检索结果-南通市图书馆

Critical Review on cathode-electrolyte interphase Toward High-Voltage cathodes for Li-Ion Batteries

Nano-Micro Letters 2022年第10期14卷 197-218页

作者： Jijian Xu Department of Chemical and Biomolecular Engineering University of Maryland College ParkCollege ParkMD 20742USA

The thermal stability window of current commercial carbonate-based electrolytes is no longer sufficient to meet the ever-increasing cathode working voltage requirements of high energy density lithium-ion batteries.It is crucial to construct a robust cathode-electrolyte interphase(CEI)for high-voltage cathode electrodes to separate the electrolytes from the active cathode materials and thereby suppress the side reactions.Herein,this review presents a brief historic evolution of the mechanism of CEI formation and compositions,the state-of-art characterizations and modeling associated with CEI,and how to construct robust CEI from a practical electrolyte design perspective.The focus on electrolyte design is categorized into three parts:CEI-forming additives,anti-oxidation solvents,and lithium salts.Moreover,practical considerations for electrolyte design applications are proposed.This review will shed light on the future electrolyte design which enables aggressive high-voltage cathodes.

关键词： cathode-electrolyte interphase High-voltage cathodes Interfacial chemistry electrolyte design Batteries.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Advanced cathode for dual-ion batteries: Waste-to-wealth reuse of spent graphite from lithium-ion batteries

引用

eScience 2022年第1期2卷 95-101页

作者： Jia-Lin Yang Xin-Xin Zhao Wen-Hao Li Hao-Jie Liang Zhen-Yi Gu Yan Liu Miao Du Xing-Long Wu MOE Key Laboratory for UV Light-Emitting Materials and Technology Northeast Normal UniversityChangchunJilin130024PR China National&Local United Engineering Lab for Power Battery Department of ChemistryNortheast Normal UniversityChangchun130024PR China

The amount of spent lithium-ion batteries (LIBs) is constantly increasing as their popularity grows. It is important todevelop a recycling method that cannot only convert large amounts of waste anode graphite into high value-addedproducts but is also simple and environmentally friendly. In this work, spent graphite from an anode was transformed into a cathode for dual-ion batteries (DIBs) through a two-step treatment. This method enables the crystalstructure and morphology of spent graphite to recover from the adverse effects of long cycling and be restored to aregular layered structure with appropriate layer spacing for anion intercalation. In addition, pyrolysis of the solidelectrolyte interphase into an amorphous carbon layer prevents the electrode from degrading and improves itscycling performance. The recycled negative graphite has a high reversible capacity of 87 mAh g^(-1) at 200 mA g^(-1),and its rate performance when used as a cathode in DIBs is comparable to that of commercial graphite. This simplerecycling idea turns spent anode graphite into a cathode material with attractive potential and superior electrochemical performance, genuinely achieving sustainable energy use. It also provides a new method for recoveringexhausted batteries.

关键词： Spent lithium-ion battery Graphite Reuse Dual-ion batteries cathode-electrolyte interphase

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Dually-functionalized Ni-rich layered oxides for high-capacity lithium-ion batteries

引用

Journal of Materials Science & Technology 2021年第27期86卷 70-76页

作者： Ji Won Kim Kwangeun Jung Taeeun Yim Department of Chemistry Incheon National University119 Academy-roYeonsu-guIncheon 22012Republic of Korea

Layered lithium nickel-cobalt-manganese oxides(NCM)have been highlighted as advanced cathode materials for lithium-ion batteries(LIBs);however,their low interfacial stability must be overcome to ensure stable cycling performance of the cell.In this work,we propose a one-step surface modification method that uses a task-specific precursor,N,N,N,N-tetraethylsulfamide(NTESA),to improve interfacial stability of Ni-rich NCM cathode materials.The unstable surface properties of Ni-rich NCM cathode material are improved by embedding an artificial cathode-electrolyte interphase(CEI)layer on the cathode surface by heat treatment of the Ni-rich NCM cathode material with an NTESA precursor at low temperature.Our material analyses indicate that this approach allows the formation of amine-and sulfone-functionalized CEI layers on the surface of Ni-rich NCM cathode material without changing the layered structure of the cathode material.NTESA-functionalized Ni-rich NCM cathode materials exhibit improved cycling retention after 100 cycles:for example,a cell cycled with a 3.0 NTESA-modified NCM811 cathode presents the highest retention ratio of 88.3%,whereas a cell cycled with a non-functionalized NCM811 cathode suffers from rapid fading of the cycling performance(68.4%).Our additional SEM,XPS,and EIS analyses indicate that electrolyte decomposition is suppressed during electrochemical cycling,thereby leading to smaller increases in the internal resistances.ICP-MS analyses of the cycled anodes also indicate that the NTESA-based artificial CEI layer inhibits the dissolution of transition metal components from the Ni-rich NCM cathode materials,thereby contributing to an improved overall electrochemical performance of the cell.

关键词： Lithium-ion battery cathode cathode-electrolyte interphase N,N,N,N-Tetraethylsulfamide Electrochemical performance

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：