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Formulation of lyotropic liquid crystal EMULSION based on natural sucrose ester and its tribological behavior as novel lubricant

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Friction 2022年第11期10卷 1879-1892页

作者： Yumei GUO Jiusheng LI Xiaojie ZHOU Yuzhao TANG Xiangqiong ZENG Laboratory for Advanced Lubricating Materials Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201210China University of Chinese Academy of Sciences Beijing 100049China National Facility for Protein Science in Shanghai Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201210China

The tribological behavior of oil-in-water EMULSIONs formulated with natural lyotropic liquid crystal(LLC)emulsifiers based on natural sucrose ester was studied for the first time.Polarized optical microscopy,synchrotron radiation small-angle X-ray scattering,wide-angle X-ray scattering,and synchrotron radiation infrared microspectroscopy demonstrated that LLC emulsifiers were tightly ordered at the oil–water interface with a distinct nematic texture.The viscosity of EMULSION was observed to change over time.Moreover,the zeta potential and laser particle size distribution verified the EMULSION’s satisfactory stability.The frictional shearing test proved that the coefficient of friction of the EMULSION versus pure oil decreased by 34.2%.The coefficient of friction of the EMULSION with liquid crystal decreased 10.1%versus that without liquid crystal.Although liquid crystal EMULSION did not exhibit outstanding anti-wear performance compared with pure oil,its wear volume was 29.4%less than the EMULSION without liquid crystal.X-ray photoelectron spectroscopy and scanning electron microscope–energy dispersive X-ray spectroscopy(SEM–EDS)proved that the tribo-film of the EMULSION with liquid crystal was formed synergistically by the liquid crystal phase with the base oil.The formulation affecting the lubricant quality was further studied by orthogonal experiments.The resulting Stribeck curve behavior suggested that proper composition with a slightly higher viscosity can better reduce friction in both boundary lubrication and mixed lubrication regimes.The lubrication mechanism indicated that the periodically ordered liquid crystal was transported to the sliding asperity in the form of EMULSION droplets,which bored the pressure and released the oil to form a tribo-film.This LLC EMULSION is environmentally friendly and potentially non-irritant to the skin.Thus,it has promising application prospects as novel water-based and biological lubricants.

关键词： lyotropic liquid crystal(LLC) EMULSION aqueous lubrication tribological behavior

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EMULSION confined block copolymer self-assembly:Recent progress and prospect

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Nano Research 2023年第1期16卷 564-582页

作者： Yilin Liu Fangfang Ke Yuanchao Li Yi Shi Zhen Zhang Yongming Chen School of Materials Science and Engineering Sun Yat-Sen UniversityGuangzhou 510006China

In the past few decades,significant progress in block copolymer self-assembly has been achieved in many fields,and with the development of nanoscience and nanotechnology,more and more complex situations need block copolymer self-assembly based nanoplatforms having more complex structures for specific multimodal or multiplexed applications.Through the combination of emulsification and self-assembly of the block copolymer,different materials with exotic architectures and functions could be combined within an entity,such as controlled vesicles,Janus particles,and composite particles which are more like ideal nanoplatforms.Various designs can show their different desired properties depending upon the application situation,including molecular delivery,surfactants,and multicolor encoding.This review will provide a complete summary of the optimization and the synthesis method for the recently designed EMULSION confined block copolymer assemblies,and also the challenges and limitations this method faces,and the potential solutions in this field.

关键词： EMULSION block copolymer confined volume self-assembly exotic architectures

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Thermally conductive poly(lactic acid)/boron nitride composites via regenerated cellulose assisted Pickering EMULSION approach

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Journal of Materials Science & Technology 2022年第6期101卷 146-154页

作者： Yating Wang Hong Jin Jiajun Shen Bijia Wang Xueling Feng Zhiping Mao Yumei Zhang Xiaofeng Sui Key Lab of Science and Technology of Eco-Textile Ministry of EducationCollege of ChemistryChemical Engineering and BiotechnologyDonghua UniversityNo.2999North Renmin RoadSongjiang DistrictShanghai 201620China Innovation Center for Textile Science and Technology of DHU Donghua UniversityNo.2999North Renmin RoadSongjiang DistrictShanghai 201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringDonghua UniversityNo.2999North Renmin RoadSongjiang DistrictShanghai 201620China

