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Tracking gassing behavior in pouch cell by operando on-line electrochemical mass spectrometry

Journal of Energy Chemistry 2023年第9期84卷 286-291页

作者： Haitang Zhang Jianken Chen Baodan Zhang Xiaohong Wu Zhengang Li Leiyu Chen Junhao Wang Xiaoyu Yu Haiyan Luo Jiyuan Xue Yu-Hao Hong Yu Qiao Shi-Gang Sun State Key Laboratory of Physical Chemistry of Solid Surfaces iChEM(Collaborative Innovation Center of Chemistry for Energy Materials)Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005FujianChina Fujian Science&Technology Innovation Laboratory for Energy Materials of China(Tan Kah Kee Innovation Laboratory) Xiamen 361005FujianChina

As the rapid development of more powerful and safer lithiumion batteries, the mechanism study of gases evolution is attacking more and more attention in recent years. Especially under overcharge/discharge and/or high-... 详细信息

关键词： Pouch cell Operando characterization Mass spectrometry Lithium-ion batteries gassing behavior

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P2-type layered high-entropy oxides as sodium-ion cathode materials

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Materials Futures 2022年第3期1卷 171-184页

作者： Junbo Wang Sören L Dreyer Kai Wang Ziming Ding Thomas Diemant Guruprakash Karkera Yanjiao Ma Abhishek Sarkar Bei Zhou Mikhail V Gorbunov Ahmad Omar Daria Mikhailova Volker Presser Maximilian Fichtner Horst Hahn Torsten Brezesinski Ben Breitung Qingsong Wang Institute of Nanotechnology Karlsruhe Institute of Technology(KIT)Hermann-von-Helmholtz-Platz 176344 Eggenstein-LeopoldshafenGermany Helmholtz Institute Ulm(HIU)Electrochemical Energy Storage Helmholtzstrasse 1189081 UlmGermany Joint Research Laboratory Nanomaterials-Technische Universität Darmstadt and Karlsruhe Institute of Technology(KIT) Otto-Berndt-Strasse 364206 DarmstadtGermany Leibniz Institute for Solid State and Materials Research(IFW)Dresden Helmholtzstrasse 2001069 DresdenGermany INM-Leibniz Institute for New Materials Campus D2266123 SaarbrückenGermany Department for Materials Science and Engineering Saarland UniversityCampus D2266123 SaarbrückenGermany Saarene Saarland Center for Energy Materials and SustainabilityCampus C4266123 SaarbrückenGermany Bavarian Center for Battery Technology(BayBatt) University of BayreuthUniversitätsstrasse 3095447 BayreuthGermany Department of Chemistry University of BayreuthUniversitätsstrasse 3095447 BayreuthGermany

P2-type layered oxides with the general Na-deficient composition Na_(x)TMO_(2)(x<1,TM:transition metal)are a promising class of cathode materials for sodium-ion *** open Na+transport pathways present in the structure lead to low diffusion barriers and enable high charge/discharge ***,a phase transition from P2 to O2 structure occurring above 4.2 V and metal dissolution at low potentials upon discharge results in rapid capacity *** this work,we demonstrate the positive effect of configurational entropy on the stability of the crystal structure during battery *** different compositions of layered P2-type oxides were synthesized by solid-state chemistry,Na_(0.67)(Mn_(0.55)Ni_(0.21)Co_(0.24))O_(2),Na_(0.67)(Mn_(0.45)Ni_(0.18)Co_(0.24)Ti_(0.1)Mg_(0.03))O_(2) and Na_(0.67)(Mn_(0.45)Ni_(0.18)Co_(0.18)Ti_(0.1)Mg_(0.03)Al_(0.04)Fe_(0.02))O_(2) with low,medium and high configurational entropy,*** high-entropy cathode material shows lower structural transformation and Mn dissolution upon cycling in a wide voltage range from 1.5 to 4.6 *** operando techniques and post-mortem analysis were used to probe the underlying reaction mechanism ***,the high-entropy strategy is a promising route for improving the electrochemical performance of P2 layered oxide cathodes for advanced sodium-ion battery applications.

关键词： P2-type layered cathode high-entropy oxides sodium-ion battery gassing behavior manganese leaching

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