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Nanotube array-like WO_3/W photoanode fabricated by electrochemical anodization for photoelectrocatalytic overall water splitting

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Chinese Journal of Catalysis 2017年第12期38卷 2132-2140页

作者： Lingfeng Li Xiaolong Zhao Donglai Pan Guisheng Li Key Laboratory of Resource Chemistry of Ministry of Education Shanghai Key Laboratory of Rare Earth Functional Materials College of Life and Environmental Science Shanghai Normal University Shanghai 200234 China

Photoactive WO3is attractive as a photocatalyst for green energy evolution through water *** the present work,an electrochemical anodic oxidation method was used to fabricate a photo‐responsive nanotube array‐like WO3/W(NA‐WO3/W)photoanode from W foil as a *** with a reference commercial WO3/W electrode,the NA‐WO3/W photoanode exhibited enhanced and stable photoelectrocatalytic(PEC)activity for visible‐light‐driven water splitting with a typical H2/O2stoichiometric ratio of2:1and quantum efficiency of approximately5.23%under visible‐light irradiation from a light‐emitting diode(λ=420nm,15mW/cm2).The greatly enhanced PEC performance of the NA‐WO3/Wphotoanode was attributed to its fast electron–hole separation rate,which resulted from the one‐dimensional nanotube array‐like structure,high crystallinity of monoclinic WO3,and strong interaction between WO3and W *** work paves the way to a facile route to prepare highly active photoelectrodes for solar light transfer to chemical energy.

关键词： WO3 W foil electrochemical anodization Nanotube arrays Photoelectrocatalysis Water splitting

Experimental investigation of anodized/spray pyrolysed nanoporous structure on heat transfer augmentation

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Journal of Thermal Science 2009年第4期18卷 358-363页

作者： Kalaiselvam S. Gugan M.S. Kuraloviyan E. Meganathan R. NiruthiyaPriyan A. Swaminathan M.R. Department of Mechanical Engineering Anna University Chennai

This paper analyzes the effects of nanoporous surface on heat transfer temperaments of assorted thermal conductingmaterials. A phenomenal proposal of wielding the surface roughness to ameliorate the heat transfer ratehas been discovered. The maximum increase of heat transfer rate procured by nanoporous layers is 133.3% higherthan the polished bare metals of surface roughness 0.2μm. This plays an imperative role in designing compact refrigerationsystems, chemical and thermal power plants. Experimental results picture a formidable upswing of58.3% heat transfer in chemically etched metals of surface roughness 3 μm, 133.3% in nanoporous surface of porosity75-95 nm formed by electrochemical anodization, and porosity of 40-50 nm formed by spray pyrolysis increasesthe heat transfer by 130%. Effects of porosity, flow velocity and scaling on the energy transfer are alsoscrutinized. This paper also analyzes the multifarious modes of nanoporous fabrication, to contrive both prodigiousand provident system.

关键词： Nanoporous surface Heat transfer augmentation electrochemical anodization Spray pyrolysis.

Single-step nano-engineering of multiple micro-rough metals via anodization

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Nano Research 2023年第1期16卷 1320-1329页

作者： Divya Chopra Tianqi Guo Sašo Ivanovski Karan Gulati The University of Queensland School of DentistryHerston QLD 4006Australia

anodization is a cost-effective technique to nano-engineer various metals,however,optimizations have been mostly restricted to Al and Ti,and for easy to manage polished and flat substrates,limiting industrial ***,we aim at standardizing and simplifying anodization of ten metals,attempting to make metal nano-engineering more *** a world-first attempt,we synthesize a standard electrolyte to fabricate controlled nanostructures on various metals,taking a close look at the influence of the substrate topography,electrolyte composition,and electrolyte aging(repeated use of same electrolyte)towards designing a standard nano-engineering *** of curved substrates(metal wires)with micro-roughness allows for ease of industrial translation across various *** study is a step closer to standardizing anodization and fabrication of controlled nanotopography on various metallic surfaces,while maintaining scalability and ease of use.

关键词： electrochemical anodization nanopores nanotubes metal metal oxide nanostructures

Macro-micron-nano-featured surface topography of Ti-6Al-4V alloy for biomedical applications

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Rare Metals 2018年第12期37卷 1055-1063页

作者： Da-Peng Zhao Jin-Cheng Tang He-Min Nie Yuan Zhang Yu-Kai Chen Xu Zhang Hui-Xing Li Ming Yan College of Biology Hunan University Shenzhen Key Laboratory for Additive Manufacturing of High-Performance Materials Department of Materials Science and Engineering Southern University of Science and Technology

One of the critical issues in the development of novel metallic biomaterials is the design and fabrication of metallic scaffolds and implants with hierarchical structures mimicking human bones. In this work, selective laser melting(SLM) and electrochemical anodization were applied to fabricate dense Ti-6 A1-4 V components with macro-micron-nanoscale hierarchical surfaces. Scanning electron microscopy(SEM), 3 D laser scanning microscopy(3 D LSM), contact angle video system, fluorescence microscopy and spectrophotometer were used to investigate the properties of the samples. The results reveal that the SLMed post-anodization(SLM-TNT) exhibits enhanced or at least comparable wettability, protein adsorption and biological response of mesenchymal stem cells(MSCs) in comparison with the three reference configurations, i.e., the polished Ti-6 Al-4 V(PO-Ti64), the SLMed Ti-6 A1-4 V(SLM-Ti64) and the polished Ti-6 A1-4 V post-anodization(PO-TNT). The improved cytocompatibility of the samples after SLM and anodization should be mainly attributed to the nanoscale tubular features,while the macro-micron-scale structures only lead to slight preference for cell attachment.

