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Effects of the number of imidazoline ring and the length of alkyl group chain of imidazoline derivatives on corrosion inhibition of carbon steel in HCl solution:Molecular simulation and experimental validation

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Petroleum 2022年第4期8卷 447-457页

作者： Chenfeng Zhang Junying Hu Zhi Yang Ziqi Zheng Shuai Geng Xiankang Zhong School of Oil and Natural Gas Engineering Southwest Petroleum UniversityChengdu610500China School of Materials Science and Engineering Xihua UniversityChengdu610039China State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu610500China

The effects of the number of imidazoline ring and the length of alkyl group chain of imidazoline derivatives were investigated using quantum chemical calculation,molecular dynamics simulation and experimental techniques.Three corrosion inhibitors including symmetrical lauric acid imidazoline(SAI),tetracyclic lauric acid imidazoline(LAI),and symmetric stearic acid imidazoline(SPI)were synthesized and their inhibition performance was evaluated using weight loss measurement,electrochemical techniques and surface characterization.The results show that SAI and LAI with the same length of alkyl group chain,LAI with more imidazoline rings could supply a better inhibition performance since the increase of active sites.The increase of active sites attached to the metal surface may also change the distribution of corrosion inhibitor,which could limit inhibition performance improvement.While,SAI and SPI with the same number of imidazoline rings,SPI with longer alkyl group chain shows a better inhibition efficiency due to the better hydrophobic performance of alkyl groups.Among the three inhibitors,SPI shows the best inhibition performance,indicating that the alkyl group chain length affects the inhibition performance more obvious than the number of the imidazoline rings.

关键词： Imidazoline derivatives corrosion inhibition Imidazoline ring Alkyl group chain

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Antibacterial and corrosion inhibition Properties of SA-ZnO@ODA-GO@PU Super-Hydrophobic Coating in Circulating Cooling Water System

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China Petroleum Processing & Petrochemical Technology 2022年第1期24卷 117-128页

作者： Liu Fang Kong Can Li Wei Jiang Guofei Wang Xueyao College of Chemical Engineering China University of PetroleumQingdao 266580 State Key Laboratory of Petroleum Pollution Control Beijing 102206

In order to solve the corrosion problem of circulating cooling water system,SA-ZnO@ODA-GO@PU super-hydrophobic coating was synthesized for pipeline protection.After hydrophobic modification,the contact angle(CA)of the coating was above 150°.The antibacterial ability of coating was essential for corrosion protection.SA-ZnO@ODA-GO can seriously damage the cell structure,make the cell content outflow,increase the leakage rate of protein,and make the bacteria unable to reach logarithmic growth phase within 24 h.The corrosion inhibition mechanism analysis of SA-ZnO@ODA-GO@PU coating indicated that the hydrophobic coating as a physical barrier can prevent the water molecules from entering the carbon steel and prevent the surface charge transfer.

关键词： SA-ZnO@ODA-GO@PU coating super-hydrophobic antibacterial corrosion inhibition

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corrosion inhibition of carbon steel in hydrochloric acid by cationic arylthiophenes as new eco-friendly inhibitors: Experimental and quantum chemical study

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Chinese Journal of Chemical Engineering 2021年第12期34卷 197-217页

作者： Abd El-Aziz S.Fouda Mohamed A.Ismail Abdulraqeb A.Al-Khamri Ashraf S.Abousalem Department of Chemistry Faculty of ScienceEl-Mansoura UniversityEl-Mansoura 35516Egypt Department of Chemistry Faculty of EducationArts and SciencesUniversity of Saba RegionMaribYemen Quality Control Laboratory Operations DepartmentJotunEgypt

