检索结果-南通市图书馆

Enhanced electrochemical performances of Ni Doped Cr_(8)O_(21)Cathode Materials for Lithium-ion Batteries

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Wuhan University of Technology(Materials Science) 2023年第6期38卷 1242-1247页

作者： TANG Guoli LIU Hanxing YU Zhiyong YANG Bo KONG Linghua School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan 430070China

Cathode materials,nickel doped Cr_(8)O_(21),were synthesized by a solid-state *** effects of Ni doping on the electrochemical performances of Cr_(8)O_(21) were *** experimental results show that the discharge capacities of the samples depend on the nickel contents,which increases firstly and then decreases with increasing Ni *** Ni_(0.5)Cr_(7.5)O_(21)delivers a first capacity up to 392.6 m Ah·g^(-1)at *** addition,Ni doped sample also demonstrates enhanced cycling stability and rate capability compared with that of the bare Cr_(8)O_(21).At 1 C,an initial discharge capacity of 348.7 m Ah·g^(-1)was achieved for Ni_(0.5)Cr_(7.5)O_(21),much higher than 271.4 m Ah·g^(-1)of the un-doped sample,with an increase of more than 28%.electrochemical impedance spectroscopy results confirm that Ni doping reduces the growth of interface resistance and charge transfer resistance,which is conducive to the electrochemical kinetic behaviors during charge-discharge.

关键词： Cr_(8)O_(21) cathode material doping electrochemical performances lithium-ion batteries

One-time sintering process to modify xLi2MnO3(1-x)LiMO2 hollow architecture and studying their enhanced electrochemical performances

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2020年第11期29卷 271-279页

作者： Renheng Wang Yiling Sun Kaishuai Yang Junchao Zheng Yan Li Zhengfang Qian Zhenjiang He Shengkui Zhong College of Physics and Optoelectronic Engineering Shenzhen UniversityShenzhen 518060GuangdongChina School of Metallurgy and Environment Central South UniversityChangsha 410083HunanChina School of Marine Science and Technology Hainan Tropical Ocean UniversitySanya 572000HainanChina College of Environmental Science and Engineering Donghua UniversityShanghai 201620China

To solve the critical problems of lithium rich cathode materials, e.g., structure instability and short cycle life, we have successfully prepared a ZrO2-coated and Zr-doping xLi2MnO3·(1–x)LiMO2 hollow architecture via one-time sintering process. The modified structural materials as lithium-ion cathodes present good structural stability and superior cycle performance in LIBs. The discharge capacity of the ZrO2-coated and Zr-doped hollow pristine is 220 mAh g-1 at the 20th cycle at 0.2 C(discharge capacity loss, 2.7%)and 150 m Ah g-1 at the 100 th cycle at 1 C(discharge capacity loss, 17.7%), respectively. However, hollow pristine electrode only delivers 203 m Ah g-1 at the 20 th cycle at 0.2 C and 124 mAh g-1 at the 100 th cycle at 1 C, respectively, and the corresponding to capacity retention is 92.2% and 72.8%, *** coefficients of modified hollow pristine electrode are much higher than that of hollow pristine electrode after 100 cycles(approach to 1.4 times). In addition, we simulate the adsorption reaction of HF on the surface of ZrO2-coated layer by the first-principles theory. The calculations prove that the adsorption energy of HF on the surface of ZrO2-coated layer is about-1.699 e V, and the ZrO2-coated layer could protect the hollow spherical xLi2MnO3·(1–x)LiMO2 from erosion by HF. Our results would be applicable for systematic amelioration of high-performance lithium rich material for anode with the respect of practical application.