关键词： Selective laser melting electrochemical anodization Hierarchical surface Cell adhesion Cell proliferation

Fresh or aged:Short time anodization of titanium to understand the influence of electrolyte aging on titania nanopores

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Journal of Materials Science & Technology 2022年第24期119卷 245-256页

作者： Tianqi Guo Saso Ivanovski Karan Gulati The University of Queensland School of DentistryHerston QLD 4006Australia

electrochemical anodization(EA)is a simple and cost-effective technique to fabricate controlled nanostructures on Ti substrates,such as TiO_(2)nanotubes and *** aging of organic EA electrolytes(repeated EA using non-target Ti before EA of target Ti)is recognized to influence the characteristics of the anodized ***,there is limited information about how surface topography and electrolyte aging dictate the formation and characteristics of the anodized *** the current study,short-time EA(starting at 10 s)of micro-machined Ti substrates was performed with electrolytes of various ages(fresh/unused,15 h aged and 30 h aged),followed by evaluation of the TiO_(2)nanopores(TNPs)characteristics in terms of topography,chemistry,stability and protein *** results showed that aligned TNPs were obtained earlier(120 s)with fresh electrolyte as compared to the aged electrolyte EA(600 s).Interestingly,TNPs fabricated using fresh electrolyte(at lower EA times)showed favorable wettability,protein adhesion capacity and mechanical properties compared with aged electrolyte *** findings of the study demonstrate how nanopore formation differs between fresh and aged electrolytes when performing EA of micro-machined Ti,which provides an improved understanding of electrolyte aging and its influence on anodized nanostructures.

关键词： Titanium Titania nanopores electrochemical anodization Electrolyte aging Surface modification

Electro-Optics and Band Gap Energies of Nanosilver-Coated TiO2 Nanotubes on Titanium Metal

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Acta Metallurgica Sinica(English Letters) 2018年第2期31卷 153-163页

作者： Ugursoy Olgun Mustafa Gülfen Fatih Ustel Hale Arslan Department of Chemistry Faculty of Arts and Sciences Sakarya University 54187 Sakarya Turkey Department of Metallurgical and Materials Engineering Faculty of Engineering Sakarya University 54187 Sakarya Turkey

TiO2 nanotubes on Ti metal surface were prepared by the electrochemical anodization method. Then, nanosilver was deposited onto the nanotubes by the electroless dip coating and the anodization. The obtained TiO2 nanotubes were examined by using scanning electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, cyclic voltammetry, and UV–Vis. The electrochemical band gap（Eg^CV） of the nanosilver-coated TiO2 nanotubes prepared by the anodization was found as 1.54 eV. Using the UV–Vis measurements, the optical band gap energy（Eg^op.） was calculated as 1.51 eV for the Ag/TiO2 nanotubes obtained by electroless dip coating. The electrical conductivity of the TiO2 nanotubes also increased from 3.0 × 10^-4 to 34.7 S/cm after nano Ag deposition by the anodization *** Ag/TiO2 nanotubes with low band gap and high electrical conductivity are desirable for the applications in electronics, Li-ion batteries, and solar cells.

关键词： electrochemical anodization TiO2 nanotubes Nano Ag deposition Band gap energy Electrical conductivity

Anodic Alumina Supported Pt Catalyst for Total Oxidation of Trace Toluene

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Chinese Journal of Chemical Engineering 2014年第8期22卷 882-887页

作者：芮泽宝陈春燕逯玉冰纪红兵 Department of Chemical Engineering School of Chemistry & Chemical Engineeringand The Key Lab of Low-carbon Chemistry & Energy Conservation of Guangdong ProvinceSun Yat-sen University

Featuring an assembly of identical pores, through-pore anodic alumina （AAO） makes an ideal monolith-like cat- alyst support for volatile organic compound （VOC） combustion. This work employs the oxidation of toluene as a model reaction to investigate the applicability of AAO supported Pt catalysts in VOC catalytic combustion. In order to modify the microstructure of AAO, some AAO samples were exposed to hot water treatment （HWT） firstly. Re- sults show that the optimum HWT time is 18 h. Pt/HWT18 gives a toluene conversion of95%; at 200 ℃, which is comparable to the initial activity of commercial γ-A1203 particle supported Pt catalyst. Considering its confine- ment effect for the supported metal and its monolith-like compact unit, AAO support offers potential applications in VOC catalytic combustion.

关键词： Anodic alumina Pt electrochemical anodization Catalytic combustion Toluene