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conjugation expansion strategy enables highly stable all-polymer solar cells

中国化学快报:英文版 2023年第8期34卷 439-443页

作者： Dingding Qiu Yanan Shi Yi Li Jianqi Zhang Kun Lu Zhixiang Wei CAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Department of Chemistry Molecular Dynamic Chemistry CenterTianjin Key Laboratory of Molecular Optoelectronic SciencesSchool of ScienceTianjin UniversityTianjin 300354China Sino-Danish Center for Education and Research Sino-Danish CollegeUniversity of Chinese Academy of SciencesBeijing 100049China

The stability issue is one of the key factors hindering the commercial application of organic solar cells.All-polymer organic solar cell is one of the effective ways to solve the stability problem.In this work,we designed and synthesized two polymer donor materials PBDT and PDTBDT with different conjugation ranges,and demonstrated for the first time that extending the conjugation range of donor materials in all polymer solar cells can significantly improve device efficiency and stability.The experimental results of materials and devices show that PDTBDT with a larger conjugation range has stronger crystallinity and a more planar structure,which endows the active layer in its corresponding device with higher exciton dissociation probability,lower carrier recombination probability,more balanced charge transport properties and more favorable film morphology.As a result,the PDTBDT:PYF-T-o devices display an outstanding PCE of 13.38%,which is much higher than PBDT with smaller conjugation range based devices.Moreover,the PDTBDT:PYF-T-o device retains 0.86 of the initial PCE after over 500 h in the air atmosphere,exhibiting significantly improved stability.The improved stability is attributed to the enhanced moisture and air tolerance of active layer film thanks to the strong crystallinity of the donor material.These results demonstrate that the conjugation expansion strategy is one of the effective ways to obtain efficient and stable all-polymer organic solar cells.

关键词： Polymer donor conjugation expansion All-polymer organic solar cells Stability Crystallinity

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