This study describes the adsorption behavior of three arylthiophene derivatives namely:2-(4-amidino-3-fluorophenyl)-5-[4-methoxy phenyl] thiophene dihydrochloride salt(MA-1217),2-(4-amidinophenyl)-5-[4-chlorophenyll thiophene dihydrochloride salt(MA-1316) and 2-(4-amidino-3-fluorophenyl)-5-[4-ch lorophenyllthiophene dihydrochloride salt(MA-1312) at C-steel in 1.0 mol·L^(-1) HCl interface using experimental and theoretical studies.Electrochemical and mass loss measurements showed that the inhibition efficiency(IE) of the arylthiophene derivatives increases with increasing concentrations and exhibited maximum efficiency 89% at 21×10^(-6) mol·L^(-1)(MA-1217) by mass loss method.The investigated arylthiophene derivatives obey the Langmuir adsorption isotherm.From polarization studies the arylthiophene derivatives act as mixed-type inhibitors.Surface analysis were carried out and discussed.The mode of orientation and adsorption of inhibitor molecules on C-steel surface was studied using molecular dynamics(MD) simulations.Quantum chemical parameters as well as the radial distribution function indices and binding energies confirm the experimental results.

关键词： Carbon steel corrosion inhibition Adsorption Arylthiophene derivatives Polarization Electrochemical frequency modulation

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corrosion inhibition of layered double hydroxides for metal-based systems

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Nano Materials Science 2021年第1期3卷 47-67页

作者： Chuan Jing Biqin Dong Aikifa Raza Tiejun Zhang Yuxin Zhang State Key Laboratory of Mechanical Transmissions College of Materials Science and EngineeringChongqing UniversityChongqing400044PR China Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering Shenzhen UniversityShenzhen518060PR China Department of Mechanical Engineering Masdar InstituteKhalifa University of Science and TechnologyP.O.Box 127788Abu DhabiUnited Arab Emirates

Layered double hydroxide(LDH),a kind of 2D layered materials,has been recognized as the promising anticorrosion materials for metal and its alloy.The microstructure,physical/chemical properties,usage in corrosion inhibition and inhibition performance of LDH have been studied separately in open literature.However,there is a lack of a complete review to summarize the status of LDH technology and the potential R&D opportunities in the field of corrosion inhibition.In addition,the challenges for LDH in corrosion inhibition of metal-based system have not been summarized systematically.Herein,we review recent advances in the rational design of LDH for corrosion inhibition of metal-based system(i.e.Mg alloy,Al alloy,steel and concrete)and high-throughput anticorrosion materials development.By evaluating the physical/chemical properties,usage in metal-based system and the corrosion inhibition mechanism of LDH,we highlight several important factors of LDH for anticorrosion performance and common features of LDH in applying different metal alloys.Finally,we provide our perspective and recommendation in this field,including high-throughput techiniques for combinatorial compositional design and rapid synthesis of anticorrosion alloys,with the goal of accelerating the development and application of LDH in corrosion inhibition of metal-based system.

关键词： Layered double hydroxide corrosion inhibition Magnesium alloy Aluminum alloy Steel Concrete

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Mechanism,quantitative characterization,and inhibition of corrosion in lithium batteries

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Nano Research Energy 2023年第1期2卷 88-105页

作者： Yang-Yang Wang Xue-Qiang Zhang Ming-Yue Zhou Jia-Qi Huang School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyDepartment of Chemical EngineeringTsinghua UniversityBeijing 100084China

Rechargeable lithium batteries with long calendar life are pivotal in the pursuit of non-fossil and wireless society as energy storage devices.However,corrosion has severely plagued the calendar life of lithium batteries.The corrosion in batteries mainly occurs between electrode materials and electrolytes,which results in constant consumption of active materials and electrolytes and finally premature failure of batteries.Therefore,understanding the mechanism of corrosion and developing strategies to inhibit corrosion are imperative for lithium batteries with long calendar life.In this review,different types of corrosion in batteries are summarized and the corresponding corrosion mechanisms are firstly clarified.Secondly,quantitative studies of the loss of lithium in corrosion are reviewed for an in-depth understanding of the mechanism.Thirdly,the recent progress in inhibiting corrosion is demonstrated.Finally,perspectives to further investigate corrosion mechanism and inhibit corrosion are put forward to promote the development of stable lithium batteries.

