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A new alternating copolymerized derivative as a cold flow improver for diesel fuel

Petroleum Science 2009年第1期6卷 82-85页

作者： ZHANG Haikuan LIU Hongyan WANG Shujun State Key Laboratory of Heavy Oil Processing China University of Petroleum Beijing 102249 China China National Oil ＆ Gas Exploration and Development Corporation China National Petroleum Corporation Beijing 100034 China

Synthesis of a cold flow improver （MAVA-a） for diesel fuel and its effect on solidifying point （SP） and cold filter plugging point （CFPP） of diesel fuels were investigated, The cold flow improver was prepared by using maleic anhydride （MA） and vinyl acetate （VA） as raw materials, toluene as solvent, dibenzoyl peroxide （BPO） as initiator, through alternating polymerization under nitrogen to obtain a binary-polymer and then through aminolysis by using a higher carbon amine as aminating agent at a temperature of 80 ℃. A cold flow improver was designed and prepared for No. 0 diesel fuel from Zhang Jia-Gang Petrochemical Company according to the contents of n-paraffin and its carbon number distribution in the No. 0 diesel fuel. It was also used together with two kinds of ethene-vinyl acetate copolymer improvers （EVA） separately. The test result showed that the CFPP of the No. 0 diesel fuel could be lowered by 3-5 ℃ when the improver MAVA-a was used. The CFPP was lowered by 8℃ when the improver MAVA-a was used together with EVA-2.

关键词： cold flow improver solidifying point cold filter plugging point copolymer amination

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Poly-Acrylic Acid Derivatives as Diesel flow improver for Paraffin-Based Daqing Diesel

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Journal of Natural Gas Chemistry 2006年第3期15卷 217-222页

作者： Cuiyu Jiang Ming Xu Xiaoli Xi Panlun Qi Hongyan Shang College of Chemistry and Chemical Engineering China University of Petroleum Dongying 257061 China Research Institute of Daqing Petroleum Co. SINOPEC Daqing 163714 China

Since the diesel products from paraffin-based Daqing crude oil showed low sensitivity to certain commercial diesel pour point depressant （PPDs） that resulted from the high content of paraffin, certain poly-acrylic acid derivatives （PADE） with-COOR, -COOH,-CONHR, and -COO-NH3^＋R groups by molecular design on the mechanics of diesel; PPDs were synthesized and evaluated as cold flow improver for Daqing 0^# diesel in this paper. The pure PADE was superior to the commercial PPDs and displayed a substantial ability of wax crystals dispersion. There was a synergistic effect among the PADE and T1804 and secondary amine. The synergism clearly improved the low temperature performance of Daqing diesel products and could reduce the cold filter plugging point of 0^# diesel by 6-7 ℃.

关键词： diesel cold flow improver acrylic acid cold filter plugging point

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Study on Dibehenyl Fumarate-Vinyl Acetate Copolymer for Lowering cold Filter Plugging Point of Diesel Fuel

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China Petroleum Processing & Petrochemical Technology 2010年第4期12卷 52-56页

作者： Du Tao Wang Shujun Liu Hongyan Zhang Ying State Key Laboratory of Heavy Oil Processing China University of Petroleum Beijing 102249 Faculty of Chemical Science ＆ Engineering China University of Petroleum

In the practice of petroleum industry, adding cold flow improver （CFI） to lower the fuel＇s cold filter plugging point （CFPP） is an effective and economic way for improving the cold flow performance of diesel fuel. This paper described the synthesis and evaluation of the performance of dibehenyl fumarate-vinyl acetate （FV） copolymer for improving the cold flow performance of the tested diesel fuels. The carbon distribution in n-alkanes of the tested diesel samples were analyzed by gas phase chromatography. The structure of the copolymer was confirmed by the 1H NMR spectroscopy. The wax crystals morphologies with and without adding the FV additive were investigated by means of polarizing microscope. The test results indicated that the FV additive could depress CFPP of the tested diesel samples by 2℃ and 4℃, respectively, when dosage of the additive was 0.08 m%. The additive can modify the size and shape of the wax crystals and inhibit the formation of larger wax crystal lattices.

关键词： diesel fuel cold flow improver cold filter plugging point copolymer wax crystal

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