检索结果-南通市图书馆

Adsorption of congo red on mesoporous activated carbon prepared by CO2 physical activation

Chinese Journal of Chemical Engineering 2020年第4期28卷 1069-1076页

作者： Mingjie Ma Huijuan Ying Fangfang Cao Qining Wang Ning Ai College of Chemical Engineering Zhejiang University of TechnologyHangzhou 310014China Zhejiang Province Key Laboratory of Biomass Fuel Hangzhou 310014China Biodiesel Laboratory of China Petroleum and Chemical Industry Federation Hangzhou 310014China National Chemical and Chemical Engineer Experiment Teaching Center National Chemical and Chemical Engineer Simulation Experiment Teaching CenterZhejiang University of TechnologyHangzhou 310014China

This research demonstrates the production of mesoporous activated carbon from sargassum fusiforme via physical activation with carbon *** composite design was applied to conduct the experiments at different levels by altering three operating *** temperature(766-934℃),CO2 flow rate(0.8-2.8 L·min^-1)and activation time(5-55 min)were the variables examined in this *** effect of parameters on the specific surface area,total pore volume and burn-out rate of activated carbon was studied,and the influential parameters of methylene blue adsorption value were identified employing analysis of *** optimum conditions for maximum methylene blue adsorption value were:activation temperature=900℃,activation time=29.05 min and CO2 flow rate=1.8 L·min(-1).The activated carbon produced under optimum conditions was characterized by BET,FTIR and *** adsorption behavior on congo red was *** effect of parameters on the adsorbent dosage,temperature,PH and initial congo red concentration was *** adsorption properties of the activated carbon were investigated by *** equilibrium removal rate and maximum adsorption capacity reaches up to 94.72%,234 mg·g^-1,respectively when initial congo red concentration is 200 mg·L^-1 under adsorbent dosage(0.8 g·L^-1),temperature(30℃),PH7.

关键词： Sargassum fusiforme Mesoporous activated carbon congo red Response surface method Kinetics

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Synthesis of photocatalytic La_(1–x)A_xTiO_(3.5–δ)(A=Ba, Sr, Ca) nano perovskites and their application for photocatalytic oxidation of congo red dye in aqueous solution

引用

Journal of Rare Earths 2015年第2期33卷 160-167页

作者： M.Bradha T.Vijayaraghavan S.P.Suriyaraj R.Selvakumar Anuradha M.Ashok Nanotech Research Facility PSG Institute of Advanced StudiesCoimbatore-641 004 India Nanobiotechnology Laboratory PSG Institute of Advanced StudiesCoimbatore-641 004 India

A-site substituted La0.8A0.2TiO3.5–δ（A=Ba, Sr, Ca） nano perovskites were prepared by sol-gel method and characterized using thermogravimetry/differential thermal analysis（TGA/DTA）, X-ray diffraction（XRD）, ultraviolet-visible（UV-Vis） spectroscopy and transmission electron microscopy（TEM）. XRD analysis showed that the La0.8A0.2TiO3.5–δ（A=Ba, Sr, Ca） nano perovskites derived after calcination at 800 oC were in single phase with orthorhombic structure. The particle size of all nano perovskites was found to be ~20 nm. The synthesized nano perovskites were tested for the photocatalytic decomposition of an azo dye, congo red. The sequential behavior of La0.8A0.2TiO3.5–δ（A=Ba, Sr, Ca） nanoperovskites for photocatalytic decomposition of congo red in aqueous solution by visible light at room temperature was studied at various time intervals and the efficiency of degradation of the nanoperovskites was compared. Among all the A-site substituted La0.8A0.2TiO3.5–δ（A=Ba, Sr, Ca） nano perovskites, Ba substituted compound showed the highest dye degradation.

关键词： nano perovskite oxidation photocatalyst congo red dye degradation rare earths

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

An efficient and comparative adsorption of congo red and Trypan blue dyes on MgO nanoparticles: Kinetics, thermodynamics and isotherm studies

引用

Journal of Magnesium and Alloys 2021年第2期9卷 478-488页

作者： Barsharani Priyadarshini Tanaswini Patra Tapas Ranjan Sahoo Department of Chemistry School of Applied SciencesKIIT deemed to be UniversityBhubaneswar 24OdishaIndia

