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Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine

Chinese Journal of Chemical Engineering 2023年第4期56卷 225-232页

作者： Tinghao Jia Yunbo Yu Qing Liu Yao Yang Ji-Jun Zou Xiangwen Zhang Lun Pan Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027China ZJU-Hangzhou Global Scientific and Technological Innovation Center Zhejiang UniversityHangzhou 311200China Key Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China

Antioxidants addition is believed as a facile and effective way to improve jet fuel thermal oxidation stability.However,amine antioxidants,as one of the most important antioxidants,have not received sufficient attention in the field of jet fuel autoxidation yet.Herein,the inhibition efficiency and mechanism of decane and exo-tetrahydrodicyclopentadiene(THDCPD)oxidation by di-4-tert-butylphenylamine(diarylamine)was experimentally and theoretically investigated.The results show that diarylamine can significantly inhibit decane oxidation but is less efficient for THDCPD oxidation,which is attributed to the higher energy barrier of retro-carbonyl-ene reaction(rate-determining step)in THDCPD than that in decane during diarylamine regeneration.However,the addition of diarylamine will cause undesirable color change after accelerated oxidation and produce slightly more deposits during high-temperature thermal oxidative stress for both decane and THDCPD.The results provide significant implications for the future design of effective antioxidant additives for high-performance jet fuel.

关键词： Jet fuel Thermal oxidation stability High-energy-density fuel diarylamine Antioxidation mechanism

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Stable diarylamine-Substituted Tris(2,4,6-trichlorophenyl)methyl Radicals: One-Step Synthesis, Near-Infrared Emission, and Redox Chemistry

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CCS Chemistry 2022年第9期4卷 3190-3203页

作者： Chuan Yan Dongyue An Weinan Chen Ning Zhang Yanjun Qiao Jing Fang Xuefeng Lu Gang Zhou Yunqi Liu Lab of Advanced Materials State Key Laboratory of Molecular Engineering of PolymersFudan UniversityShanghai 200438 Department of Materials Science Fudan UniversityShanghai 200438

A mild one-step radical-to-radical synthetic strategy has been developed to directly produce a new family of diarylamine-substituted tris(2,4,6-trichlorophenyl)methyl(TTM)radicals TTM-DPA,TTM-DBPA,and TTM-DFA.The obtained TTM radical derivatives are extremely stable during chromatography purification and long-term storage in the solid state.

关键词： tris(2 4 6-trichlorophenyl)methyl radical diarylamine one-step synthesis near-infrared emission redox chemistry

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