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Two-dimensional metal-organic framework nanosheet composites:Preparations and applications

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Chinese Chemical Letters 2022年第2期33卷 693-702页

作者： Yutian Qin Yue Wan Jun Guo Meiting Zhao School of Chemistry Tiangong UniversityTianjin 300387China Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistryInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China

As emerging two-dimensional materials, metal-organic framework(MOF) nanosheet composites possess many unique physical and chemical properties, thus being expected to be widely applied in gas separation and adsorption, energy conversion and storage, heterogeneous catalysis, sensing as well as biomedicine. In this review, we first introduce the methods for integrating MOF nanosheets with other materials to prepare multifunctional composites. Next, the applications of MOF nanosheet composites in versatile fields are summarized and discussed. We hope this review will be instructive for researchers in the aspects of designs, preparations and applications of MOF nanosheet composites.

关键词： Metal-organic framework 2D nanosheet Composite energy conversion Catalysis Separation Biomedicine

In Situ Synthesis of Cu_(3)P/P-Doped g-C_(3)N_(4)Tight 2D/2D Heterojunction Boosting Photocatalytic H2 Evolution

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Chinese Journal of Chemistry 2023年第2期41卷 173-180页

作者： Fangyong Hou Feng Liu Haochen Wu Muhammad Qasim Yi Chen Yang Duan Zhibo Feng Maochang Liu International Research Center for Renewable energy&State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'anShaanxi 710049China School of Electronic Engineering Jiujiang UniversityJiujiangJiangxi 332005China Gree Altairnano New energy Inc ZhuhaiGuangdong 519040China Suzhou Academy of Xi'an Jiao tong University SuzhouJiangsu 215123China

Heterojunction design in a two-dimensional(2D)fashion has been deemed beneficial for improving the photocatalytic activity of g-C_(3)N_(4)because of the promoted interfacial charge transfer,yet still facing challenges.Herein,we construct a novel 2D/2D Cu_(3)P nanosheet/P-doped g-C_(3)N_(4)(PCN)nanosheet heterojunction photocatalyst(PCN/Cu_(3)P)through a simple in-situ phosphorization treatment of 2D/2D CuS/g-C_(3)N_(4)composite for photocatalytic H2 evolution.We demonstrate that the 2D lamellar structure of both CuS and g-C_(3)N_(4)could be well reserved in the phosphorization process,while CuS and g-C_(3)N_(4)in-situ transformed into Cu_(3)P and PCN,respectively,leading to the formation of PCN/Cu_(3)P tight 2D/2D heterojunction.Owing to the large contact area provided by intimate face-to-face 2D/2D structure,the PCN/Cu_(3)P photocatalyst exhibits significantly enhanced charge separation efficiency,thus achieving a boosted visible-light-driven photocatalytic behavior.The highest rate for H2 evolution reaches 5.12 umol·h^(-1),nearly 24 times and 368 times higher than that of pristine PCN and g-C_(3)N_(4),respectively.This work represents an excellent example in elaborately con-structing g-C_(3)N_(4)-based 2D/2D heterostructure and could be extended to other photocatalyst/co-catalyst system.

关键词： Photocatalysis Water splitting 2D/2D heterojunction g-C_(3)N_(4) energy conversion Charge transfer Nanosheet photocatalyst

Black Phosphorus Nanosheets Enhance Photophosphorylation by Positive Feedback

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Chinese Journal of Chemistry 2022年第8期40卷 939-945页

作者： Zhenzhen Dong Jinbo Fei Tonghui Wang Xia Xu Weiguang Dong Junbai Li Beijing National Laboratory for Molecular Sciences(BNLMS) CAS Key Lab of ColloidInterface and Chemical ThermodynamicsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China

We construct a natural-artificial hybrid architecture containing black phosphorus nanosheets(BPNS)to enhance photosynthesis of chloroplast in a positive-feedback manner.In this architecture,oxygen yielded by photosynthesis during water splitting by photosystemⅡpromotes the photoreaction of BPNS to produce proton and inorganic phosphate(Pi).Further,transmembrane proton gradient is increased to drive ATP synthase to synthesize ATP.Meanwhile,additional photogenerated electrons produced by BPNS are transferred to the photosynthesis process.As a consequence,photosynthesis performed by chloroplast is improved.Quantitatively,photophosphorylation efficacy of the hybrid system is increased by 1.89 times in the case of Pi deficiency.This work offers a new path to enhance solar-to-chemical energy conversion,holding promise in boosting natural photosynthesis.