Cubic phase of Mg O nanoparticles were prepared by microwave-assisted combustion synthesis and investigated for the removal of toxic dyes like congo red(CR)and Trypan blue(TB).The crystallite size of the Mg O nanoparticle was calculated to be 18 nm from XRD *** sample was further characterized by FTIR,TGA and FESEM *** dyes were subjected to prototypical batch adsorption process,including investigation of different parameters like Mg O dosage,dye concentration,solution pH,agitation speed and *** was found that,0.2 g of Mg O NPs showed maximum removal efficiency for both the dyes(more than 98%),having 25 ppm of dye concentration at an acidic p H(3–4).The maximum loading capacity of Mg O NPs was obtained to be 136 mg/g and 132 mg/g for CR and TB,*** thermodynamic parameters like△G^(0),△H^(0)and△S^(0)were *** negative△H^(0)and the positive△S^(0)values for both the dyes correspond to an exothermic process and an increase in randomness of the adsorbent and *** isotherm analysis exhibited that the Freundlich model fits better to the experimental equilibrium data,suggesting heterogeneous surface of the ***,the kinetic data revealed a pseudo 2 nd order rate for adsorption process.

关键词： Adsorption congo red Trypan blue MgO NPs Kinetics Isotherm

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Nanoscale zero-valent iron integrated with bioreactor for recalcitrant antimony-congo red dyeing wastewater treatment

引用

Progress in Natural Science:Materials International 2023年第5期33卷 569-574页

作者： Jing Liu Airong Liu Yi Wei Jiahui Fu Wei-xian Zhang College of Environmental Science and Engineering Tongji University State Key Laboratory for Pollution Control and Resource Reuse

Antimony(Sb) and recalcitrant organic dyes often coexist in dyeing wastewater, and the simultaneous removal of Sb and dyes has been a challenge for traditional biological method in the treatment of Sb-dyeing *** zero-valent iron(n ZVI) is particularly suitable for separating heavy metals and enhancing the biodegradability of recalcitrant organic compounds. Herein, n ZVI is integrated with bioreactors(n ZVI-bio system) to achieve enhanced removal of Sb and degradation of congo red(CR) in wastewater. The n ZVI-bio system achieves a reduction in Sb levels from 2.5 g L-1to 0.064 mg L-1, with a color removal efficiency of up to 98.60 % and a reduction in COD from 167 mg L-1to 55 mg L-1. The excellent performance is mainly attributed to n ZVI pretreatment, which removes Sb and degrades CR into smaller and more biodegradable organic compounds,providing favorable environmental conditions for the subsequent biotreatment system. This suggests that integrated n ZVI-bio system has potential for the treatment of complex wastewater containing heavy metals and recalcitrant organic dyes.

关键词： Nanoscale zero-valent iron Biotreatment Antimony congo red nZVI-bio system

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Radio Frequency Underwater Discharge Operation and Its Application to congo red Degradation

引用

Plasma Science and Technology 2012年第2期14卷 111-117页

作者：吉亮亮邹帅沈明荣辛煜 Provincial Key Lab.of Thin Films School of Physical Science and TechnologySoochow University

Radio frequency （RF） underwater discharge operation was performed for different liquid conductivities driven by different frequencies ranging from 13.56 MHz to 60 MHz, and its application to organic degradation was investigated. The RF underwater discharge was observed to be generated within the bubble at electrode surface formed by RF and plasma heating. It was shown that the sizes of the bubbles and plasmas increased as the driving frequency and the input power went up. The breakdown voltage decreased rapidly with the increase of the water conductivity and driving frequency. Comparative experiments of the UV-VIS absorbance spectra of congo red solution before and after discharge suggested effective degradation of the organic dye due to the active species generated during the discharge, such as .OH, .O, .H, etc. revealed by optical emission spectroscopy. The results show that higher exciting frequency and lower conduc- tivity of the solution are more effective for organic degradation. With the combination of Fourier Transform Infrared Spectroscopy （FT-IR） and Liquid Chromatography-Mass Spectrometry （LC- MS） data, one possible degradation process was proposed and the main conceivable components and structures of the products were also presented.