关键词： corrosion mechanism quantitative method corrosion inhibition lithium batteries

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corrosion inhibition Studies of Benzoxazole Derivates for N80 Steel in 1 M HCl Solution: Synthesis, Experimental, and DTF Studies

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Open Journal of Yangtze Oil and Gas 2022年第2期7卷 101-123页

作者： Dongqiu Yang Xiaojun Feng Ning Yan Yanqun Wang Lilin Lu Ping Mei Wu Chen Lu Lai College of Chemistry and Environmental Engineering Yangtze University Jingzhou China College of Chemistry and Chemical Engineering Wuhan University of Science and Technology Wuhan China

Three benzoxazole corrosion inhibitors, namely 2-(benzo [d]oxazol-2-yl)phenol (BOP), 6-(benzo [d]oxazol-2-yl)pyridin-2-ol (BOPO), and 2-(quinolin-2-yl) benzo [d]oxazole (QBO), were synthesized. Moreover, their corrosion inhibition performance for N80 steel in 1 M HCl solution at 303 K was measured by the electrochemical measurements and surface analysis studies. The results show that the inhibition efficiency of all corrosion inhibitors increases with the increase of concentration. At the same concentration, the order of inhibition efficiency is BOP inhibition efficiency. The results show that BOP and KI are synergistic, BOPO and QBO are competitive adsorptions with KI. The quantum chemical parameters such as highest occupied molecular orbital, lowest unoccupied molecular orbital energy levels, and energy gap were calculated by the density functional theory (DTF). The relations between the inhibition efficiency and some quantum parameters have been discussed. The protective effect of the three inhibitors followed the sequence of BOP < BOPO < QBO. The results obtained from quantum chemicals and electrochemical were in reasonable agreement.

关键词： N80 Steel Benzoxazole Derivatives corrosion inhibition Electrochemical Measurements DFT

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corrosion inhibition of a Green Scale Inhibitor Polyepoxysuccinic Acid

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Chinese Chemical Letters 2003年第9期14卷 955-957页

作者： Rong Chun XIONG, Qing ZHOU, Gang WEI Beijing University of Chemistry and Technology, Beijing 100029 Beijing Univ. of Chem./Technology Beijing 100029 China

The corrosion inhibition of a green scale inhibitor, polyepoxysuccinic acid (PESA) was studied based on dynamic tests. It is found that when PESA is used alone, it had good corrosion inhibition. So, PESA should be included in the category of corrosion inhibitors. It is not only a kind of green scale inhibitor, but also a green corrosion inhibitor. The synergistic effect between PESA and Zn2+ or sodium gluconate is poor. However, the synergistic effect among PESA, Zn2+ and sodium gluconate is excellent, and the corrosion inhibition efficiency for carbon steel is higher than 99%. Further study of corrosion inhibition mechanism reveals that corrosion inhibition of PESA is not affected by carboxyl group, but by the oxygen atom inserted. The existence of oxygen atom in PESA molecular structure makes it easy to form stable chelate with pentacyclic structure.

关键词： Green scale inhibitor polyepoxysuccinic acid corrosion inhibition synergistic effect.

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inhibition mechanism of air nanobubbles on brass corrosion in circulating cooling water systems

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Chinese Journal of Chemical Engineering 2023年第10期62卷 168-181页

作者： Yuling Zhang Shaolei Lu Delie Li Haiyang Duan Congwen Duan Jinghong Zhang Songtao Liu Department of Environmental Science and Engineering North China Electric Power UniversityBaoding 071003China MOE Key Laboratory of Resources and Environmental Systems Optimization College of Environmental Science and EngineeringNorth China Electric Power UniversityBeijing 102206China

Air nanobubbles(A-NBs)were used to inhibit the brass corrosion in circulating cooling water for the first time in the study.The results of mass loss method and electrochemical method showed that A-NBs had the obvious corrosion inhibition effect.The inhibition rate reached 52%at 35℃.The impedance and surface characterization results of corrosion samples indicated that the corrosion inhibition mechanisms of A-NBs mainly included adsorption of corrosion ions,promoting the formation of the passivation film on metal surface and the formation of the bubble layer and scale film on metal surface.A-NBs are potential excellent corrosion inhibitors.

