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Porous heterostructure of graphene/hexagonal boron nitride as an EFFICIENT ELECTROCATALYST for hydrogen peroxide generation

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Carbon Energy 2023年第5期5卷 138-151页

作者： Mengmeng Fan Zeming Wang Yuying Zhao Qixin Yuan Jian Cui Jithu Raj Kang Sun Ao Wang Jingjie Wu Hao Sun Bei Li Liang Wang Jianchun Jiang Jiangsu Co-Innovation Center of efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and MaterialsCollege of Chemical EngineeringNanjing Forestry UniversityNanjingChina Key Lab of Biomass Energy and Material Jiangsu ProvinceJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest ResourcesInstitute of Chemical Industry of Forest ProductsChinese Academy of ForestryNanjingChina School of Environmental and Chemical Engineering Institute of Nanochemistry and NanobiologyShanghai UniversityShanghaiChina Chemicobiology and Functional Materials Institute Nanjing University of Science and TechnologyNanjingChina Department of Chemical and Environmental Engineering University of CincinnatiCincinnatiOhioUSA

Compared with the traditional heteroatom doping,employing heterostructure is a new modulating approach for carbon-based electrocatalysts.Herein,a facile ball milling-assisted route is proposed to synthesize porous carbon materials composed of abundant graphene/hexagonal boron nitride(G/h-BN)heterostructures.Metal Ni powder and nanoscale h-BN sheets are used as a catalytic substrate/hard template and“nucleation seed”for the formation of the heterostructure,respectively.As-prepared G/h-BN heterostructures exhibit enhanced electrocatalytic activity toward H_(2)O_(2) generation with 86%-95%selectivity at the range of 0.45-0.75 V versus reversible hydrogen electrode(RHE)and a positive onset potential of 0.79 versus RHE(defined at a ring current density of 0.3 mA cm^(-2))in the alkaline solution.In a flow cell,G/h-BN heterostructured electrocatalyst has a H_(2)O_(2) production rate of up to 762 mmol g_(catalyst)^(-1) h^(-1) and Faradaic efficiency of over 75%during 12 h testing,superior to the reported carbon-based electrocatalysts.The density functional theory simulation suggests that the B atoms at the interface of the G/h-BN heterostructure are the key active sites.This research provides a new route to activate carbon catalysts toward highly active and selective O_(2)-to-H_(2)O_(2) conversion.

关键词： EFFICIENT ELECTROCATALYST graphene H_(2)O_(2)generation hexagonal boron nitride porous heterostructure

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