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Rare earth doped CaCu_3Ti_4O_(12) electronic ceramics for high frequency applications

Journal of Rare Earths 2010年第1期28卷 43-47页

作者：慕春红张怀武刘颖力宋远强刘鹏 State Key Laboratory of electronic Thin Films and Integrated Devices University of Electronic Science and Technology of China School of Physics and Information Technology Shaanxi Normal University

Ca1-xRxCu3Ti4O12(R=La,Y,Gd;x=0,0.1,0.2,0.3) electronic ceramics were fabricated by conventional solid-state reaction *** microstructure and dielectric properties as well as impedance behavior were carefully *** results showed that the secondary phases with the general formula R2Ti2O7 existed at grain boundaries of rare earth doped ceramics,which inhibited abnormal grain *** dielectric constant decreased from 4×105 in pure CaCu3Ti4O12(CCTO) ceramics to 2×103 with rare earth doping....

关键词： CaCu3Ti4O12 dielectric relaxation electronic ceramics LTCC devices rare earth ions doping

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Dielectric relaxation and conduction behaviors of Aurivillius Na_(0.5)Bi_(4.5)Ti_(4)O_(15) ceramics with Na doping

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Rare Metals 2021年第5期40卷 1247-1254页

作者： Fida Rehman Jing-Bo Li Pervaiz Ahmed Muhammad Sheraz Khan Yasir Saeed Asma khan Muhammad Zubair Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Department of Physics Abbottabad University of Science&TechnologyHavelian 22500Pakistan Department of Physics University of Azad Jammu and KashmirMuzafarabad 13100Pakistan Beijing Key Lab of Nanophotonics and Ultrafine Optoelectronic Systems and School of Physics Beijing Institute of TechnologyBeijing 100081China Department of Chemistry Abbottabad University of Science&TechnologyHavelian 22500Pakistan Key Laboratory of Advanced Functional Materials College of Materials Science and EngineeringMinistry of EducationBeijing University of TechnologyBeijing 100124China

Aurivillius Na_(0.5)Bi_(4.5)Ti_(4)O_(15) and Bi_(4)Ti_(3)O_(12)compounds were synthesized via solid-state reaction technique.X-ray powder diffraction study confirmed monophasic four-layered Na_(0.5)Bi_(4.5)Ti_(4)O_(15) and three-layered Bi_(4)Ti_(3)O_(12) *** relaxation and conduction behaviors of Na-contained Na_(0.5)Bi_(4.5)Ti_(4)O_(15)ceramics were thoroughly investigated in a large scale of temperature of 30-650℃ and frequency of 40 Hz^(-1) *** addition,comparative studies of both the compounds were *** and modulus analyses revealed a single relaxation behavior in Na_(0.5)Bi_(4.5)Ti_(4)O_(15) compound which was originated from the grain’s interior with grain resistance of 2.189×10^(5)Ω and capacitance of 4.268×10^(-10) F at 570℃.While in Bi_(4)Ti_(3)O_(12) ceramic the relaxation was due to the contributions of grain and grain *** current(AC)conductivity analysis revealed the presence of two different conduction regions in both the *** energies for the two different conduction mechanisms,i.e.,in low-temperature region and in high-temperature region were calculated to be~0.23 and~1.27 eV at 1 kHz for Na_(0.5)Bi_(4.5)Ti_(4)O_(15) compound and~0.43 eV and~0.97 eV at 1 kHz for Bi_(4)Ti_(3)O_(12) compound,*** present study of dielectric relaxation and conduction behaviors would be helpful for further investigations of Na_(0.5)Bi_(4.5)Ti_(4)O_(15)-related Aurivillius compounds.

关键词： Na_(0.5)Bi_(4.5)Ti_(4)O_(15) electronic ceramics Dielectric Impedance Electrical properties

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