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Linking the effect of localised pitting corrosion with mechanical integrity of a rare earth magnesium alloy for implant use

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Bioactive Materials 2023年第3期21卷 32-43页

作者： Kerstin van Gaalen Conall Quinn Felix Benn Peter E.McHugh Alexander Kopp Ted J.Vaughan Biomechanics Research Centre(BioMEC) Biomedical EngineeringSchool of EngineeringNational University of Ireland GalwayGalwayIreland Meotec GmbH AachenGermany School of Mechanical and Aerospace Engineering Queen’s University BelfastBelfastUnited Kingdom

This study presents a computational framework that investigates the effect of localised surface-based corrosion on the mechanical performance of a magnesium-based alloy.A finite element-based phenomenological corrosion model was used to generate a wide range of corrosion profiles,with subsequent uniaxial tensile test simulations to predict the mechanical response to *** python-based detection framework PitScan provides detailed quantification of the spatial phenomenological features of corrosion,including a full geometric tracking of corroding *** this approach,this study is the first to quantitatively demonstrate that a surface-based non-uniform corrosion model can capture both the geometrical and mechanical features of a magne-sium alloy undergoing corrosion by comparing to experimental *** this verified corrosion modelling approach,a wide range of corrosion scenarios was evaluated and enabled quantitative relationships to be established between the mechanical integrity and key phenomenological corrosion *** particular,we demonstrated that the minimal cross-sectional area parameter was the strongest predictor of the remaining mechanical strength(R2=0.98),with this relationship being independent of the severity or spatial features of localised surface ***,our analysis demonstrated that parameters described in ASTM G46-94 showed weaker correlations to the mechanical integrity of corroding specimens,compared to parameters determined by *** study establishes new mechanistic insight into the performance of the magnesium-based materials undergoing corrosion.

关键词： Magnesium Localised corrosion corrosion modelling Phenomenology FEM

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