关键词： Lithium rich cathode materials One-time sintering process Coated and doped electrochemical performances First-principles calculations

An investigation on electrochemical performances of as-cast and annealed La_(0.8)Mg_(0.2)Ni_(3.3)Co_(0.2)Si_x(x=0-0.2)alloy electrodes for Ni/MH battery application

在线全文

学校读者我要写书评

暂无评论

Journal of Central South University 2014年第6期21卷 2125-2135页

作者：张羊换陈莉翠赵宸杨泰徐超赵栋梁 Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University of Science and Technology Department of Functional Material Research Central Iron and Steel Research Institute

The La-Mg-Ni-based A2B7-type La0.5Mg0.2Ni3.3Co0.2Six （x=0-0.2） electrode alloys were prepared by casting and annealing. The influences of the additional silicon and the annealing treatment on the structure and electrochemical performances of the alloys were investigated systemically. Both of the analyses of XRD and SEM reveal that the as-cast and annealed alloys are of a multiphase structure, involving two main phases （La, Mg）2Ni7 and LaNi5 as well as one minor phase LaNi3. The addition of Si and annealing treatment bring on an evident change in the phase abundances and cell parameters of （La, Mg）2Ni7 and LaNi5 phase for the alloy without altering its phase structure. The phase abundances decrease from 74.3% （x=0） to 57.8% （x=0.2） for the （La, Mg）2Ni7 phase, and those of LaNi5 phase increase from 20.2% （x^0） to 37.3% （x=0.2）. As for the electrochemical measurements, adding Si and performing annealing treatment have engendered obvious impacts. The cycle stability of the alloys is improved dramatically, being enhanced from 80.3% to 93.7% for the as-annealed （950 ℃） alloys with Si content increasing from 0 to 0.2. However, the discharge capacity is reduced by adding Si, from 399.4 to 345.3 mA.h/g as the Si content increases from 0 to 0.2. Furthermore, such addition makes the electrochemical kinetic properties of the alloy electrodes first increase and then decrease. Also, it is found that the overall electrochemical properties of the alloys first augment and then fall with the annealing temperature rising.

关键词： A2B7-type electrode alloy adding Si annealing treatment structure electrochemical performances

Preparation of Large-Scale Double-Side BDD Electrodes and Their electrochemical performances

在线全文

学校读者我要写书评

暂无评论

Transactions of Nanjing University of Aeronautics and Astronautics 2015年第6期32卷 674-680页

作者：吴海兵徐锋刘召志周春卢文壮左敦稳 College of Mechanical and Electrical Engineering Nanjing University of Aeronautics and Astronautics

Boron doped diamond(BDD)performs well in electrochemical oxidation for organic pollutants thanks to its wide electrochemical window and superior chemical *** presented a method to obtain well-adherent large-scale BDD/Nb electrode by the modified hot filament chemical vapor deposition system(HFCVD).SiC particles were sand blasted to enhance the adhesion of BDD *** BDD coating was then deposited on both sides of Nb which was placed vertically and closely with filament grids on both *** BDD/Nb electrodes had no deformation because the thermal deformations of the BDD films on both sides of the Nb substrate conteracted each other during cooling process after *** surface morphology and purity of the BDD/Nb electrode were analyzed by Raman and scanning elestron microscope(SEM)*** test was used to investigate the adhesion of BDD *** electrochemical performances were measured by cyclic voltammetry *** BDD electrode at the B/C ratio of 2 000×10^(-6) held a higher oxygen evolution potential thanks to its high sp3 carbon *** life test illustrated that the sandblasting pretreatment obviously enhanced the adhesion of BDD coating which resulted in a longer service duration than the un-sandblasted one.

关键词： hot filament chemical vapor deposition(CVD) boron doped diamond large-scale double side elec-trode electrochemical performances

The role of tungsten-related elements for improving the electrochemical performances of cathode materials in lithium ion batteries

在线全文

学校读者我要写书评

暂无评论

Tungsten 2021年第3期3卷 245-259页

作者： Yong-Qi Sun Weng Fu Yu-Xiang Hu James Vaughan Lian-Zhou Wang Nanomaterials Centre School of Chemical Engineering and Australian Institute for Bioengineering and NanotechnologyThe University of QueenslandBrisbaneQLD 4072Australia School of Chemical Engineering The University of QueenslandBrisbaneQLD 4072Australia

