To produce the Mg alloys with superior strength-ductility balances,the potential capacity of this GS theory for guiding processing path design is discussed,finally。

关键词： Magnesium alloys Synergy of thermodynamics and kinetics generalized stability Superior strength-ductility balance

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FOURIER　PSEUDOSPECTRAL－FINITE　DIFFERENCE　METHOD　FOR　TWO－DIMENSIONAL　VORICITY　EQUATION

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Chinese Annals of Mathematics,Series B 1994年第4期15卷 469-488页

作者： GUO BENYU XIONG YUESHAN(Department of Mathematics,Shanghai University of Science and Technology f Shanghai 201800,China.) SHANGHAI UNIV SCI & TECHNOL DEPT MATHSHANGHAI 201800PEOPLES R CHINA

A Fourier pseudospectral-finite difference sheme is proposed for solving two-dimensionalvorticity equations. The generalized stability and the convergence are *** numericalresults are given.

关键词： Vorticity equation Fourier pseudospectral-finite difference method generalized stability Convergence.

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