关键词： radio frequency plasma underwater discharge degradation congo red

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Hierarchical porous MgBO_2(OH) microspheres: Hydrothermal synthesis,thermal decomposition, and application as adsorbents for congo red removal

引用

Chinese Journal of Chemical Engineering 2018年第7期26卷 1561-1569页

作者： Panpan Sun Liyuan Chen Lin Xu Wancheng Zhu Department of Chemical Engineering Qufu Normal University

A facile eco-friendly hydrothermal route （180 ℃, 12.0 h） has been developed for the first time to the uniform hierarchical porous MgBO2（OH） microspheres without the aid of any organic additive, surfactant or template, by using the abundant MgCl2·6H2O, H3BO3 and NaOH as the raw materials. The as-obtained porous microspheres exhibit a specific surface area of 94.752 mg·g-1, pore volume of 0.814 cm3.g-1, and ca. 84.0% of which have a diameter of 2.25-3.40 μm. The thermal decomposition of the porous MgBO2（OH） microspheres （650 ℃, 2.5 ℃. min-l） leads to the porous Mg2B2O5 rnicrospheres with well-retained morphology. When utilized as the adsorbents for the removal of CR from mimic waste water, the present porous MgBO2（OH） microspheres exhibit satisfactory adsorption capacity, with the maximum adsorption capacity qm of 309.1 mg-g-1, much higher than that derived from most of the referenced adsorbents. This opens a new window for the facile green hydrothermal synthesis of the hierarchical porous MgBO2（OH） microspheres, and extends the potential application of the 3D hierarchical porous metal borates as high-efficiency adsorbents for organic dyes removal.

关键词： Hierarchical porous microspheres Magnesium borate hydroxide Adsorption congo red Hydrothermal

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Facile synthesis of α-MnO2 micronests composed of nanowires and their enhanced adsorption to congo red

引用

Frontiers of Chemical Science and Engineering 2014年第1期8卷 64-72页

作者： Weixin ZHANG School of Chemical Engineering Hefei University of Technology Hefei 230009 China Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering Hefei 230009 China

In this paper, α-MnO2 micronests composed of nanowires were fabricated via a hydrothermal reaction of MnSO4. H20 and K2S208 solutions. The α-MnO2 micron- ests were demonstrated to have a higher adsorption capacity than 7-MnO2 microspheres due to their large specific surface area. The amount of congo red adsorbed per unit weight of α-MnO2 micronests increased signifi- cantly from 114 to 282mg.g-1 with concentration of congo red solution increasing from 50 to 200 mg. L-1, but it had a little change with temperature. Kinetics, isotherms and thermodynamics for the adsorption of congo red on α- MnO2 micronests were examined. The adsorption process followed the pseudo-second-order kinetics with good correlation. The experimental data were analyzed by Langmuir and Freundlich models, and equilibrium data fitted the Langmuir isotherm very well with maximum monolayer adsorption capacity of 625 mg. g-1 at 22 ℃. The adsorption was spontaneous and endothermic accord- ing to thermodynamic studies. The experimental results indicate that α-MnO2 micronests possess a high adsorption capacity and could be employed as a replacement of traditional sorbents.

关键词： MnO2 congo red adsorption kinetics isotherm thermodynamics

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

One-step hydrothermal synthesis of Sn-doped α-Fe_(2)O_(3) nanoparticles for enhanced photocatalytic degradation of congo red

引用

Journal of Semiconductors 2022年第12期43卷 22-31页

作者： Van Nang Lam Thi Bich Vu Quang Dat Do Thi Thanh Xuan Le Tien Dai Nguyen T-Thanh-Bao Nguyen Hoang Tung Do Thi Tu Oanh Nguyen Department of Natural Sciences Hoa Lu UniversityNinh NhatNinh Binh CityViet Nam Institute of Theoretical and Applied Research Duy Tan UniversityHanoi 100000Viet Nam Faculty of Natural Sciences Duy Tan UniversityDa Nang 550000Vietnam Institute of Physics Vietnam Academy of Science and Technology10 Dao TanBa DinhHanoiVietnam Institute of Materials Science Vietnam Academy of Science and Technology18 Hoang Quoc VietCaugiayHanoiVietnam

We report on the synthesis of Sn-doped hematite nanoparticles(Sn-α-Fe_(2)O_(3) NPs)by the hydrothermal *** prepared Sn-α-Fe_(2)O_(3) NPs had a highly pure and well crystalline rhombohedral phase with an average particle size of 41.4 *** optical properties of as-synthesizedα-Fe_(2)O_(3) NPs show a higher bandgap energy(2.40-2.57 eV)than that of pure bulkα-Fe_(2)O_(3)(2.1 eV).By doping Sn intoα-Fe_(2)O_(3) NPs,the Sn-doped hematite was observed a redshift toward a long wavelength with in-creasing Sn concentration from 0%to 4.0%.The photocatalytic activity of Sn-dopedα-Fe_(2)O_(3) NPs was evaluated by congo red(CR)dye *** degradation efficiency of CR dye using Sn-α-Fe_(2)O_(3) NPs catalyst is higher than that of pureα-Fe_(2)O_(3) *** highest degradation efficiency of CR dye was 97.8%using 2.5%Sn-dopedα-Fe_(2)O_(3) NPs catalyst under visible-light *** results suggest that the synthesized Sn-dopedα-Fe_(2)O_(3) nanoparticles might be a suitable approach to develop a photocatalytic degradation of toxic inorganic dye in wastewater.

