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Nano-Micro Letters 2011年第3期3卷 160-165页

作者： Ying Huang D.K.Sarkar X-Grant Chen University Research Center on Aluminum (CURAL) University of Qubec at Chicoutimi

Superhydrophobic aluminum surfaces have been prepared by means of electrodeposition of copper on aluminum surfaces, followed by electrochemical modification using stearic acid organic molecules. Scanning electron microscopy(SEM) images show that the electrodeposited copper films follow "island growth mode" in the form of microdots and their number densities increase with the rise of the negative deposition potentials. At an electrodeposition potential of-0.2 V the number density of the copper microdots are found to be 4.5×104cm^(-2)that are increased to 2.9×105cm^(-2)at a potential of-0.8 V. Systematically, the distances between the microdots are found to be reduced from 26.6 μm to 11.03 μm with the increase of negative electrochemical potential from-0.2 V to-0.8 V. X-ray diffraction(XRD) analyses have confirmed the formation of copper stearate on the stearic acid modified copper films. The roughness of the stearic acid modified electrodeposited copper films is found to increase with the increase in the density of the copper microdots. A critical copper deposition potential of-0.6 V in conjunction with the stearic acid modification provides a surface roughness of 6.2 μm with a water contact angle of 157?, resulting in superhydrophobic properties on the aluminum substrates.

关键词： Superhydrophobic aluminum surface Water contact angle Copper microdots Surface roughness electrochemical modification

Chemical Scissors Tailored Nano‑Tellurium with High‑Entropy Morphology for Efficient Foam‑Hydrogel‑Based Solar Photothermal Evaporators

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Nano-Micro Letters 2024年第3期16卷 149-168页

作者： Chenyang Xing Zihao Li Ziao Wang Shaohui Zhang Zhongjian Xie Xi Zhu Zhengchun Peng State Key Laboratory of Radio FrequencyHeterogeneous Integration Shenzhen UniversityShenzhen 518060People’s Republic of China Center for Stretchable Electronics and NanoSensors College of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060People’s Republic of China School of Science and Engineering The Chinese University of Hong KongShenzhenShenzhen 518172People’s Republic of China Institute of Pediatrics Shenzhen Children’s HospitalShenzhen 518038GuangdongPeople’s Republic of China International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060People’s Republic of China

The development of tellurium(Te)-based semiconductor nanomaterials for efficient light-to-heat conversion may offer an effective means of harvesting sunlight to address global energy ***,the nanosized Te(nano-Te)materials reported to date suffer from a series of drawbacks,including limited light absorption and a lack of surface ***,we report the preparation of nano-Te by electrochemical exfoliation using an electrolyzable room-temperature ionic ***,cations,and their corresponding electrolytic products acting as chemical scissors can precisely intercalate and functionalize bulk *** resulting nano-Te has high morphological entropy,rich surface functional groups,and broad light *** also constructed foam hydrogels based on poly(vinyl alcohol)/nano-Te,which achieved an evaporation rate and energy efficiency of 4.11 kg m^(−2)h^(−1)and 128%,respectively,under 1 sun ***,the evaporation rate was maintained in the range 2.5-3.0 kg m^(−2)h^(−1)outdoors under 0.5-1.0 sun,providing highly efficient evaporation under low light conditions.

关键词： Tellurium High entropy electrochemical modification Solar absorption Evaporation rate

Fabrication of electrochemically-modified BiVO_(4)-MoS_(2)-Co_(3)O_(4)composite film for bisphenol A degradation

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Journal of Environmental Sciences 2021年第4期33卷 341-351页

作者： Yanqing Cong Wenhua Zhang Wenchen Ding Tongtong Zhang Yi Zhang Nianping Chi Qi Wang School of Environmental Science and Engineering Zhejiang Gongshang UniversityHangzhou 310018China Institute of Urban Aquatic Environment Zhejiang Gongshang UniversityHangzhou 310018China

A new electrochemically-modified BiVO_(4)-MoS_(2)-Co_(3)O_(4)(represented as E-BiVO_(4)-MoS_(2)-Co_(3)O_(4))thin film electrode was successfully synthesized for environmental ***_(2)and Co_(3)O_(4)were grown on the surface of Bi VO 4 to obtain BiVO_(4)-MoS_(2)-Co_(3)O_(4).E-BiVO_(4)-MoS_(2)-Co_(3)O_(4)film was achieved by further electrochemical treatment of BiVO_(4)-MoS_(2)-Co_(3)O_(4).The asprepared E-BiVO_(4)-MoS_(2)-Co_(3)O_(4)exhibited significantly enhanced photoelectrocatalytic *** photocurrent density of E-BiVO_(4)-MoS_(2)-Co_(3)O_(4)thin film is 6.6 times that of Bi VO 4 under visible light *** degradation efficiency of E-BiVO_(4)-MoS_(2)-Co_(3)O_(4)for bisphenol A pollutant was 81.56%in photoelectrochemical *** pseudo-first order reaction rate constant of E-BiVO_(4)-MoS_(2)-Co_(3)O_(4)film is 3.22 times higher than that of Bi VO *** its reaction rate constant in photoelectrocatalytic process is 14.5 times or 2 times that in photocatalytic or electrocatalytic process,*** improved performance of E-BiVO_(4)-MoS_(2)-Co_(3)O_(4)was attributed to the synergetic effects of the reduction of interfacial charge transfer resistance,the formation of oxygen vacancies and sub-stoichiometric metal oxides and higher separation efficiency of photogenerated electron-hole pairs.E-BiVO_(4)-MoS_(2)-Co_(3)O_(4)is a promising composite material for pollutants removal.

关键词： electrochemically-modified BiVO_(4)-MoS_(2)-Co_(3)O_(4) Photoelectrocatalytic(PEC) electrochemical modification Visible light Bisphenol A(BPA)

electrochemically modified piezoelectric crystal biosensor for detection of Staphylococcus aureus

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Chinese Journal of Chemistry 1996年第3期14卷 222-227页

作者： Si, SH Chen, JH He, FJ Nie, LH Yao, SZ HUNAN UNIV NEW MAT RES INSTCHANGSHA 410082HUNANPEOPLES R CHINA

Electropolymerized o-phenylenediamine firm is used as a functional coating for the immobilization of anti-S. aureus antibody on the surface of a gold-plated piezoelectric crystal, and this piezoelectric immunosensor is applied to detect S. aureus. The frequency shift (Delta F = F-20s - F-380s, Hz) between the frequency at the 20th second (after the addition of sample, F-20s) and that at 380 seconds later (F-380s) was introduced to construct a calibration graph, and shortening of assay time was achieved. The S. aureus concentrations in the range of 10(5)-10(9) cells/mL can be detected by this system.

关键词： piezoelectric biosensor detection of S-aureus electrochemical modification