Lithium ion batteries using Ni-Co-Mn ternary oxide materials(NCMs)and Ni-Co-Al materials(NCAs)as the cathode materials are dominantly employed to power the electric vehicles(EVs).Increasing the driving range of EVs necessitates an increase of Ni content to improve the energy densities,which,however,degrades the cycle *** we review the doping/coating of tungsten and related elements to improve the electrochemical performance of these cathodes especially the cycle *** selection of tungsten and related elements is based on their special properties including the high valence state,strong bonding with oxygen and the large ionic *** improvement of cycle stability mainly results from two features:(1)the enhancement of bulk structure stability upon doping(Mo,W,Ta,Nb)and(2)the resistance of side reactions of electrode/electrolyte by the surficial layer induced by direct coating(V,W,Nb)or bulk *** the recent high Ni materials,the formation of Ni2+and its migration to the Li layer induced by these doped/coated tungsten-related elements,and the presence of spinel or rock-salt phase before cycling contributes to improving the cycle *** key challenges are the selection of an optimized additive concentration and the fundamental understanding of the reaction mechanism,which will provide insightful guidance for maximizing the electrochemical performance of the state-of-the-art lithium-ion batteries at minimal additional process costs.

关键词： Nickel-cobalt-manganese oxide cathodes electrochemical performances Tungsten and related elements Doping/coating

Improving electrochemical performances of LiFePO_4 /C cathode material via a novel three-layer electrode

在线全文

学校读者我要写书评

暂无评论

Transactions of Nonferrous Metals Society of China 2013年第11期23卷 3324-3329页

作者：肖政伟胡国荣杜柯彭忠东昆明理工大学冶金与能源工程学院昆明650093 中南大学冶金与环境学院长沙410083

As an improvement on the conventional two-layer electrode （active material layerlcurrent collector）, a novel sandwich-like three-layer electrode （conductive layerlactive material layertcurrent collector） for cathode material LiFePO4/C was introduced in order to improve its electrochemical performance. LiFePO4/C in the three-layer electrode exhibited superior rate capability in comparison with that in the two-layer electrode in accordance with charge-discharge examination. Cyclic voltammetry and electrochemical impedance spectroscopy indicated that Fe3＋/Fe2＋ redox couple for LiFePO4 in the three-layer electrode displayed faster kinetics, better reversibility and much lower charge transfer resistance than that in the two-layer electrode in electrochemical process. For three-layer electrode, the holes in the surface of active material layer were filled by smaller acetylene black grains, which formed electrical connections and provided more pathways to electron transport to/from LiFePO4/C particles exposed to the bulk electrolyte.

关键词： lithium ion cells LiFePO4 cathode electrode configuration three-layer electrode electrochemical performances

electrochemical Hydrogen Storage performances of the Si Added La-Mg-Ni-based A_2B_7-type Electrode Alloys for Ni/MH Battery Application

在线全文

学校读者我要写书评

暂无评论

Journal of Wuhan University of Technology(Materials Science) 2015年第1期30卷 166-174页

作者：张羊换 YANG Tai CHEN Licui XU Chao REN Huiping ZHAO Dongliang Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University of Science and Technology Department of Functional Material Research Central Iron and Steel Research Institute

The casting and annealing technologies were applied to fabricate the La0.8Mg0.2Ni3.3Co0.2Six （x = 0-0.2） electrode alloys. The effects of Si content and annealing temperature on the structure and electrochemical performances of the alloys were investigated systematically. The analyses of XRD and SEM show that all the alloys possess a multiphase structure, involving two main phases （La, Mg）2Ni7 and LaNi5 as well as a residual phase LaNi3. The addition of Si brings on an evident increase in the LaNi5 phase and a decrease in the （La, Mg）2Ni7 phase, without altering the main phase component of the alloy, which also makes the lattice constants and cell volumes of the alloy enlarged. Likewise, the annealing treatment engenders the same action on the lattice constants and cell volumes as adding Si. Simultaneously, it gives rise to the variation of the phase abundance and the coarsening of the alloy grains. The electrochemical measurements indicate that the addition of Si ameliorates the cycle stability of the as-cast and annealed alloys significantly, but impairs their discharge capacities clearly. Similarly, the annealing treatment makes a positive contribution to the cycle stability of the alloy evidently, and the discharge capacity of the alloy shows a maximum value with annealing temperature rising. Furthermore, the high rate discharge ability （HR） first augments and then declines with the rising of Si content and annealing temperature.