关键词： Black phosphorus nanosheets Electron transport energy conversion Photosynthesis Positive feedback

Recent status and advanced progress of tip effect induced by micro-nanostructure

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中国化学快报:英文版 2023年第8期34卷 102-113页

作者： Jingwen Li Junan Pan Weinan Yin Yuntao Cai Hao Huang Yuhao He Gu Gong Ye Yuan Chengpeng Fan Qingfeng Zhang Longlu Wang College of Electronic and Optical Engineering&College of Flexible Electronics(Future Technology) Nanjing University of Posts&Telecommunications(NJUPT)Nanjing 210023China School of Materials Science and Engineering Xiangtan UniversityXiangtan 411105China

The unique structural features represented by micro-nanoneedle tip structure reflect wonderful physical and chemical properties.The tip effect includes the concentration of energy such as electrons,photons and magnetism in the tip region,which has promising applications in the fields of energy conversion,water capture,environmental restoration and so on.In this review,a comprehensive and systematic summary of the latest advances in the application of the tip effect in different fields is provided.Utilizing advanced Finite Difference Time Domain simulation,we further propose our understanding of the fundamental mechanism of the tip effect induced by micro-nanostructure.However,we need to forge the present study to further reveal the essential law of the tip effect from the perspective of theoretical calculations.This review would provide a solid foundation for further development and application of the tip effect.

关键词： Tip effect Finite difference time domain simulation energy conversion Water capture Environmental restoration

Engineering sulfur vacancies for boosting electrocatalytic reactions

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中国化学快报:英文版 2023年第9期34卷 34-44页

作者： Xianxu Chu Yueyu Liao Lu Wang Junru Li Hui Xu Henan Key Laboratory of Biomolecular Recognition and Sensing College of Chemistry and Chemical EngineeringShangqiu Normal UniversityShangqiu 476000China Key Laboratory of Advanced Catalytic Materials and Technology Advanced Catalysis and Green Manufacturing Collaborative Innovation CenterChangzhou UniversityChangzhou 213164China

Transition metal sulfides are demonstrated to play an increasingly important role in boosting the deployment of ecofriendly electrocatalytic energy conversion technologies.It is also widely recognized that the introduction of vacancies is now becoming an important and valid approach to promote the electrocatalytic performance.In this review,the significance of sulfur vacancies on the enhancement of catalytic performance via four main functionalities,including tuning the electronic structure,tailoring the active sites,improving the electrical conductivity,and regulating surface reconstruction,is comprehensively summarized.Many effective strategies for the sulfur vacancy engineering,such as plasma treatment,heteroatom doping,and chemical reduction are also comprehensively provided.Subsequently,recent achievements in sulfur vacancy fabrication on various hotspot electrocatalytic reactions are also systematically discussed.Finally,a summary of the recent progress and challenges of this interesting field are organized,which hopes to guide the future development of more efficient metal sulfide electrocatalysts.

关键词： Sulfur vacancy Electrocatalytic reactions Functionalities Surface properties energy conversion

Analysis of temperature distribution in PV-integrated electrochemical flow cells

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Materials Futures

Materials Futures 2023年第4期2卷 137-144页

作者： Dorian Santander Shaun Whitley Jungmyung Kim Dowon Bae Institute of Mechanical Process and Energy Engineering(IMPEE)School of Engineering and Physical SciencesHeriot-Watt UniversityEdinburgh EH144ASUnited Kingdom Ecole nationale supérieure d’électricitéet de mécanique de Nancy Vandoeuvre-lès-NancyFrance AECOM EdinburghEH35DAUnitedKingdom

Photovoltaic(PV)-integrated flow cells for electrochemical energy conversion and storage underwent a huge development.The advantages of this type of integrated flow cell system include the simultaneous storage of solar energy into chemicals that can be readily utilized for generating electricity.However,most studies overlook the practical challenges arising from the inherent heat exposure and consequent overheating of the reactor under the sun.This work aims to predict the temperature profiles across PV-integrated electrochemical flow cells under light exposure conditions by introducing a computational fluid dynamics–based method.Furthermore,we discuss the effects of the flow channel block architecture on the temperature profile to provide insights and guidelines for the effective remedy of overheating.

关键词： solar redox flow battery CFD redox flow cell energy conversion temperature profile

Realizing Stable Carbonate Electrolytes in Li-O_(2)/CO_(2)Batteries

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Chinese Journal of Chemistry 2023年第3期41卷 314-321页

作者： Kai Chen Jia-Yi Du Jin Wang Dong-Yue Yang Jiang-Wei Chu Hao Chen Hao-Ran Zhang Gang Huang Xin-Bo Zhang State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchunJilin130022 China School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefeiAnhui230026 China