Polymer-based thermally conductive composites have attracted tremendous interest in thermal management of electronics.However,it remains challenging to achieve high thermal conductivity partly because the difficulty to obtain favorable distribution and orientation of conductive fillers within the polymer matrix.Herein,networked boron nitride(BN)conductive pathway was realized within the poly(lactic acid)(PLA)matrix,via regenerated cellulose(RC)-assisted assembly of BN on Pickering EMULSION interface based on the noncovalent interaction,followed by solvent evaporation and hot-compressing.The strong noncovalent interactions between BN and RC were found critical to enhance the wettability and stability of BN in aqueous media with a lowest mass ratio of 1:40 of RC and BN.The obtained PLA/BN composites feature a thermal conductivity of 1.06 W/(m K)at 28.4 wt%BN loading,representing an enhancement of 430%comparing to neat PLA,and the crystallinity of the composites could increase significantly from11.7%(neat PLA)to 43.7%.This simple,environmentally friendly and effective strategy could be easily extended for effective construction of thermally conductive composites.

关键词： Boron nitride Regenerated cellulose EMULSION Noncovalent interaction Thermal conductivity

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Preparation of porous adsorbent via Pickering EMULSION template for water treatment: A review

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Journal of Environmental Sciences 2020年第2期32卷 217-236页

作者： Yongfeng Zhu Wenbo Wang Hui Yu Aiqin Wang Key Laboratory of Clay Mineral Applied Research of Gansu Province Center of Eco-material and Green ChemistryLanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Porous materials as emerging potential adsorbents have received much more attention because they are capable of capturing various pollutants with fast adsorption rate, high adsorption capacity, good selectivity and excellent reusability.In order to prepare porous materials with decent porous structure, Pickering EMULSION template method has been proved to be one of the most effective technologies to create pore structure.This paper reviewed comprehensively the latest research progress on the preparation of porous materials from various Pickering EMULSIONs and their applications in the decontamination of pollutants(e.g., heavy metal ions, organic pollutants) and in the oil/water separation.It was expected that the summaries and discussions in this review will provide insights into the design and fabrication of new efficient porous adsorbents, and also give us a better understanding of the subject.

关键词： Pickering EMULSION Porous material Soft template Water treatment

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’EMULSION locks’ for the containment of hydrocarbons during surfactant flushing

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Journal of Environmental Sciences 2020年第4期32卷 98-109页

作者： Kristine Lamont Alejandro GMarangoni Erica Pensini University of Guelph School of Engineering50 Stone Road EastGwelph ONNIG 2W1Canada University of Guelph Food Science Department50 Stone Road EastGuelph ONNIG 2WlCanada

Reversible double water in oil in water(W/O/W)EMULSIONs were developed to contain subsurface hydrocarbon spills during their remediation using surfactant flushing.Double EMULSIONs were prepared by emulsifying CaCl2 solutions in canola oil,and subsequently by emulsifying the W/O EMULSIONs in aqueous sodium alginate solutions.The formation of double EMULSIONs was confirmed with confocal and optical microscopy.The double EMULSIONs reversed and gelled when mixed with the surfactants sodium dodecyl sulfate(SDS)and cocamidopropyl betaine(CPB).Gels can act as’EMULSION locks’to prevent spreading of the hydrocarbon plume from the areas treated with surfactant flushing,as shown in sand column tests.Shear rheology was used to quantify the viscoelastic moduli increase(gelation)upon mixing the double EMULSION with SDS and CPB.SDS was more effective than CPB in gelling the double EMULSIONs.CPB and SDS could adsorb at the interface between water and model hydrocarbons(toluene and motor oil),lowering the interfacial tension and rigidifying the interface(as shown with a Langmuir trough).Bottle tests and optical microscopy showed that SDS and CPB produced W/O and O/W EMULSIONs,with either toluene or motor oil and water.The emulsification of motor oil and toluene in water with SDS and CPB facilitated their flow through sand columns and their recovery.Toluene recovery from sand columns was quantitated using Gas-Chromatography MassSpectroscopy(GC-MS).The data show that SDS and CPB can be used both for surfactant flushing and to trigger the gelation of’EMULSION locks’.Ethanol also gelled the EMULSIONs at100 mL/L.