关键词： A2B7-type electrode alloy Si addition annealing temperature structure electrochemical performances

Effects of substituting Ni with M (M=Cu, Al and Mn) on microstructures and electrochemical characteristics of La-Mg-Ni system (PuNi_3-type) electrode alloys

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2006年第z1期25卷 25-32页

作者： ZHANG Yanghuan ZHAO Dongliang DONG Xiaoping REN Huiping GUO Shihai WANG Xinlin Department of Functional Material Research Central Iron and Steel Research Institute Beijing 100081 China School of Material Inner Mongolia University of Science and Technology Baotou 014010 China Department of Functional Material Research Central Iron and Steel Research Institute Beijing 100081 China Department of Functional Material Research Central Iron and Steel Research Institute Beijing 100081 China School of Material University of Science and Technology Beijing Beijing 100083 China School of Material Inner Mongolia University of Science and Technology Baotou 014010 China Department of Functional Material Research Central Iron and Steel Research Institute Beijing 100081 China Department of Functional Material Research Central Iron and Steel Research Institute Beijing 100081 China

In order to improve the electrochemical cycle stability of La-Mg-Ni system (PuNi3-type) hydrogen storage alloy, Ni in the alloys was partially substituted by M (M=Cu, Al, Mn). A new La-Mg-Ni system electrode alloys La0.7Mg0.3Ni2.55-xCo0.45Mx (M=Cu, Al, Mn; x=0, 0.1) were prepared by casting and rapid quenching. The effects of element substitution and rapid quenching on the microstructures and electrochemical performances of the alloys were investigated. The results by XRD, SEM and TEM show that the alloys have a multiphase structure, including the (La, Mg)Ni3 phase, the LaNi5 phase and the LaNi2 phase. The rapid quenching and element substitution have an imperceptible influence on the phase compositions of the alloys, but both change the phase abundance of the alloys. The rapid quenching significantly improves the composition homogeneity of the alloys and markedly decreases the grain size of the alloys. The Cu substitution promotes the formation of an amorphous phase in the as-quenched alloy, and a reversal result by the Al substitution. The electrochemical measurement indicates that the element substitution decreases the discharge capacity of the alloys, whereas it obviously improves the cycle stability of the alloys. The positive influence of element substitution on the cycle life of the alloys is in sequence Al>Cu>Mn, and negative influence on the discharge capacity is in sequence Al>Mn>Cu. The rapid quenching significantly enhances the cycle stability of the alloys, but it leads to a different extent decrease of the discharge capacity of the alloys.

关键词： element substitution rapid quenching La-Mg-Ni system electrode alloy microstructures electrochemical performances

Enabling superior electrochemical performance of NCA cathode in Li_(5.5)PS_(4.5)Cl_(1.5)-based solid-state batteries with a dual-electrolyte layer

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第4期35卷 231-236页

作者： Ziling Jiang Shaoqing Chen Chaochao Wei Ziqi Zhang Zhongkai Wu Qiyue Luo Liang Ming Long Zhang Chuang Yu School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China Innovation Center for Chemical Sciences College of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China College of Physics and Energy Fujian Normal UniversityFuzhou 350117 China

LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA) is a promising cathode for sulfide-based solid-state lithium batteries(ASSLBs)profiting from its high specific capacity and voltage plateau, which yielding high energy density. However, the inferior interfacial stability between the bare NCA and sulfides limits its electrochemical performance. Hereien, the dual-electrolyte layer is proposed to mitigate this effect and enhance the battery performances of NCA-based ASSLIBs. The Li_(3)InCl_6 wih high conductivity and excellent electrochemcial stability act both as an ion additives to promote Li-ion diffusion across the interface in the cathode and as a buffer layer between the cathode layer and the solid electrolyte layer to avoid side reactions and improve the interface stability. The corresponding battery exhibits high discharge capacities and superior cyclabilities at both room and elevated temperatures. It exhibits discharge performance of 237.04 and216.07 m Ah/g at 0.1 and 0.5 C, respectively, when cycled at 60 ℃, and sustains 95.9% of the capacity after100 cycles at 0.5 C. The work demonstrates a simple strategy to ensure the superior performances of NCA in sulfide-based ASSLBs.

关键词： LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2) Li_(5.5)PS_(4.5)Cl_(1.5) Double solid electrolyte layer configuration Operating temperatures electrochemical performances