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Highly Efficient Random Terpolymers for Photovoltaic Applications with Enhanced absorption and Molecular Aggregation

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Chinese Journal of Polymer Science 2017年第2期35卷 249-260页

作者： Xiao-peng Xu Guang-jun Zhang Yun-zhe Zhao 刘江 Ying Li 彭强 Key Laboratory of Green Chemistry and Technology of Ministry of Education College of ChemistryState Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610064China Chengdu Green Energy and Green Manufacturing Technology R&D Center Chengdu 610207China

A series of copolymers, based on benzo[1,2-b：4,5-b＇]dithiophene （BDT） as the electron donor and 2,1,3- benzothiadiazole （BT）/diketopyrrolo[3,4-c]pyrrole （DPP） as the electron acceptors, were synthesized for highly efficient polymer solar cells. By changing the BT/DPP ratio in the conjugated backbone, the absorption, energy levels, molecular aggregation and carrier mobility could be finely tuned. With increased DPP content, the absorption range was extended to the longer wavelength region with narrower bandgaps. The highest occupied molecular orbital （HOMO） levels were also raised up and the molecular aggregation was enhanced. The balance of these factors would afford a remarkable device performance enhancement. Polymer P3 with BT：DPP = 0.7：0.3 （molar ratio） exhibited the highest power conversion efficiency （PCE） of 9.01%, with open circuit voltage （Voc） = 0.73 V, short current density （Jsc） = 18.45 ***-2, and fill factor （FF） - 66.9%. The PCE value was improved by 48.7% compared to P1 and by 117.6% compared to P7, respectively, indicating a great potential in photovoltaic application.

关键词： Polymer solar cells Terpolymers complementary absorption Molecular aggregation

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Recent Advances of Monolithic All-Perovskite Tandem Solar Cells:From Materials to Devices

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Chinese Journal of Chemistry 2022年第7期40卷 856-871页

作者： Shan Jiang Yiming Bai Zongwen Ma Shengli Jin Chao Zou Zhao'ao Tan State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources North China Electric Power UniversityBeijing 102206China Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical TechnologyBeijing 100029China Key Laboratory of Solar Energy Utilization&Energy Saving Technology of Zhejiang Province Zhejiang Energy Group R&D Institute Co.Ltd.HangzhouZhejiang 311121China College of Chemistry and Materials Engineering Wenzhou UniversityWenzhouZhejiang 325027China

Organic-inorganic metal-halide perovskite solar cells(PerSCs)have achieved significant progresses due to their outstanding optoelectronic charac-teristics,and the power conversion efficiency(PCE)of single-junction PerSCs has been boosted from 3.8%to a certified 25.2%.However,the efficien-cy of single-junction cells is governed by the Shockley-Queisser(S-Q)radiative limit,and fabricating all-perovskite tandem solar cells is a particularly attractive method to break the S-Q *** the bandgap of lead(Pb)-based mixed halide perovskite can be tuned from 1.55 eV to 2.3 eV,and the mixed tin(Sn)-Pb perovskites have bandgap of~1.2 eV,these perovskites become the best candidates for the front and rear subcells of all-perovskite tandem device,*** this review,we firstly summarize the current development progresses of two-terminal(2-T)all-perovskite tandem so-lar *** further optimizing the device performance,the wide bandgap mixed halide perovskites for front subcell,mixed Sn-Pb narrow bandgap perovskites for rear subcell,and the interconnection layer(ICL)of 2-T tandem device are then *** review aims to open a pathway to real-ize highly efficient all-perovskite tandem solar cells.

关键词： Perovskite phase Tandem solar cells Interconnection layer Energy conversion complementary absorption

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