关键词： Brass Air nanobubble Passivation film Bubble layer corrosion inhibition

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Effect of Hydrodynamic Conditions on corrosion inhibition of Cu-Ni(90/10)Alloy in Seawater and Sulphide Containing Seawater Using 1,2,3-Benzotriazole

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Journal of Materials Science & Technology 2014年第1期30卷 65-76页

作者： B.V.Appa Rao K.Chaitanya Kumar Department of Chemistry National Institute of Technology Warangal

Electrochemical studies of the effect of hydrodynamic conditions on corrosion inhibition of Cu-Ni （90/10） alloy in synthetic seawater and sulphide containing synthetic seawater by 1,2,3-benzotriazole （BTAH） are presented. Impedance, potentiodynamic polarization and cyclic voltammetric （CV） studies are employed in the present investigation. The studies are carried out by using Cu-Ni （90/10） alloy rotating disc electrode at different rotation speeds and at different immersion periods. Reynolds numbers at each rotation speed infer that the flow of seawater is laminar. With increasing rotation speed of the electrode immersed in seawater without sulphide and BTAH, both the charge transfer resistance （Rot） and film resistance （Rf^lm） are increased. However, in the presence of sulphide ions and without BTAH, both the Rot and Rf,m are found to decrease with increasing rotation speed at identical immersion periods. Interestingly, when BTAH is added to seawater or seawater containing sulphide, both the Rot and Rf,m are increased to such a great extent that an inhibition efficiency of 99.99% is obtained. In the presence of BTAH, the phase angle Bode plots are more broadened and the maximum values of phase angle are increased to a value close to 90~ as the rotation speed is increased. The BTAH film is highly protective even under hydrodynamic condition also. Potentiodynamic polarization studies infer that BTAH functions as a mixed inhibitor under hydrodynamic conditions also. CV studies reveal that the protective BTAH film is stable even at anodic potentials of ＋850 mV vs Ag/AgCI.

关键词： Cu-Ni （90/10） alloy Rotating disc electrode Seawater corrosion inhibition Electrochemical studies 1,2,3-Benzotriazole

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New Polymer Syntheses Part 60: A Facile Synthetic Route to Polyamides Based on Thieno[2,3-b]thiophene and Their corrosion inhibition Behavior

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Chinese Journal of Polymer Science 2018年第7期36卷 835-847页

作者： Kamal I.Aly Amr H.Moustafa Essam K.Ahmed Hany M.Abd El-lateef Mohamed Gamal Mohamed Sahar M.Mohamed Polymer Research Lab Chemistry Department Faculty of Science Assiut University Chemistry Department Faculty of Science Sohag University Chemistry Department Faculty of Science Minia University Chemistry Department College of Science King Faisal university

Polyamides containing thieno[2,3-b]thiophene moiety were prepared via a simple polycondensation reaction of the diaminothieno[2,3-b]thiophene monomer la with different kinds of diacid chlorides （including oxalyl, adipoyl, sebacoyl, isophthaloyl, terephthaloyl, 4,4＇-azodibenzoyl, 3,3＇-azodibenzoyl, p-phenylene diacryloyl） in the presence of LiC1 and NMP as a solvent through lowtemperature solution polycondensation. The chemical structures of model compound and synthesized polyamides were confirmed by FTIR, nuclear magnetic resonance spectroscopy （including 1 H-NMR and 13 C-NMR） and elemental analysis. In addition, the thermal stability, crystallinity structure and surface morphology of synthesized polyamides were characterized via thermogravametric analysis （TGA）, wide-angle X-ray diffraction analysis （WAXD） and scanning electron microscopy （SEM）. Also, the corrosion inhibition behavior of selected examples ofpolyamides was investigated; the inhibitive effect of the investigated polymers for carbon steel in 1.0 mol＇L-1 HCI was studied using potentiodynamic polarization （PDP） and electrochemical impedance spectroscopy （EIS） methods. PDP results displayed that the polyamides containing thieno[2,3-b]thiophene moiety can be as mixed-type inhibitors. The inhibition efficiency （P, %） was found to be in the range from 67.13% to 96.01%. There is an increase in P by the synthesized polymers in comparison to the starting monomer. The adsorption of these polymers was found to obey Langmuir adsorption isotherm.

关键词： Thieno[2 3-b]thiophene Polymer synthesis Thermal properties Industrial applications corrosion inhibition

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