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Steel slag carbonation in a flow-through reactor system:The role of fluid-flux

Journal of Environmental Sciences 2015年第1期27卷 266-275页

作者： Eleanor J.Berryman Anthony E.Williams-Jones Artashes A.Migdisov Department of Earth and Planetary Sciences McGill University Technische Universitat Berlin Los Alamos National Laboratory

Steel production is currently the largest industrial source of atmospheric CO2. As annual steel production continues to grow, the need for effective methods of reducing its carbon footprint increases correspondingly. The carbonation of the calcium-bearing phases in steel slag generated during basic oxygen furnace（BOF） steel production, in particular its major constituent, larnite {Ca2SiO4}, which is a structural analogue of olivine {（MgFe）2SiO4}, the main mineral subjected to natural carbonation in peridotites, offers the potential to offset some of these emissions. However, the controls on the nature and efficiency of steel slag carbonation are yet to be completely understood. Experiments were conducted exposing steel slag grains to a CO2–H2O mixture in both batch and flow-through reactors to investigate the impact of temperature, fluid flux, and reaction gradient on the dissolution and carbonation of steel slag. The results of these experiments show that dissolution and carbonation of BOF steel slag are more efficient in a flow-through reactor than in the batch reactors used in most previous studies. Moreover, they show that fluid flux needs to be optimized in addition to grain size, pressure, and temperature, in order to maximize the efficiency of carbonation. Based on these results, a two-stage reactor consisting of a high and a low fluid-flux chamber is proposed for CO2 sequestration by steel slag carbonation,allowing dissolution of the slag and precipitation of calcium carbonate to occur within a single flow-through system.

关键词： CO2sequestration Steel slag carbonation flow-through reactor Fluid flux

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Degradation of micropolluants in flow-through VUV/UV/H2O2 reactors: Effects of H2O2 dosage and reactor internal diameter

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Journal of Environmental Sciences 2021年第12期33卷 28-37页

作者： Lumeng Zhan Wentao Li Li Liu Tao Han Mengkai Li Zhimin Qiang 无 Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Department of Geosciences and Natural Resource Management University of CopenhagenFrederiksberg C 1985Denmark Sino-Danish College University of Chinese Academy of SciencesBeijing 100049China School of Environmental Science and Engineering Qingdao UniversityQingdao 266071China

The degradation of atrazine (ATZ),sulfamethoxazole (SMX) and metoprolol (MET) in flowthrough VUV/UV/H2O2reactors was investigated with a focus on the effects of H2O2dosage and reactor internal diameter (ID).Results showed that the micropollutants were degraded efficiently in the flow-through VUV/UV/H2O2reactors following the pseudo first-order kinetics (R2>0.92).However,the steady-state assumption (SSA) kinetic model being vital in batch reactors was found invalid in flow-through reactors where fluid mixing was less *** the increase of H2O2dosage,the ATZ removal efficiency remained almost constant while the SMX and MET removal was enhanced to different extents,which could be explained by the different reactivities of the pollutants towards HO·.A larger reactor ID resulted in lower degradation rate constants for all the three pollutants on account of the lower average fluence rate,but the change in energy efficiency was much more *** reality,the electrical energy per order (EEO) of the investigated VUV/UV/H2O2treatments ranged between 0.14–0.20,0.07–0.14 and 0.09–0.26 k Wh/m3/order for ATZ,SMX and MET,respectively,with the lowest EEOfor each pollutant obtained under varied H2O2dosages and reactor *** study has demonstrated the efficiency of VUV/UV/H2O2process for micropollutant removal and the inadequacy of the SSA model in flow-through reactors,and elaborated the influential mechanisms of H2O2dosage and reactor ID on the reactor performances.

关键词： VUV/UV/H2O2 flow-through reactor Degradation H2O2 dosage reactor internal diameter

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