关键词： Remediation EMULSION Hydrocarbons Surfactant Rheology Langmuir trough

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Glyoxal induced advanced glycation end products formation in chicken meat EMULSION instead of oxidation

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Food Science and Human Wellness 2022年第4期11卷 828-836页

作者： Rui Fang Zongshuai Zhu Anthony Pius Bassey Iftikhar Ali Khan Ming Huang College of Food Science and Technology Nanjing Agricultural UniversityNanjing 210095China Center Testing International Pinbiao(Jiangsu) Certifi cation Technology Co.Ltd.Nanjing 210046China Shenzhen Key Laboratory of Marine Microbiome Engineering Institute for Advanced StudyShenzhen UniversityShenzhen 518060China Nanjing Huangjiaoshou Food Science and Technology Co.Ltd. Jiangsu Research Center for Livestock and Poultry Products Processing Engineering TechnologyNanjing 211200China

Advanced glycation end products(AGE) are potential harmful substances formed in the advanced Maillard reaction and increasingly investigated in muscle foods. However, the contribution of oxidation to the AGE formation is controversial. Moreover, reports on glyoxal(GO) induced AGE formation in chicken meat EMULSION(CME) are limited. Thus, the effects of GO on emulsifying properties, rheological behavior and AGE formation in CME were investigated. Our findings exhibited that levels of Nε-carboxymethyllysine(CML) and Nε-carboxyethyllysine(CEL) were associated with lipid oxidation but not significantly(P > 0.05). Levels of AGE peaked when GO concentration ranged from 5 mmol/L(CML) to 10 mmol/L(CEL). The droplets’ aggregation associated with the disulfide bond when the concentration of GO was at 0.5–30 mmol/L while non-disulfide bond association occurred at 30–50 mmol/L GO concentration. In conclusion, compared to the effect of oxidation, GO exhibited the main role in the AGE formation of CME. This study will provide theoretical significance for further understanding and controlling the formation of AGE in CME.

关键词： Glyoxal EMULSION Oxidation Advanced glycation end products Chicken meat

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EMULSION cold mix asphalt in the UK: A decade of site and laboratory experience

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Journal of Traffic and Transportation Engineering(English Edition) 2019年第4期6卷 359-365页

作者： Dennis Day Ian Michael Lancaster Dougie McKay Nynas UK AB Ellesmere Port CH651AJUK Tayside Contracts Dundee DD38SSUK

Cold mix asphalt manufactured using bitumen EMULSION, by its very nature, has struggled to gain market penetration in the UK due to lack of design guidance and specifications and the need to comply with prevailing hot mix asphalt specification requirements. Despite this, a number of contractors have successfully utilized EMULSION cold mix asphalt materials containing recycled asphalt planings on various categories of road. Whilst the majority of schemes in the UK have been on lower category traffic roads, in this paper we discuss the use of one material which has been used on a strategic highway(trunk road) in2008 which saved 43 t of CO2 during construction and is still performing well in situ to this day. Site construction details along with an analysis of traffic loading are presented. Laboratory simulations of in-situ curing of material supplied to site demonstrated an indirect tensile stiffness modulus at 10℃ of 5 GPa was achieved within 6 months. Binder recovered from site cores was found to be in line with comparable hot mix materials, whilst wheel tracking of site cores demonstrated excellent deformation resistance which has been borne out by site performance over the last decade. The continued development of standards enabling engineers to design and specify cold mix asphalt in the UK is also reviewed.

关键词： Cold mix Bitumen EMULSION Specifications Carbon savings

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Preparation of double-EMULSION-templated microspheres with controllable porous structures by premix membrane emulsification

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Particuology 2019年第3期17卷 22-27页

作者： Xiangming Na Weiqing Zhou Tong Li Ding Hong Juan Li Guanghui Ma State Key Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing 100190 China University of Chinese Academy of Sciences Beijing 100049 China

A scalable and versatile strategy was developed for the fabrication of uniform polymeric microspheres with controllable interconnected porous structures. Uniform water-in-oil-in-water EMULSIONs with linear poly(methyl methacrylate-glycidyl methacrylate) in the oil phase were generated by two-step premix membrane emulsification and used for constructing the microspheres. During the EMULSION solidification process, internal water droplets were packed densely together, forming a thin oil film between the internal and external water phases. After solvent diffusion, the thin film can be ruptured and pores can be templated from the internal water droplets to form interconnected porous structures. Membranes with various pore sizes were obtained. The osmotic pressure and Laplace pressure balance were used to control the porosity and pore size precisely. The proposed method enables the fabrication of functional polymeric microspheres with uniform and controllable porous structures and particle sizes. This improves their performance and broadens the scope of their applications, especially in chromatographic separation.