关键词： α-Fe_(2)O_(3)nanoparticles Sn congo red photocatalytic properties photodegradation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Ionic Liquid-assisted Formation of Lanthanide Metal-organic Framework Nano/Microrods for Superefficient Removal of congo red

引用

Chemical Research in Chinese Universities 2015年第6期31卷 899-903页

作者： XIAO Yi CHEN Fang ZHU Xixi QIN Hongling HUANG Hongmei ZHANG Youyu YIN Dulin HE Xiaoxiao WANG Kemin Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research Ministry of EducationCollege of Chemistry and Chemical Engineering Hunan Normal University Changsha 410081 P. R. China State Key Laboratory of Chemo/Biosensing and Chemometrics College of Chemistry andChemical Engineering College of Biology Hunan University Changsha 410082 P. R. China

New lanthanide metal-organic framework（MOF） nano/microrods, [C4mim]Cl-Eu-MOF, [C8mim]Cl-Eu- MOF and [C12mim]Cl-Eu-MOF, were conveniently synthesized via an ionic liquid-assisted hydrothermal method and characterized by means of powder X-ray diffraction（XRD）, Fourier transform infrared spectroscopy（FTIR）, thermo- gravimetric analysis（TG） and transmission electron microscopy（TEM）. The obtained nano/microrods with low sur- face areas were efficient for the removal of congo red（CR） from aqueous solutions. Under the optimum conditions, [C4mim]Cl-Eu-MOF with a specific surface area of 5.1 m^2/g exhibited an ultrahigh adsorption capacity of 2606 mg/g toward CR. Notably, the adsorption efficiency of [C4mim]Cl-Eu-MOF for CR via nano/microscale stacking can be directly demonstrated by TEM. In-depth understanding of CR removal by [C4mim]Cl-Eu-MOF nano/microrods was also supported by FTIR, Raman spectroscopy and zeta potential analyses.

关键词： Lanthanide metal-organic framework Nano/microrod Ionic liquid congo red Adsorption

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

A green cross-linking method for the preparation of renewable threedimensional graphene sponges for efficient adsorption of congo red dye

引用

Chinese Journal of Chemical Engineering 2024年第2期66卷 84-93页

作者： Zhuang Liu Bo Gao Haoyuan Han Yuling Li Haiyang Fu Donghui Wei Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China

Graphene-based materials possess significant potential for the treatment of dye wastewater due to their exceptional adsorption properties toward stubborn ***,their utilization is hindered by high preparation costs,low yields,environmental pollution during synthesis,and challenges in regenerating the *** study proposes a novel approach to address these limitations by developing nitrogen-doped three-dimensional(3D)polyvinyl alcohol(PVA)crosslinked graphene sponges(N-PGA)using a cross-linking method with ammonium *** method offers a relatively mild,environmentally friendly *** carbonate serves as both a reducing and modifying agent,facilitating the formation of the intrinsic structure of N-PGA and acting as a nitrogen ***,PVA is utilized as the cross-linking *** results demonstrate that N-PGA exhibits a favorable internal 3D hierarchical porous structure and possesses robust mechanical *** measured specific surface area(BET)of N-PGA was as high as406.538 m^(2)·g^(-1),which was favorable for its efficient adsorption of congo red(CR)dye *** an initial concentration of 50 mg·L^(-1),N-PGA achieved an impressive removal rate of 89.6%and an adsorption capacity of 112 mg·g^(-1)for CR ***,it retained 79%of its initial adsorption capacity after 10 cycles,demonstrating excellent regeneration *** summary,the synthesized N-PGA displays remarkable efficacy in the adsorption of CR dye in wastewater,opening up new possibilities for utilizing 3D porous graphene nanomaterials as efficient adsorbents in wastewater treatment.

关键词： Green chemistry Graphene sponge Adsorbents Adsorption congo red Regeneration

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：