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Confined gas transport in low-dimensional materials

International Journal of Smart and Nano Materials 2024年第1期15卷 127-164页

作者： Hongwei Duan Zeyu Zhuang Jing Yang Shengping Zhang Luda Wang National Key Laboratory of Advanced Micro and Nano Manufacture Technology School of Integrated CircuitsPeking UniversityBeijingChina Academy for Advanced Interdisciplinary Studies and Center for Nanochemistry Beijing Science and Engineering Center for NanocarbonsPeking UniversityBeijingChina Beijing Advanced Innovation Center for Integrated Circuits BeijingChina Technology Innovation Center of Graphene Metrology and Standardization for State Market Regulation Beijing Graphene instituteBeijingChina

gas transport under confinement exhibits a plethora of physical and chemical phenomena that differ from those observed in bulk media,owing to the deviations of continuum description at the molecular *** biological systems,gas channels play indispen-sable roles in various physiological functions by regulating gas transport across cell ***,investigating gas trans-port under such confinement is crucial for comprehending cellular physiological ***,leveraging these underlying mechanisms can enable the construction of bioinspired artificial nanofluidic devices with tailored gas transport properties akin to those found in biological *** review provides a comprehensive summary of confined gas transport mechanisms,focusing on the unique effects arising from ***,we categorize nanoconfinement spaces based on dimensionality to elucidate their control over gas transport ***,we highlight the potential of bioinspired smart gas membranes that mimic precise modulation of transportation observed in *** conclude,we present a concise outlook on the challenges and opportunities in this rapidly expanding field.

关键词： Nanofluidics gas transport transport mechanism low-dimensional materials smart membranes

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Reconcile the contradictory wettability requirements for the reduction and oxidation half-reactions in overall CO_(2) photoreduction via alternately hydrophobic surfaces

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Journal of Energy Chemistry 2024年第6期93卷 202-212,I0006页

作者： Hailing Huo Ting Hu Chengxi Huang Fang Wu Tongyu Wang Xuan Liu Liang Zhang Qiang Ju Zhiqing Zhong Hongbin Xing Erjun Kan Ang Li MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing Nanjing University of Science and TechnologyNanjing 210094JiangsuChina College of Information Science and Technology Nanjing Forestry UniversityNanjing 210037JiangsuChina

The overall photocatalytic CO_(2) reduction reaction(OPCRR)that can directly convert CO_(2) and H_(2)O into fuels represents a promising renewable energy conversion *** a typical redox reaction,the OPCRR involves two half-reactions:the CO_(2) reduction half-reaction(CRHR)and the water oxidation half-reaction(WOHR).Generally,both half-reactions can be promoted by adjusting the wettability of ***,there is a contradiction in wettability requirements for the two ***,CRHR prefers a hydrophobic surface that can accumulate more CO_(2) molecules on the active sites,ensuring the appropriate ratio of gas-phase(CO_(2))to liquid-phase(H_(2)O)***,the WOHR prefers a hydrophilic surface that can promote the departure of the gaseous product(O_(2))from the catalyst surface,preventing isolation between active sites and the reactant(H_(2)O).Here,we successfully reconciled the contradictory wettability requirements for the CRHR and WOHR by creating an alternately hydrophobic *** was achieved through a selectively hydrophobic modification method and a charge-transfer-control ***,the collaboratively promoted CRHR and WOHR led to a significantly enhanced OPCRR with a solar-to-fuel conversion efficiency of 0.186%.Notably,in ethanol production,the catalyst exhibited a 10.64-fold increase in generation rate(271.44μmol g^(-1)h~(-1))and a 4-fold increase in selectivity(55.77%)compared to the benchmark *** innovative approach holds great potential for application in universal overall reactions involving gas participation.