关键词： Double EMULSION Membrane emulsification Porous microsphere Uniform structure

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Experimental characterization of the 3D linear viscoelastic behavior of cold recycled bitumen EMULSION mixtures

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Journal of Traffic and Transportation Engineering(English Edition) 2019年第4期6卷 324-336页

作者： Andrea Graziani Carlotta Godenzoni Francesco Canestrari Dipartimento di Ingegneria Civile Edile e Architettura Università Politecnica delle Marche

Cold mixtures with bitumen EMULSION are produced at ambient temperature, leading to substantial reductions of energy consumption and atmospheric emissions. In cold recycling applications, cement is normally used to improve the mixture performance. Thus, the rheological behavior of cold recycled mixtures is different from that of conventional hot mixtures because it is due to the interaction of fresh bitumen, aged bitumen and cementitious bonds. In this study, we investigated the three-dimensional(3 D) linear viscoelastic(LVE) behavior of a cement-bitumen treated material(CBTM) mixture fabricated using bitumen EMULSION and cement. For comparison, we also investigated the 3 D LVE behavior of hot-mix asphalt containing 25% of reclaimed asphalt and fabricated using polymermodified binder. Sinusoidal axial tests on cylindrical specimens, were carried out at various temperatures(from 0℃ to 50℃) and frequencies(from 0.1 to 12 Hz). The complex Young’s modulus E~*and the complex Poisson’s ratio v~*were determined through the measurement of axial and transverse strain. We show that when considering E*, CBTM mixtures may be considered thermo-rheologically simple and the Huet-Sayegh model can be used to simulate the frequencyetemperature dependence. On the other hand, when considering v*the behavior of CBTM mixtures is very different from that of hot mix asphalt. In particular, its absolute value is almost constant and very close to 0.15.

关键词： Bitumen EMULSION Cold recycling Complex modulus Complex Poisson’s ratio Huet-Sayegh model

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Study on the thixotropy and structural recovery characteristics of waxy crude oil EMULSION

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Petroleum Science 2021年第4期18卷 1195-1202页

作者： Li-Ping Guo Xue Han Yun Lei Lei Wang Peng-Fei Yu Shuang Shia Key Laboratory of Enhanced Oil Recovery Ministry of EducationNortheast Petroleum UniversityHeilongjiang163000China Jiangsu Key Laboratory of Oil and Gas Storage&Transportation Technology Changzhou UniversityJiangsu213164China Exploration and Development Research Institute Daqing Oil Field Company LtdDaqingHeilongjiang163712China

Waxy crude oil EMULSION has thixotropic properties at the temperature near gel point,which is a macromechanical characterization of the structure failure and recovery of waxy crude oil EMULSION.In this paper,the thixotropic behaviors of waxy crude oil EMULSION near gel point were studied using hysteresis loop formed by stress linear increase and decrease,as well as the structural recovery characteristics.The influence of the loading conditions and water content on the thixotropy of waxy crude oil EMULSION were analyzed with hysteresis loop area.The concept of"structural recovery"was introduced to study the degree of structural recovery after different stewing,and influencing factors were taken into account.Results have shown that for waxy crude oil EMULSION,the failure to fully restore of the structure after lysis is the cause of the formation of hysteresis loop,and the loading conditions will not affect the strength of thixotropy and the degree of structural recovery.Additionally,the dispersed phase droplets weaken the thixotropy and structure recovery characteristics of waxy crude oil EMULSION,and the greater the water content,the weaker the thixotropy.The findings can help to better understand the safe and economic operation of waxy crude oil-water pipeline transportation.

关键词： Waxy crude oil EMULSION Thixotropic properties Structural recovery Hysteresis loop

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