The increasing demand for high-energy storage systems has propelled the development of Li-air batteries and Li-O_(2)/CO_(2)batteries to elucidate the mechanism and extend battery life.However,the high charge voltage of Li2CO3 accelerates the decomposition of traditional sulfone and ether electrolytes,thus adopting high-voltage electrolytes in Li-O_(2)/CO_(2)batteries is vital to achieve a stable battery system.Herein,we adopt a commercial carbonate electrolyte to prove its excellent suitability in Li-O_(2)/CO_(2)batteries.The generated superoxide can be captured by CO_(2)to form less aggressive intermediates,stabilizing the carbonate electrolyte without reactive oxygen species induced decomposition.In addition,this electrolyte permits the Li metal plating/stripping with a significantly improved reversibility,enabling the possibility of using ultra-thin Li anode.Benefiting from the good rechargeability of Li2CO3,less cathode passivation,and stabilized Li anode in carbonate electrolyte,the Li-O_(2)/CO_(2)battery demonstrates a long cycling lifetime of 167 cycles at 0.1 mA·cm^(-2)and 0.25 mAh·cm^(-2).This work paves a new avenue for optimizing carbonate-based electrolytes for Li-O_(2)and Li-O_(2)/CO_(2)batteries.

关键词： energy conversion Li-O_(2)/CO_(2)batteries Carbonate electrolytes Carbon dioxide fixation Oxygen heterocycles

Recent Progress in Covalent Organic Frameworks(COFs) for Electrocatalysis

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Chinese Journal of Structural Chemistry 2022年第11期41卷 84-99页

作者： Cha Li Zining Qiu Hongming Sun Yijie Yang Cheng-Peng Li College of Chemistry Tianjin Key Laboratory of Structure and Performance for Functional MoleculesTianjin Normal UniversityTianjin 300387China

Electrocatalysis provides various technologies for energy storage and conversion,which is an important part of realizing sustainable clean energy for the future.COFs,as emerging porous crystalline polymers,possess high specific surface areas,tunable pore structures,high crystallinity and tailorable functionalization.These features endow COFs with abundant active sites and fast electron transport channels,making them potentially efficient electrocatalysts.In recent years,COF-based electrocatalysts have been widely developed for hydrogen evolution reaction(HER),hydrogen oxidation reaction(HOR),oxygen evolution reaction(OER),oxygen reduction reaction(ORR),nitrogen reduction reaction(NRR)and carbon dioxide reduction reaction(CO_(2)RR).In this review,design strategies of COF-based electrocatalysts are briefly summarized,including applying COF as supports,introducing active metals in COF,constructing two-dimensional conductive COF,formation of COF-based hybrid and pyrolysis of COF to obtain carbon materials.Then,the recent research progress in COF-derived catalysts for specific electrocatalytic reactions is introduced systematically.Finally,the outlook and challenges of future applications of COFs in electrocatalysis are highlighted.

关键词： covalent organic frameworks electrocatalyst catalytic performance catalytic kinetics energy conversion

Dynamic analysis of impulse waves generated by the collapse of granular pillars

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Journal of Mountain Science 2022年第1期19卷 198-210页

作者： HUANG Bo-lin LI Bin ZHENG Jia-hao FENG Wang-li CHEN Xiao-ting LUO Chao-lin Hubei Key Laboratory of Disaster Prevention and Mitigation China Three Gorges UniversityYichang 443002China College of Civil Engineering&Architecture China Three Gorges UniversityYichang 443002China Institute of Geomechanics Chinese Academy of Geological SciencesBeijing 100081China The Pearl River Hydraulic Research Institute Guanzhou 510611China

Impulse waves generated by the collapse of pillar-shaped rock masses in Three Gorges, China,have attracted the attention of both researchers and local authorities owing to their catastrophic consequences. In this work, particle imaging velocimetry(PIV) was used to study impulse waves generated by the collapse of granular pillars during a series of physical experiments. Subsequently, the scenes of particles collapsing into water and the resulting impulse waves were analysed in terms of the solid/fluid fields. The energy obtained by the water during this process is mainly derived from the volume encroachment and continuous thrusting of particles.As indicated by the experimental results, as the aspect ratio(a) of the pillar and water depth increased, the potential energy of the granular pillar became more prone to reduction, whereas the efficiency of energy conversion to the liquid phase reduced. At constant water depth and granular pillar width, the maximum amplitude generated by the collapse of the granular pillar remained essentially the same(i.e., "saturation"was achieved) once the aspect ratio exceeded a certain threshold. The maximum impulse wave(the primary wave) formed before the main body of particles collapsed, resulting in the "saturation" of the maximum amplitude. When the kinetic energy of the particles reaches the maximum, the ratio of energy dissipation of the particles is the lowest;as the energy of water reaches the maximum, the particle collapse process does not end. The dynamic analysis of the impulse waves generated by the collapse of granular pillars provides a new approach to obtain an in-depth understanding of landslides and impulse waves. This can provide technical guidelines for disaster prevention and mitigation of impulse waves generated by bank collapse or coastline collapse.

关键词： Granular pillar collapse Particle imaging velocimetry particle/fluid interaction energy conversion Maximum amplitude