关键词： Hydrophobic Hydrophilic gas transport Overall CO_(2)photoreduction Z-scheme

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Preparation and gas Permeation of Supported γ-Al_2O_3 Membranes Used as Substrate Layer for Microporous Membranes

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Journal of Wuhan University of Technology(Materials Science) 2005年第3期20卷 27-30页

作者：韦奇 Department of Materials Science & Engineering University of Science & Technology of China College of Materials Science & Engineering Beijing University of Technology Beijing 100022China

γ-Al2O3 membranes were successfidly deposited on the top of porous α-Al2O3 support by sol-gel process and characterized by means of XRD , SEM, N2 adsorption and gas permeation. The γ-Al2O3 membranes, free of pin-holes and cracks, adhere tightly to the supports and have a thlekness of about 7μm. When sintered at 400 ℃ , γ-Al2O3 membranes have a rutrrow pore size distribution, with a pore diameter of 3.6nm, and the transport of both H2 and CO2 in supported γ-Al2O3 membrane is governed by Knudsen mechanism, with H2 permeance of 3.3× 10^-6 molm^-2Pa^-1s^-1 and H2/ CO2 permselectivity close to the ideal Knudsen value at 50 ℃ . The γ-Al2O3 membranes are suitable for being used as the substrates of microparoas membranes .

关键词： supported γ-Al2O3 membranes hydrogen separation gas transport

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Confinement effect on CO_(2)and CH_(4)permeability in shale

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Energy Geoscience 2024年第1期5卷 256-263页

作者： Vikram Vishal Tuli Bakshi Computational and Experimental Geomechanics Laboratory Department of Earth SciencesIndian Institute of Technology BombayMumbai400076India National Centre of Excellence in Carbon Capture and Utilization Indian Institute of Technology BombayMumbai400076India

gas flow in shales follows a number of physical mechanisms that include Knudsen diffusion,Darcy flow,and adsorption in the matrix and micro *** aim of the study is to resolve the interplay of gas transport in these media at increased effective stress as well as net pore *** this research,we investigated the nature of gas transport in the matrix of shale by sending He,CH_(4)and CO_(2)gases through a transient upstream pressure pulse decay instrument.A series of experiments were conducted at constant pore pressures and a gradually increasing confining *** same study was done in three different scenarios,injecting He,CO_(2)and CH_(4).At a constant pore pressure,gas permeability appears to decrease with an increasing confining pressure and effective *** increasing effective stress,the slip factor also decreases along with the *** decrease in slip could be attributed to prestressing,that is likely to create new *** the three purged gases,permeability of shale to CH_(4)is the highest,and that to CO_(2)is the lowest owing to its high *** permeability of CH_(4)against He,could be attributed to the dual transport mechanism.

关键词： Energy Porous media gas transport Effective stress

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A multi-scale model for CO_(2) sequestration enhanced coalbed methane recovery

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Frontiers of Chemical Science and Engineering 2009年第1期3卷 20-25页

作者： G.X.WANG X.R.WEI V.RUDOLPH C.T.WEI Y.QIN School of Engineering University of QueenslandSt Lucia Qld 4072Australia School of Resources and Geoscience China University of Mining&TechnologyXuzhou 221008China

This paper presents a multi-scale model to simulate the multicomponent gas diffusion andﬂow in bulk coals for CO_(2) sequestration enhanced coalbed methane *** model is developed based on a bi-dispersed structure model by assuming that coal con-sists of microporous micro-particles,meso/macro-pores and open *** bi-disperse diffusion theory and the Maxwell-Stefan approach were incorporated in the model,providing an improved simulation of the CH4-CO_(2)/CH4-N2 counter diffusion *** the model,the counter diffusion process is numerically coupled with theﬂow of the mixture gases occurring within macro-pores or fractures in coal so as to account for the interaction between diffusion andﬂow in gas transport through *** model was validated by both experimental data from literature and our CO_(2)ﬂush tests,and shows an excellent agreement with the *** results reveal that the gas diffusivities,in particular the micro-pore diffusivities are strongly concentration-dependent.

关键词： multi-scale model gas transport coal coalbed methane CO_(2)sequestration

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