检索结果-南通市图书馆

FePO4-coated Li[Li0.2Ni0.13Co0.13Mn0.54]O2 with improved cycling performance as cathode material for Li-ion batteries

引用

Rare Metals 2017年第11期36卷 899-904页

作者： Zhong Wang Hua-Quan Lu Yan-Ping Yin Xue-Yi Sun Xiang-Tao Bai Xue-Ling Shen Wei-Dong Zhuang Shi-Gang Lu R&D Center for Vehicle and Energy Storage General Research Institute of Nonferrous Metals Beijing 100088 China China Automotive Battery Research Institue Co. Ltd Beijing 100088 China

Li[Li0.2Ni0.13Coo.13Mn0.54]O2 cathode materials were synthesized by carbonate-based co-precipitation method, and then, its surface was coated by thin layers of FePO4. The prepared samples were characterized by X-ray diffraction （XRD）, field emission scanning electron micro- scope （FESEM）, energy-dispersive spectroscopy （EDS）, and transmission electron microscopy （TEM）. The XRD and TEM results suggest that both the pristine and the coated materials have a hexagonal layered structure, and the FePO4 coating layer does not make any major change in the crystal structure. The FePO4-coated sample exhibits both improved initial discharge capacity and columbic efficiency compared to the pristine one. More significantly, the FePO4 coating layer has a much positive influence on the cycling perfor- mance. The FePO4-coated sample exhibits capacity reten- tion of 82 % after 100 cycles at 0.5℃ between 2.0 and 4.8 V, while only 28 % for the pristine one at the same charge-discharge condition. The electrochemical impe- dance spectroscopy （EIS） results indicate that this improved cycling performance could be ascribed to the presence of FePO4 on the surface of Li[Li0.2Ni0.13Co0.13Mno.54102 par- ticle, which helps to protect the cathode from chemical attacks by HF and thus suppresses the large increase in charge transfer resistance.

关键词： cathodes Charge transfer Coated materials Coatings Crystal structure Electric batteries Electrochemical impedance spectroscopy Electrodes Energy dispersive spectroscopy field emission cathodes High resolution transmission electron microscopy Lithium Lithium alloys Lithium compounds Manganese Nickel Precipitation (chemical) Scanning electron microscopy Secondary batteries Transmission electron microscopy X ray diffraction

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Transmission-mode GaN photocathode based on graded Al_xGa_(1-x)N buffer layer

引用

Chinese Optics Letters 2011年第1期9卷 17-20页

作者：杜晓晴常本康钱芸生高频 Key Laboratory of Optoelectronic Technology and Systems of Ministry of Education of China College of Optoelectronic EngineeringChongqing University Institute of Electronic Engineering and Opto-Electric Technology Nanjing University of Science and Technology

We create a GaN photocathode based on graded AlxGa1-xN buffer layers to overcome the influence of buffer-emission layer interface on the photoemission of transmission-mode GaN photocathodes. A gate- shaped spectral response with a 260-nm starting wavelength and a 375-nm cut-off wavelength is obtained. Average quantum efficiency is 15% and short wavelength responses are almost equivalent to long wavelength ones. The fitted interface recombination velocity is 5×10^4 cm/s, with negligible magnitude, proving that the design of the graded buffer layers is efficient in obtaining good interface quality between the buffer and the emission laver.

关键词： Buffer layers Epitaxial layers field emission cathodes Gallium nitride Optical waveguides Photocathodes

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：